Emulsion Explosives: A Tutorial Review and Highlight of Recent Progress

Emulsion explosives (EE) have been commercially available in various forms for over 50 years. Over this period, the popularity and production technology of this class of energetic materials have been developing constantly. Despite this rapid rise to prominence and, in some applications, prevalence over traditional energetic materials, remarkably little information is available on the physicochemical and energetic properties of these materials and factors affecting those properties. This work is dedicated to presenting the fundamental information relevant to the features, properties and applications of EEs, while highlighting the most significant recent progress pertaining to those materials. Particular emphasis has been given to providing information about the types, composition, modifications and detonation parameters of EEs, as well as to highlighting the less obvious, emerging applications of EEs.

[1]  Tomasz Jarosz,et al.  Novel Sensitizing Agent Formulation for Bulk Emulsion Explosives with Improved Energetic Parameters , 2022, Materials.

[2]  Bartlomiej Kramarczyk,et al.  Study of the Influence of Sensitizer Content on the Density of a Bulk Emulsion Explosive Used in Underground Operations , 2021, Central European Journal of Energetic Materials.

[3]  S. Stankovic,et al.  Prediction of concentration of toxic gases produced by detonation of commercial explosives by thermochemical equilibrium calculations , 2021, Defence Technology.

[4]  Hai-Rong Zhao,et al.  Advances in the rheology of emulsion explosive , 2021, Journal of Molecular Liquids.

[5]  M. Zhao,et al.  The effect of surfactant on the rheology and stability properties of emulsion explosive matrices , 2021, Journal of Dispersion Science and Technology.

[6]  N. Jiang,et al.  Safety assessment of buried gas pipeline subject to surface explosion: A case study in Wuhan, China , 2021 .

[7]  Mateusz Pytlik,et al.  Effect of aluminium additives on selected detonation parameters of a bulk emulsion explosive , 2020 .

[8]  L. Cristofolini,et al.  Emulsification and emulsion stability: The role of the interfacial properties. , 2020, Advances in colloid and interface science.

[9]  B. D. Le,et al.  Modeling the fracture behavior of Ultra - High Performance Fiber Reinforced Concrete slabs under contact Blast Loading , 2020, IOP Conference Series: Materials Science and Engineering.

[10]  Mateusz Pytlik,et al.  The influence of temperature on the detonation velocity of selected emulsion explosives , 2020 .

[11]  S. Jagtap,et al.  Metal-oxide semiconductors for carbon monoxide (CO) gas sensing: A review , 2020 .

[12]  R. Sinha,et al.  Prediction of Ground Vibration Induced Due to Single Hole Blast Using Explicit Dynamics , 2020 .

[13]  Mateusz Pytlik,et al.  The Influence of Time on the Density and Detonation Velocity of Bulk Emulsion Explosives – a Case Study from Polish Copper Mines , 2019, Central European Journal of Energetic Materials.

[14]  Jing Zhu,et al.  Thermal behavior and stability of emulsion explosives in the presence of ferrous ion , 2019, Journal of Thermal Analysis and Calorimetry.

[15]  Ariffin Ismail,et al.  Characteristics of Iron powder when Pressed using Explosive Pressing method , 2018, IOP Conference Series: Materials Science and Engineering.

[16]  D. Geneva Agreement Concerning the International Carriage of Dangerous Goods by Road (ADR) , 2018, European Agreement Concerning the International Carriage of Dangerous Goods by Road (ADR).

[17]  A. Nour Emulsion Types, Stability Mechanisms and Rheology: A Review , 2018, International Journal of Innovative Research and Scientific Studies.

[18]  Honghao Ma,et al.  Detonation Characteristics of Emulsion Explosives Sensitized by Hydrogen-Storage Glass Microballoons , 2018, Propellants, Explosives, Pyrotechnics.

[19]  Bartlomiej Kramarczyk,et al.  The Impact of Time on the Detonation Capacity of Bulk Emulsion Explosives based on Emulinit 8L , 2018, Propellants, Explosives, Pyrotechnics.

[20]  Bartlomiej Kramarczyk,et al.  Influence of Explosive Charge Diameter on the Detonation Velocity Based on Emulinit 7L and 8L Bulk Emulsion Explosives , 2018, Central European Journal of Energetic Materials.

