Ion beam synthesis of nanothermochromic diffraction gratings with giant switching contrast at telecom wavelengths

Nanothermochromic diffraction gratings based on the metal-insulator transition of VO2 are fabricated by site-selective ion beam implantation in a SiO2 matrix. Gratings were defined either (i) directly by spatially selective ion beam synthesis or (ii) by site-selective deactivation of the phase transition by ion beam induced defects. The strongest increase of the diffracted light intensities was observed at a wavelength of 1550 nm exceeding a factor of 20 for the selectively deactivated gratings. The observed pronounced thermal hysteresis extending down close to room temperature makes this system ideally suited for optical memory applications.

[1]  Richard F. Haglund,et al.  Synthesis and characterization of size-controlled vanadium dioxide nanocrystals in a fused silica matrix , 2002 .

[2]  J C Grossman,et al.  Strain engineering and one-dimensional organization of metal-insulator domains in single-crystal vanadium dioxide beams. , 2009, Nature nanotechnology.

[3]  Byung-Gyu Chae,et al.  Memory Metamaterials , 2009, Science.

[4]  T. E. Haynes,et al.  Switchable reflectivity on silicon from a composite VO2-SiO2 protecting layer , 2004 .

[5]  S. Tanemura,et al.  Optical constants of V(1-x)W(x)O(2) Films. , 1998, Applied optics.

[6]  Qingxin Zhang,et al.  An Electrically Tuned Solid‐State Thermal Memory Based on Metal–Insulator Transition of Single‐Crystalline VO2 Nanobeams , 2011 .

[7]  Zhao Hao,et al.  Intrinsic optical properties of vanadium dioxide near the insulator-metal transition. , 2011, Nano letters.

[8]  Harry A Atwater,et al.  Compact silicon photonic waveguide modulator based on the vanadium dioxide metal-insulator phase transition. , 2010, Optics express.

[9]  T. E. Haynes,et al.  Enhanced hysteresis in the semiconductor-to-metal phase transition of VO2 precipitates formed in SiO2 by ion implantation , 2001 .

[10]  F. J. Morin,et al.  Oxides Which Show a Metal-to-Insulator Transition at the Neel Temperature , 1959 .

[11]  C. N. Berglund,et al.  Optical Properties of V O 2 between 0.25 and 5 eV , 1968 .

[12]  Hongkun Park,et al.  Strain-induced self organization of metal-insulator domains in single-crystalline VO2 nanobeams. , 2006, Nano letters.

[13]  J. C. Kieffer,et al.  Evidence for a structurally-driven insulator-to-metal transition in VO 2 : A view from the ultrafast timescale , 2004, cond-mat/0403214.

[14]  H. F. Taylor,et al.  Fiber optic application for thermal switching in vanadium dioxide films. , 1989, Applied optics.

[15]  Claes-Göran Granqvist,et al.  Nanothermochromics: Calculations for VO2 nanoparticles in dielectric hosts show much improved luminous transmittance and solar energy transmittance modulation , 2010 .

[16]  Richard F. Haglund,et al.  Modulated optical transmission of subwavelength hole arrays in metal-VO2 films , 2006 .

[17]  Sarbajit Banerjee,et al.  Microscopic and Nanoscale Perspective of the Metal−Insulator Phase Transitions of VO2: Some New Twists to an Old Tale , 2011 .

[18]  S. Ramanathan,et al.  Oxide Electronics Utilizing Ultrafast Metal-Insulator Transitions , 2011 .

[19]  W. R. Roach Holographic Storage in VO2 , 1971 .

[20]  Wei Chen,et al.  New aspects of the metal-insulator transition in single-domain vanadium dioxide nanobeams. , 2009, Nature nanotechnology.

[21]  Matteo Rini,et al.  Photoinduced phase transition in VO2 nanocrystals: ultrafast control of surface-plasmon resonance. , 2004, Optics letters.