Inkjet Printed Large Area Multifunctional Smart Windows

Multifunctional smart windows are successfully fabricated by assembling inkjet printed CeO2/TiO2 and WO3/poly(3,4-ethylenedioxythiophene)-poly(styrene sulfonate) films as the anode and cathode, respectively. Large optical modulation (more than 70% at 633 nm), fast switching (12.7/15.8 s), high coloration efficiency (108.9 cm2 C−1), and excellent bistability are achieved by the assembled smart windows. The multifunctional smart window not only can be used as typical electrochromic window, which can change its color to dynamically control the solar radiation transmittance through windows or protect privacy during the day, but also can be used as energy-storage device simultaneously. The designed smart window releases the stored energy to light the bulbs and power other electronic devices at night while its color gradually reverts to transparent state. Moreover, the level of stored energy can be monitored via the visually detectable reversible color variation of the window. The fascinating multifunctional smart windows exhibit promising features for a wide range of applications in buildings, airplanes, automobiles, etc.

[1]  S. Samdarshi,et al.  A novel thermophotocatalyst of mixed-phase cerium oxide (CeO2/Ce2O3) homocomposite nanostructure: Role of interface and oxygen vacancies , 2015 .

[2]  Wenjie Mai,et al.  Flexible solid-state electrochemical supercapacitors , 2014 .

[3]  Zhigang Zhao,et al.  Single‐Crystalline Tungsten Oxide Quantum Dots for Fast Pseudocapacitor and Electrochromic Applications , 2014, Advanced materials.

[4]  Zhigang Zhao,et al.  Synergy of W18O49 and polyaniline for smart supercapacitor electrode integrated with energy level indicating functionality. , 2014, Nano letters.

[5]  Guofa Cai,et al.  The direct growth of a WO3 nanosheet array on a transparent conducting substrate for highly efficient electrochromic and electrocatalytic applications , 2014 .

[6]  Guofa Cai,et al.  Inkjet-printed all solid-state electrochromic devices based on NiO/WO3 nanoparticle complementary electrodes. , 2016, Nanoscale.

[7]  S. A. Agnihotry,et al.  Sol–gel derived nanocrystalline CeO2–TiO2 coatings for electrochromic windows , 2005 .

[8]  Guofa Cai,et al.  Ultra-large optical modulation of electrochromic porous WO3 film and the local monitoring of redox activity , 2015, Chemical science.

[9]  Guofa Cai,et al.  Hierarchical structure Ti-doped WO3 film with improved electrochromism in visible-infrared region , 2013 .

[10]  Guofa Cai,et al.  Efficient electrochromic materials based on TiO2@WO3 core/shell nanorod arrays , 2013 .

[11]  Huisheng Peng,et al.  Smart, Stretchable Supercapacitors , 2014, Advanced materials.

[12]  M. Desai,et al.  Studies of ZrO2 electrolyte thin-film thickness on the all-solid thin-film electrochromic devices , 2014, Journal of Solid State Electrochemistry.

[13]  Jongbeom Na,et al.  Energy saving electrochromic windows from bistable low-HOMO level conjugated polymers , 2016 .

[14]  S. A. Agnihotry,et al.  Sol-gel processed nanostructured CeO2–TiO2 thin films for electrochromic applications , 2005 .

[15]  S. Hong,et al.  Influence of calcination temperature on Ce/TiO2 catalysis of selective catalytic oxidation of NH3 to N2 , 2014 .

[16]  Jing Xu,et al.  Integrated smart electrochromic windows for energy saving and storage applications. , 2014, Chemical communications.

[17]  Pooi See Lee,et al.  Next-Generation Multifunctional Electrochromic Devices. , 2016, Accounts of chemical research.

[18]  Yu Zhong,et al.  Perovskite solar cell powered electrochromic batteries for smart windows , 2016 .

[19]  Carlos B. Pinheiro,et al.  Inkjet printing of sol-gel synthesized hydrated tungsten oxide nanoparticles for flexible electrochromic devices. , 2012, ACS applied materials & interfaces.

[20]  Pooi See Lee,et al.  “Nano to nano” electrodeposition of WO3 crystalline nanoparticles for electrochromic coatings , 2014 .

[21]  Hyoyoung Lee,et al.  An Electrolyte‐Free Flexible Electrochromic Device Using Electrostatically Strong Graphene Quantum Dot–Viologen Nanocomposites , 2014, Advanced materials.

[22]  Xiang Cai,et al.  Large-scale fabrication of pseudocapacitive glass windows that combine electrochromism and energy storage. , 2014, Angewandte Chemie.

[23]  Rui-Tao Wen,et al.  Eliminating degradation and uncovering ion-trapping dynamics in electrochromic WO3 thin films , 2015, Nature materials.

[24]  Sreekumar Kurungot,et al.  Novel scalable synthesis of highly conducting and robust PEDOT paper for a high performance flexible solid supercapacitor , 2015 .

[25]  S. A. Agnihotry,et al.  Optimization of CeO2–TiO2 composition for fast switching kinetics and improved Li ion storage capacity , 2004 .

[26]  Zhixiang Wei,et al.  Integrated energy storage and electrochromic function in one flexible device: an energy storage smart window , 2012 .

[27]  Yang Wang,et al.  Linear topology in amorphous metal oxide electrochromic networks obtained via low-temperature solution processing. , 2016, Nature materials.

[28]  Luis Pérez-Lombard,et al.  A review on buildings energy consumption information , 2008 .

