BINUCLEAR METAL COMPLEXES. V. TEMPLATE SYNTHESIS OF A BINUCLEAR COPPER(II) COMPLEX OF A MACROCYCLE CONTAINING AMIDO GROUPS

A new binucleating ligand, 2,6-bis (β-aminoethylcarbamoyl)-4-methylphenol was prepared and its copper(II) complex was isolated. By the reaction of this complex and 2,6-diformyl-4-methylphenol, a binuclear copper(II) complex of a new macrocycle, 23,24-dihydroxy-10,21-dimethyl-3,6,14,17-tatraazatricyclo[17,3,1,18,12]tetracosa-1(23),6,8(24),9,11,13,19,21-octaene-2,18-dione, was synthesized.

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