Correlated motion of small Ag clusters and Ge dimer-buckling on Ge(001)

We study submonolayer Ag deposited Ge(001) surfaces at 90 K by scanning tunneling microscopy (STM). Silver atoms and their small aggregates on the surface are found as bright dots on the surface at 78 K. The Ag aggregates form small clusters, and move with the change of the buckling phase in the adjacent Ge dimer row at 180 K as observed in successive STM images. These are transient processes to the formation of a surface alloy between Ag and Ge.

[1]  E. Altman,et al.  Effect of surface intermixing on the morphology of Sb-terminated Ge(100) surfaces , 2001 .

[2]  C. Ordás,et al.  Formation and decay of metastable Ge clusters on Ge(001) , 2000 .

[3]  S. Arai,et al.  Initial stage of Ag growth on Ge(001) surfaces at room temperature , 1999 .

[4]  S. Arai,et al.  Growth of thin Ag islands on Ge(001)-2×1 surfaces below room temperature , 1999 .

[5]  K. Hata,et al.  Spontaneous Fluctuation between Symmetric and Buckled Dimer Domains of Si(100) at 80 K , 1999 .

[6]  B. Swartzentruber,et al.  Spontaneous formation of an ordered c(4×2)-(2×1) domain pattern on Ge(001) , 1998 .

[7]  G. Ehrlich,et al.  Diffusion of Large Surface Clusters: Direct Observations on Ir(111) , 1997 .

[8]  K. Takayanagi,et al.  DIMER BUCKLING INDUCED BY SINGLE-DIMER VACANCIES ON THE SI(001) SURFACE NEAR TC , 1997 .

[9]  Besenbacher,et al.  Growth of Ag on Cu(100) studied by STM: From surface alloying to Ag superstructures. , 1996, Physical review. B, Condensed matter.

[10]  Ferrer,et al.  Disordering of the low-temperature c(4 x 2) structure of Ge(001) to the (2 x 1) reconstruction: Evidence for a mean-field transition. , 1996, Physical review. B, Condensed matter.

[11]  Rosenfeld,et al.  Decay of two-dimensional Ag islands on Ag(111). , 1996, Physical review letters.

[12]  H. Neddermeyer,et al.  Low‐temperature scanning tunneling microscopy on vicinal Ge(100) , 1996 .

[13]  Wolkow Evidence of adsorbed atom pairing during homoepitaxial growth of silicon. , 1995, Physical review letters.

[14]  Wu,et al.  Energetics and dynamics of Si Ad-dimers on Si(001). , 1995, Physical review letters.

[15]  Kevan Surface states and reconstruction on Ge(001). , 1985, Physical review. B, Condensed matter.

[16]  J. R. Lince,et al.  Electron localization and superconductivity in very thin epitaxially grown Ag films on Ge (001) , 1984 .

[17]  T. Chiang,et al.  Studies of the Ag-Ge(100) interface , 1984 .

[18]  J. R. Lince,et al.  Epitaxial growth of Ag films on Ge(001) , 1983 .