[21]  V. Kiselev,et al.  Use of Emulsion Explosives in Experimental Studies of Flows in the Bonding Zone in Explosive Welding , 2018 .

[22]  V. Lyashenko,et al.  Improving the efficiency of blasting operations in mines with the help of emulsion explosives , 2018 .

[23]  Deepanshu R. Singh,et al.  Influence of Gassing Agent and Density on Detonation Velocity of Bulk Emulsion Explosives , 2018, Geotechnical and Geological Engineering.

[24]  A. Mishra,et al.  A Study on Influence of Density and Viscosity of Emulsion Explosive on Its Detonation Velocity , 2017 .

[25]  M. Mishrif,et al.  Preparation and investigation of emulsion explosive matrix based on gas oil for mining process , 2017 .

[26]  Honghao Ma,et al.  The Effect of the Hydrogen Containing Material TiH2 on the Detonation Characteristics of Emulsion Explosives , 2017 .

[27]  Xuguang Wang,et al.  Crystallization of interphase droplets in emulsion explosive matrices , 2017 .

[28]  V. Sil’vestrov,et al.  Influence of artificial pores on the detonation parameters of an emulsion explosive , 2017 .

[29]  Jeongsoo Nam,et al.  Experimental Investigation on the Blast Resistance of Fiber-Reinforced Cementitious Composite Panels Subjected to Contact Explosions , 2017 .

[30]  Daniel Ainalis,et al.  Modelling the Source of Blasting for the Numerical Simulation of Blast-Induced Ground Vibrations: A Review , 2017, Rock Mechanics and Rock Engineering.

[31]  V. Kiselev,et al.  Enhancement of Explosive Welding Possibilities by the Use of Emulsion Explosive/ Rozwój Mozliwości Łączenia Wybuchowego Przez Użycie Emulsji Wybuchowych , 2014 .

[32]  J. Ribeiro,et al.  Differences between the detonation behavior of emulsion explosives sensitized with glass or with polymeric micro-balloons , 2014 .

[33]  Bogdan Z. Dlugogorski,et al.  Trapping of Nitric Oxide, Generated during Sensitization of Ammonium Nitrate Emulsion Explosive, by Aromatic Nitroso Sulfonates , 2013 .

[34]  M. Pradhan Sleep time: Its consequences on performance of bulk emulsion explosive , 2010 .

[35]  V. Sil’vestrov,et al.  Critical diameter and critical thickness of an emulsion explosive , 2008 .

[36]  A. Malkin,et al.  Evolution of rheological properties of highly concentrated emulsions with aging —Emulsion-to-suspension transition , 2006 .

[37]  Bogdan Z. Dlugogorski,et al.  Water-in-oil emulsion foaming by thiourea nitrosation: Reaction and mass transfer , 2006 .

[38]  A. Anshits,et al.  Detonation Velocity of Emulsion Explosives Containing Cenospheres , 2005 .

[39]  H. Delalu,et al.  Elaboration of High-grade Chloramine from Ternary and Quaternary Ammoniacal Combinations and Hypochlorite at 100 Chlorometric Degrees , 1999 .

[40]  永瀬 淳,et al.  Method for producing a water-in-oil emulsion explosive composition , 1998 .

[41]  P. Dhekne,et al.  FIELD INVESTIGATION IN THE DETONATION BEHAVIOR OF EMULSION EXPLOSIVE COLUMN INDUCED WITH AIR GAPS , 2019, Mining Scince.

[42]  Gennady N. Bogomolov,et al.  Research destruction ice under dynamic loading. Part 1. Modeling explosive ice cover into account the temperature , 2017 .

[43]  Y. Ogata by emulsion explosive , 2017 .

[44]  U. Nyberg,et al.  Short time measurements of toxic fumes from detonation of emulsion explosive : Initial tests in blast chamber , 2015 .

[45]  A. Maranda,et al.  Aluminum Powder Infuence on ANFO Detonation Parameters , 2011 .

[46]  K. Murata,et al.  DETONATION CHARACTERISTICS OF EMULSION EXPLOSIVES AS FUNCTIONS OF VOID SIZE AND VOLUME , 2002 .

[47]  J. Beckman,et al.  The comparative toxicity of nitric oxide and peroxynitrite to Escherichia coli. , 1995, Archives of biochemistry and biophysics.