Effects of Carbon Fillers on Tensile and Flexural Properties in Polypropylene-Based Resins

A potential application for conductive resins is in bipolar plates for use in fuel cells. The addition of carbon filler can increase the electrical and thermal conductivities of the polymer matrix but will also have an effect on the tensile and flexural properties, important for bipolar plates. In this research, three different types of carbon (carbon black, synthetic graphite, and carbon nanotubes) were added to polypropylene and the effects of these single fillers on the flexural and tensile properties were measured. All three carbon fillers caused an increase in the tensile and flexural modulus of the composite. The ultimate tensile and flexural strengths decreased with the addition of carbon black and synthetic graphite, but increased for carbon nanotubes/polypropylene composites due to the difference in the aspect ratio of this filler compared to carbon black and synthetic graphite. Finally, it was found that the Nielsen model gave the best prediction of the tensile modulus for the polypropylene based composites. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010

[1]  J. King,et al.  Effects of Carbon Fillers in Thermally Conductive Polypropylene Based Resins , 2010 .

[2]  Hanafi Ismail,et al.  Effect of Multi-walled Carbon Nanotubes on Mechanical Properties of Feldspar Filled Polypropylene Composites , 2009 .

[3]  I. Miskioglu,et al.  Tensile modulus modeling of carbon‐filled liquid crystal polymer composites , 2009 .

[4]  J. King,et al.  Electrical conductivity of carbon-filled polypropylene-based resins , 2009 .

[5]  K. Kashyap,et al.  On Young’s modulus of multi-walled carbon nanotubes , 2008 .

[6]  S. Tjong,et al.  Mechanical behaviors of polypropylene/carbon nanotube nanocomposites : The effects of loading rate and temperature , 2008 .

[7]  I. Miskioglu,et al.  Synergistic effects of carbon fillers on tensile and flexural properties in liquid‐crystal polymer based resins , 2008 .

[8]  J. Keith,et al.  Synergistic effects of carbon fillers in electrically and thermally conductive liquid crystal polymer based resins , 2008 .

[9]  L. Drzal,et al.  Flexural and tensile moduli of polypropylene nanocomposites and comparison of experimental data to Halpin-Tsai and Tandon-Weng models , 2007 .

[10]  D. Baird,et al.  Development of bipolar plates for fuel cells from graphite filled wet-lay material and a thermoplastic laminate skin layer , 2007 .

[11]  Tianxi Liu,et al.  Preparation and characterization of carbon nanotube/polyetherimide nanocomposite films , 2007 .

[12]  I. Miskioglu,et al.  Nanoscratch testing to assess the fiber adhesion of short‐carbon‐fiber composites , 2007 .

[13]  Yong Zhang,et al.  Effect of different carbon fillers on the properties of PP composites : Comparison of carbon black with multiwalled carbon nanotubes , 2006 .

[14]  J. Keith,et al.  Electrical conductivity and rheology of carbon‐filled liquid crystal polymer composites , 2006 .

[15]  Jonathan N. Coleman,et al.  Mechanical Reinforcement of Polymers Using Carbon Nanotubes , 2006 .

[16]  E. Thomas,et al.  Morphology and properties of melt-spun polycarbonate fibers containing single- and multi-wall carbon nanotubes , 2006 .

[17]  J. Keith,et al.  Thermal and electrical conductivity of carbon–filled liquid crystal polymer composites , 2006 .

[18]  M. Sumita,et al.  A study on correlation between physical properties and interfacial characteristics in highly loaded graphite-polymer composites , 2005 .

[19]  Jose Maria Kenny,et al.  Thermal and mechanical properties of single-walled carbon nanotubes–polypropylene composites prepared by melt processing , 2005 .

[20]  M. Huneault,et al.  Electrically conductive thermoplastic blends for injection and compression molding of bipolar plates in the fuel cell application , 2004 .

[21]  Tianxi Liu,et al.  Morphology and Mechanical Properties of Multiwalled Carbon Nanotubes Reinforced Nylon-6 Composites , 2004 .

