The Use of Visible and Near-Infrared Reflectance Measurements to assess Sensory Changes in Carrot Texture and Sweetness during Heat Treatment

Abstract The use of non-destructive near-infrared reflectance (NIR) measurements to predict the change in sensory quality of carrot discs during heat treatment was investigated. Near-infrared reflectance measurements were performed on five different batches of carrots, cooked for 0, 1, 2, 5, 10, or 15 min, with a spectrophotometer with a wavelength range of 400–2500 nm. Per combination of batch and heat treatment, 20 carrot discs with a height of 8 mm and a diameter of 25 mm were tested. As instrumental reference measurements the dry matter content (DM), soluble solids content (SSC), compressive strength F C and tensile strength F t were recorded on carrots from the same batches and heat treatments. Sensory profiling was carried out on three of the five batches. The sensory attributes considered were hardness, crispness, juiciness, sweet smell, and sweet taste. The shape of the NIR spectra was determined by the water absorption bands and the absorption by carotenoids in the visual light region. Partial least-squares regression (PLSR) was used to predict the average sensory scores for each batch and cooking time from the NIR spectra obtained from individual carrot discs. Second-order derivative pre-processing combined with meancentring, provided a better prediction capability than first-order derivation or multiplicative scatter correction. The root mean square errors of prediction (RMSEP) amounted to 1·13, 1·20, 0·89, 0·78, and 1·06 for hardness, crispness, juiciness, sweet smell and sweet taste, respectively, in sensory units (scale 0 to 15). To obtain the best possible prediction, it appeared to be important to include batch-specific information in the model. Compared with a PLSR model based on the four physico-chemical reference measurements, the NIR model provided a better estimation of hardness, crispness, and sweet smell. Measurements for one batch on xylem and phloem parts of the carrot discs separately, showed that a further improvement of the model calibration could be obtained by taking the NIR spectrum on the phloem part. The average physico-chemical results for a specific batch and heat treatment, could be estimated from a PLSR model based on the NIR spectra, with an average RMSEP of 7–13% of the measurement range under consideration. The results suggest that NIR measurements could be successfully used to control sensory quality during heat treatment.

[1]  C. Wright,et al.  Measurement of firmness in carrot tissue during cooking using dynamic, static and sensory tests , 1992 .

[2]  Cesarettin Alasalvar,et al.  Method for the static headspace analysis of carrot volatiles , 1999 .

[3]  Tom Fearn,et al.  Practical Nir Spectroscopy With Applications in Food and Beverage Analysis , 1993 .

[4]  M. Bourne,et al.  KINETICS OF THERMAL SOFTENING OF VEGETABLES , 1983 .

[5]  K. Norris,et al.  4. Direct Spectrophotometric Determination of Moisture Content of Grain and Seeds , 1996 .

[6]  P. Geladi,et al.  Linearization and Scatter-Correction for Near-Infrared Reflectance Spectra of Meat , 1985 .

[7]  I. Saguy,et al.  EFFECT OF HEAT TREATMENT ON THE QUALITY OF COOKED CARROTS , 1980 .

[8]  M. Bourne Applications of Chemical Kinetic Theory to the Rate of Thermal Softening of Vegetable Tissue , 1989 .

[9]  Pictiaw Chen,et al.  A review of non-destructive methods for quality evaluation and sorting of agricultural products , 1991 .

[10]  R. Bro,et al.  USE OF PHYSICO‐CHEMICAL METHODS FOR ASSESSMENT OF SENSORY CHANGES IN CARROT TEXTURE AND SWEETNESS DURING COOKING , 2002 .

[11]  Rasmus Bro,et al.  The N-way Toolbox for MATLAB , 2000 .

[12]  D. R. Massie,et al.  Spectral Reflectance and Transmittance Properties of Grain in the Visible and Near Infrared , 1965 .

[13]  Harald Martens,et al.  Near-Infrared Reflectance Determination of Sensory Quality of Peas , 1986 .

[14]  W. R. Windham,et al.  Prediction of cooked rice texture quality using near-infrared reflectance analysis of whole-grain milled samples , 1997 .

[15]  T. Durance,et al.  Water Blanching Effects on Headspace Volatiles and Sensory Attributes of Carrots , 1996 .