Disorder-induced far infrared absorption in amorphous materials

Abstract In a variety of amorphous materials, the far infrared and microwave absorption (3–3000 GHz or 0.1–100 cm−1) is orders of magnitude greater than that observed in corresponding crystalline materials. This absorption is temperature independent and rises with frequency as νβ (β ≲ 2). The magnitude of the absorption correlates with the density of states inferred from the T3 term in specific heat, and is interpreted as due to a disorder-induced coupling of the far infrared radiation to a density of low frequency Debye modes in the amorphous solids.

[1]  E. Schlömann,et al.  Dielectric Losses in Ionic Crystals with Disordered Charge Distributions , 1964 .

[2]  J. E. Smith,et al.  Theory of Infrared and Raman Spectra of Amorphous Si and Ge , 1973 .

[3]  E. Whalley Infra-red and Raman spectra of glasses. Part 1.—Theory for the translational lattice vibrations , 1972 .

[4]  William M. Sinton,et al.  Recent Investigations in the Far Infra-Red , 1950 .

[5]  M. Kastner Compositional Trends in the Optical Properties of Amorphous Lone-Pair Semiconductors , 1973 .

[6]  R. Hanna Infrared Absorption Spectrum of Silicon Dioxide , 1965 .

[7]  M. Brodsky,et al.  Infrared vibrational spectra of amorphous Si and Ge , 1974 .

[8]  M. Cardona,et al.  Far‐infrared absorption in amorphous III‐V compound semiconductors , 1973 .

[9]  R. Stephens Low-Temperature Specific Heat and Thermal Conductivity of Noncrystalline Dielectric Solids , 1973 .

[10]  H. Schulze,et al.  Abschätzung der Ein- und Mehrphononenanteile der Absorption von Polymeren zwischen 1011 Hz und 1012 Hz , 1972 .

[11]  M. Miler Infrared absorption of glassy silicon dioxide , 1968 .

[12]  R. Stolen,et al.  Far infrared absorption in fused quartz and soft glass , 1968 .

[13]  P. Wong,et al.  Infra-red and Raman spectra of glasses. Part 2.—Far infra-red spectrum of vitreous silica in the range 100–15 cm–1 , 1970 .

[14]  E. Amrhein,et al.  Low-temperature microwave absorption in insulating materials , 1968 .

[15]  J. Tauc,et al.  Infrared absorption in amorphous germanium , 1970 .

[16]  R. Pohl,et al.  Thermal Conductivity and Specific Heat of Noncrystalline Solids , 1971 .