Pyridine-Conjugated Pillar[5]arene: From Molecular Crystals of Blue Luminescence to Red-Emissive Coordination Nanocrystals.

A luminescent molecular crystal (P5bipy) and a Cu(I)-coordinated luminescent nanocrystal (Cu(I)-P5bipy) have been prepared concurrently using one conjugated pillar[5]arene macrocycle via a facile supramolecular self-assembling strategy. The molecular crystal shows enhanced luminescence compared with unmodified pillar[5]arene, attributed to its conjugated structure and staggered packing mode, while the coordination nanocrystal exhibits well-defined crystalline structures and long-lifetime triplet state emission along with pronounced solvochromic features.

[1]  Zheng Li,et al.  Functional Materials with Pillarene Struts , 2021 .

[2]  Mohamad S. Kodaimati,et al.  Recent advances in persistent luminescence based on molecular hybrid materials. , 2021, Chemical Society reviews.

[3]  Dongpeng Yan,et al.  Boosting Wide‐Range Tunable Long‐Afterglow in 1D Metal–Organic Halide Micro/Nanocrystals for Space/Time‐Resolved Information Photonics , 2021, Advanced materials.

[4]  F. Zamora,et al.  Copper(I)-iodide cluster structures as functional and processable platform materials. , 2021, Chemical Society reviews.

[5]  Nan Song,et al.  A stimuli-responsive pillar[5]arene-based hybrid material with enhanced tunable multicolor luminescence and ion-sensing ability , 2020, National science review.

[6]  Ruibing Wang,et al.  Versatile Roles of Macrocycles in Organic-Inorganic Hybrid Materials for Biomedical Applications , 2020 .

[7]  B. Tang,et al.  Pillar[5]arene‐Modified Gold Nanorods as Nanocarriers for Multi‐Modal Imaging‐Guided Synergistic Photodynamic‐Photothermal Therapy , 2020, Advanced Functional Materials.

[8]  Feihe Huang,et al.  Formation of Planar Chiral Platinum Triangles via Pillar[5]arene for Circularly Polarized Luminescence. , 2020, Journal of the American Chemical Society.

[9]  Yingwei Yang,et al.  Pillar[n]arene‐Based Supramolecular Switches in Solution and on Surfaces , 2020, Advanced materials.

[10]  Feihe Huang,et al.  Transformation of Nonporous Adaptive Pillar[4]arene[1]quinone Crystals into Fluorescent Crystals via Multi-Step Solid-Vapor Postsynthetic Modification for Fluorescence Turn-on Sensing of Ethylenediamine. , 2020, Journal of the American Chemical Society.

[11]  Jiarui Wu,et al.  Synthetic Macrocycle‐Based Nonporous Adaptive Crystals for Molecular Separation , 2020, Angewandte Chemie.

[12]  Kecheng Jie,et al.  Vapochromic crystals: understanding vapochromism from the perspective of crystal engineering. , 2020, Chemical Society reviews.

[13]  N. Giuseppone,et al.  From Molecular Machines to Stimuli‐Responsive Materials , 2019, Advanced materials.

[14]  Bao Li,et al.  Separation of Bromoalkanes Isomers by Nonporous Adaptive Crystals of Leaning Pillar[6]arene. , 2019, Angewandte Chemie.

[15]  Dongpeng Yan,et al.  Simultaneous Long-Persistent Blue Luminescence and High Quantum Yield within 2D Organic-Metal Halide Perovskite Micro/Nanosheets. , 2019, Angewandte Chemie.

[16]  P. Weiss,et al.  Organic-Inorganic Hybrid Pillarene-Based Nanomaterial for Label-Free Sensing and Catalysis , 2019, Matter.

[17]  Feihe Huang,et al.  Alkyl Chain Length-Selective Vapor-Induced Fluorochromism of Pillar[5]arene-Based Nonporous Adaptive Crystals. , 2019, Journal of the American Chemical Society.

[18]  Nan Song,et al.  Efficient Aggregation‐Induced Emission Manipulated by Polymer Host Materials , 2019, Advanced materials.

[19]  Jiarui Wu,et al.  Geminiarene: Molecular Scale Dual Selectivity for Chlorobenzene and Chlorocyclohexane Fractionation. , 2019, Journal of the American Chemical Society.

[20]  A. Kobayashi,et al.  Quantitative Solvent-Free Thermal Synthesis of Luminescent Cu(I) Coordination Polymers. , 2019, Inorganic chemistry.

[21]  Yan Wang,et al.  Supramolecular Assembly-Induced Emission Enhancement for Efficient Mercury(II) Detection and Removal. , 2019, Journal of the American Chemical Society.

[22]  T. Ogoshi,et al.  Applications of Pillar[n]arene-Based Supramolecular Assemblies. , 2018, Angewandte Chemie.

[23]  Nan Song,et al.  Molecular-Scale Porous Materials Based on Pillar[n]arenes , 2018, Chem.

[24]  B. Jiang,et al.  Pillar[5]arene–Py–Cu Gel, the First Pillar[5]arene‐Based Metallo(organo)gel, and Adsorption of Sudan III by Its Gel‐Precipitate , 2017 .

[25]  Yoshiaki Nakamoto,et al.  Pillar-Shaped Macrocyclic Hosts Pillar[n]arenes: New Key Players for Supramolecular Chemistry. , 2016, Chemical reviews.

[26]  Song Gao,et al.  Copper(I)-iodide based coordination polymers: bifunctional properties related to thermochromism and PMMA-doped polymer film materials , 2015 .

[27]  Gustavo Fernández,et al.  Strategies to create hierarchical self-assembled structures via cooperative non-covalent interactions. , 2015, Chemical Society reviews.

[28]  Sean Xiao‐An Zhang,et al.  Pillar[5]arene‐Based Supramolecular Organic Frameworks for Highly Selective CO2‐Capture at Ambient Conditions , 2014, Advanced materials.

[29]  Dongpeng Yan,et al.  Molecular crystalline materials with tunable luminescent properties: from polymorphs to multi-component solids , 2014 .

[30]  T. Ogoshi,et al.  Pillararenes: Versatile Synthetic Receptors for Supramolecular Chemistry , 2013 .

[31]  J. F. Stoddart,et al.  Incorporation of an A1/A2-difunctionalized pillar[5]arene into a metal-organic framework. , 2012, Journal of the American Chemical Society.

[32]  Laura Maggini,et al.  Hierarchised luminescent organic architectures: design, synthesis, self-assembly, self-organisation and functions. , 2012, Chemical Society reviews.

[33]  Yoshiaki Nakamoto,et al.  para-Bridged symmetrical pillar[5]arenes: their Lewis acid catalyzed synthesis and host-guest property. , 2008, Journal of the American Chemical Society.

[34]  P. C. Ford,et al.  Photochemical and photophysical properties of tetranuclear and hexanuclear clusters of metals with d10 and s2 electronic configurations , 1993 .