[22]  J. Coleman,et al.  A generic organometallic approach toward ultra-strong carbon nanotube polymer composites. , 2004, Journal of the American Chemical Society.

[23]  R. Gorga,et al.  Toughness enhancements in poly(methyl methacrylate) by addition of oriented multiwall carbon nanotubes , 2004 .

[24]  I. Miskioglu,et al.  Synergistic effects of carbon fillers on tensile and impact properties in nylon 6,6 and polycarbonate based resins , 2004 .

[25]  I. Miskioglu,et al.  Tensile and impact properties of carbon filled nylon-6,6 based resins , 2004 .

[26]  I. Miskioglu,et al.  Tensile modulus modeling of carbon-filled nylon 6,6 and polycarbonate-based resins , 2003 .

[27]  Tsu-Wei Chou,et al.  Elastic moduli of multi-walled carbon nanotubes and the effect of van der Waals forces , 2003 .

[28]  Viral S. Mehta,et al.  Review and analysis of PEM fuel cell design and manufacturing , 2003 .

[29]  Jan-Chan Huang,et al.  Carbon black filled conducting polymers and polymer blends , 2002 .

[30]  J. Eguiazábal,et al.  Structure and mechanical properties of blends of two thermotropic copolyesters , 2002 .

[31]  Mária Omastová,et al.  Relation between electrical and mechanical properties of conducting polymer composites , 2001 .

[32]  K. Friedrich,et al.  The electrical conductivity of carbon-fibre-reinforced polypropylene/polyaniline complex-blends: experimental characterisation and modelling , 2001 .

[33]  Julia A. King,et al.  Factorial design approach applied to electrically and thermally conductive nylon 6,6 , 2001 .

[34]  M. Narkis,et al.  New injection moldable electrostatic dissipative (ESD) composites based on very low carbon black loadings , 1999 .

[35]  P. K. Mallick,et al.  Composites engineering handbook , 1997 .

[36]  U. Yilmazer,et al.  Some microwave and mechanical properties of carbon fiber-polypropylene and carbon black-polypropylene composites , 1996 .

[37]  H. Chiu,et al.  Influence of mechanical properties in carbon black (CB) filled isotactic polypropylene (iPP) and propylene-ethylene block copolymer , 1996 .

[38]  V. Divjaković,et al.  Polypropylene–Carbon black interaction in conductive composites , 1993 .

[39]  D. Adams,et al.  Development and evaluation of surface teratmetns to enhance the fiber-matrix adhesion in PAN-based carbon fiber/liquid crystal polymer composites. Part II: Electrochemical teatments , 1993 .

[40]  D. Adams,et al.  Development and evaluation of surface treatments to enhance the fiber‐matrix adhesion in PAN‐based carbon fiber/liquid crystal polymer composites. Part I: Coupling agent and amine surface treatments , 1993 .

[41]  Y. Agari,et al.  Thermal conductivity of polymer filled with carbon materials: Effect of conductive particle chains on thermal conductivity , 1985 .

[42]  S. McGee,et al.  Combining rules for predicting the thermoelastic properties of particulate filled polymers, polymers, polyblends, and foams , 1981 .

[43]  Donald M. Bigg Battelle Conductive polymeric compositions , 1977 .

[44]  J. C. H. Affdl,et al.  The Halpin-Tsai Equations: A Review , 1976 .

[45]  L. Nielsen The Thermal and Electrical Conductivity of Two-Phase Systems , 1974 .

[46]  L. Nielsen Generalized Equation for the Elastic Moduli of Composite Materials , 1970 .

[47]  J. Halpin Stiffness and Expansion Estimates for Oriented Short Fiber Composites , 1969 .

[48]  Marko Canadija,et al.  FE modelling of multi-walled carbon nanotubes , 2009 .

[49]  I. Miskioglu,et al.  Tensile properties of carbon filled liquid crystal polymer composites , 2008 .

[50]  C. L. Tucker,et al.  Enhanced conductivity of fuel cell plates through controlled fiber orientation , 2003 .