[29]  Udo Lang,et al.  Microscopical Investigations of PEDOT:PSS Thin Films , 2009 .

[30]  Wenjie Mai,et al.  Flexible electrochromic supercapacitor hybrid electrodes based on tungsten oxide films and silver nanowires. , 2016, Chemical communications.

[31]  J. Hrbek,et al.  Activity of CeOx and TiOx Nanoparticles Grown on Au(111) in the Water-Gas Shift Reaction , 2007, Science.

[32]  Xiao Wei Sun,et al.  A bi-functional device for self-powered electrochromic window and self-rechargeable transparent battery applications , 2014, Nature Communications.

[33]  A. Pawlicka,et al.  Preparation of transparent CeO2–TiO2 coatings for electrochromic devices , 1998 .

[34]  Xuehong Lu,et al.  One-pot sequential electrochemical deposition of multilayer poly(3,4-ethylenedioxythiophene):poly(4-styrenesulfonic acid)/tungsten trioxide hybrid films and their enhanced electrochromic properties , 2014 .

[35]  C. Granqvist Electrochromics for smart windows: Oxide-based thin films and devices , 2014 .

[36]  M. Deepa,et al.  A poly(3,4-ethylenedioxypyrrole)-Au@WO3 -based electrochromic pseudocapacitor. , 2015, Chemphyschem : a European journal of chemical physics and physical chemistry.

[37]  Kamaruzzaman Sopian,et al.  The role of window glazing on daylighting and energy saving in buildings , 2015 .

[38]  Jian-Chiun Liou,et al.  Self-powered smart window controlled by a high open-circuit voltage InGaN/GaN multiple quantum well solar cell. , 2015, Chemical communications.

[39]  Guofa Cai,et al.  Highly Stable Transparent Conductive Silver Grid/PEDOT:PSS Electrodes for Integrated Bifunctional Flexible Electrochromic Supercapacitors , 2016 .

[40]  G. Thornton,et al.  Satellite structure in the X-ray photoelectron spectra of some binary and mixed oxides of lanthanum and cerium , 1976 .

[41]  Guofa Cai,et al.  Electrochromo-supercapacitor based on direct growth of NiO nanoparticles , 2015 .

[42]  Linen Wu,et al.  Facile synthesis of CeO2 hollow structures with controllable morphology by template-engaged etching of Cu2O and their visible light photocatalytic performance , 2015 .

[43]  Wenjie Mai,et al.  Electrochromic energy storage devices , 2016 .

[44]  W. Mai,et al.  Nickel oxide nanoflake-based bifunctional glass electrodes with superior cyclic stability for energy storage and electrochromic applications , 2015 .

[45]  J. Tu,et al.  Bi-functional Mo-doped WO3 nanowire array electrochromism-plus electrochemical energy storage. , 2016, Journal of colloid and interface science.

[46]  Guofa Cai,et al.  Growth of vertically aligned hierarchical WO3 nano-architecture arrays on transparent conducting substrates with outstanding electrochromic performance , 2014 .

[47]  G. Ingo,et al.  Thermal and surface characterizations of 25.5 (wt.%) CeO2–2.5 Y2O3–72 ZrO2 fine powder , 1992 .

[48]  Hongzhi Wang,et al.  Hierarchical NiO microflake films with high coloration efficiency, cyclic stability and low power consumption for applications in a complementary electrochromic device. , 2013, Nanoscale.

[49]  Daniel Mandler,et al.  Nanostructured electrochromic films by inkjet printing on large area and flexible transparent silver electrodes. , 2014, Nanoscale.

[50]  J. Tu,et al.  An all-solid-state electrochromic device based on NiO/WO3 complementary structure and solid hybrid polyelectrolyte , 2009 .

[51]  Ataullah Khan,et al.  Structural Characterization of CeO2−TiO2 and V2O5/CeO2−TiO2 Catalysts by Raman and XPS Techniques , 2003 .

[52]  K. Abdelhady,et al.  Gelatin-based solid electrolyte releasing Li+ for smart window applications ☆ , 2014 .

[53]  Delia J. Milliron,et al.  Tunable near-infrared and visible-light transmittance in nanocrystal-in-glass composites , 2013, Nature.

[54]  Zhong Lin Wang,et al.  A self-powered electrochromic device driven by a nanogenerator , 2012 .

[55]  Guofa Cai,et al.  Constructed TiO2/NiO Core/Shell Nanorod Array for Efficient Electrochromic Application , 2014 .

[56]  Zhiping Luo,et al.  Electropolymerized Polyaniline Stabilized Tungsten Oxide Nanocomposite Films: Electrochromic Behavior and Electrochemical Energy Storage , 2012 .

[57]  K. Ho,et al.  Highly conductive PEDOT:PSS electrode by simple film treatment with methanol for ITO-free polymer solar cells , 2012 .

[58]  C. Song,et al.  Characterization of Structural and Surface Properties of Nanocrystalline TiO2−CeO2 Mixed Oxides by XRD, XPS, TPR, and TPD , 2009 .

[59]  Piers Andrew,et al.  A nanostructured electrochromic supercapacitor. , 2012, Nano letters.

[60]  Min Wei,et al.  Ultrafast switching of an electrochromic device based on layered double hydroxide/Prussian blue multilayered films. , 2015, Nanoscale.

[61]  Yang Wang,et al.  Nanocomposite Architecture for Rapid, Spectrally-Selective Electrochromic Modulation of Solar Transmittance. , 2015, Nano letters.