We report the first ultraviolet spectropolarimetry of the peculiar B-type emission-line star with infrared excess HD 45677. The observations were obtained during the 1990 December Astro-l space shuttle mission with the Wisconsin Ultraviolet Photo-Polarimeter Experiment, and cover the spectral range 1400-3220 A. We also present the first optical spectropolarimetry, extending from the atmospheric cutoff to about 7600 A. The observed UV/optical linear polarization displays a strong increase toward shorter wavelengths indicative of scattering by circumstellar dust. The position angle of the intrinsic polarization flips by 90 deg in the near-UV as expected from a bipolar reflection nebula.