Quartz crystal resonators as sensors in liquids using the acoustoelectric effect

Piezoelectric quartz crystal resonators (QCRs) have been investigated as detectors in liquid environments. In all the applications, mass loading and viscous coupling are the main interaction mechanisms which result in changes in the QCR resonant frequency. However, other interaction mechanisms such as the acoustoelectric interaction due to fringing fields at electrode ends arise which contribute to the total change in frequency, in particular, the parallel resonant frequency. In the present work, it is shown that by modifying the geometry of the electrode at the QCR surface in contact with the solution, a transition region can be created in which the lateral decaying acoustic field is enhanced

[1]  Stephen J. Martin,et al.  Characterization of a quartz crystal microbalance with simultaneous mass and liquid loading , 1991 .

[2]  Theory and application of a quartz resonator as a sensor for viscous liquids , 1990 .

[3]  J. Gordon,et al.  The oscillation frequency of a quartz resonator in contact with liquid , 1985 .

[4]  Harold E. Hager,et al.  FLUID PROPERTY EVALUATION BY PIEZOELECTRIC CRYSTALS OPERATING IN THE THICKNESS SHEAR MODE , 1986 .

[5]  H. Sekimoto Analysis of trapped energy resonators with circular electrodes , 1984, IEEE Transactions on Sonics and Ultrasonics.

[6]  Stanley Bruckenstein,et al.  Experimental aspects of use of the quartz crystal microbalance in solution , 1985 .

[7]  F. Josse,et al.  Quartz resonator as sensor for viscous/conductive liquids , 1989 .

[8]  F. Josse,et al.  Acoustoionic interaction of SH surface waves with dilute ionic solutions , 1991, IEEE Transactions on Ultrasonics, Ferroelectrics and Frequency Control.

[9]  F. Josse,et al.  Analysis of piezoelectric bulk-acoustic-wave resonators as detectors in viscous conductive liquids , 1990, IEEE Transactions on Ultrasonics, Ferroelectrics and Frequency Control.

[10]  W. H. King,et al.  A Universal Mass Detector for Liquid Chromatography , 1973 .

[11]  T. Nomura,et al.  Effect of metal ions on a piezoelectric quartz crystal in aqueous solution and the adsorptive determination of iron(III) as phosphate , 1983 .

[12]  Harold E. Hager,et al.  Velocity profile on quartz crystals oscillating in liquids , 1989 .

[13]  Isao Karube,et al.  Computation of equivalent circuit parameters of quartz crystals in contact with liquids and study of liquid properties , 1988 .

[14]  Y. Shou-zhuo,et al.  On equivalent circuits of piezoelectric quartz crystals in a liquid and liquid properties: Part I. Theoretical derivation of the equivalent circuit and effects of density and viscosity of liquids , 1990 .

[15]  M. Grunze,et al.  On the use of ZX-LiNbO3 acoustic plate mode devices as detectors for dilute electrolytes , 1992 .

[16]  M. Thompson,et al.  Perturbation of the electrified interface and the response of the thickness-shear mode acoustic wave sensor under conductive liquid loading , 1993 .

[17]  S. Yao,et al.  Dependence of the oscillation frequency of a piezoelectric crystal on the physical parameters of liquids , 1988 .

[18]  G. Bastiaans,et al.  Piezoelectric crystals as detectors in liquid chromatography , 1980 .

[19]  Stephen J. Martin,et al.  Effect of surface roughness on the response of thickness-shear mode resonators in liquids , 1993 .

[20]  M. Ward,et al.  Scanning Electrochemical Mass Sensitivity Mapping of the Quartz Crystal Microbalance in Liquid Media , 1992 .

[21]  T. S. West,et al.  Behaviour of piezoelectric quartz crystals in solutions with application to the determination of iodide , 1985 .

[22]  H. F. Tiersten,et al.  Analysis of trapped‐energy resonators operating in overtones of coupled thickness‐shear and thickness‐twist , 1976 .

[23]  W. J. Spencer,et al.  Thickness‐Shear Vibration in Rectangular AT‐Cut Quartz Plates with Partial Electrodes , 1968 .

[24]  Michael J. Thompson,et al.  Thickness-shear-mode acoustic wave sensors in the liquid phase. A review , 1991 .