Changes of lignin concentration and C:N in oilseed rape, wheat and clover residues during their decomposition in the soil

Field experiments were conducted in 2003-2005 at the Experimental Station of the Lithuanian University of Agriculture to study the changes of lignin concentration and C:N in roots and top residues of winter and spring oilseed rape (Brassica napus L.), winter wheat (Triticum aestivum L.) and red clover (Trifolium pratense L.) after 14, 33, 63, 85 and 116 weeks of decomposition in the soil. Correlation between lignin concentration and amount of dry matter as well as the ratio of carbon and nitrogen in investigated crop residues were estimated. Investigation of crop residue decomposition during the period of 116 weeks showed that stubble and roots of winter and spring oilseed rape decompose more slowly than their threshing remains, or stubble, and roots of winter wheat and red clover. Dry matter and lignin decomposed and the ratio of carbon and nitrogen in winter oilseed rape residues decreased more slowly than that of spring oilseed rape residues. The ratio of carbon and nitrogen in the decomposing crop residues decreased most intensively during the 33-63 week period. After that, the concentration of lignin started to decrease, but its significant decline in all investigated crop residues was estimated after 116 weeks of decomposition. Lignin was most decomposed from its concentration peak in the stubble of red clover (37,9%) and least in winter oilseed rape roots (12.8%). Negative correlation between lignin concentration and dry matter amount and between lignin concentration and C:N was established in winter and spring oilseed rape, winter wheat and red clover top and root residues decomposing in the soil.