Di--phenylmethanethiolato--sulfido-bis[carbonyl(? 5 -cyclopentadienyl)molybdenum(III)]
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The reaction of bis[cyclopentadienyltricarbonylmolybdenum(I)] with dibenzyl trisulfide affords the title compound, [Mo2S(C5H5)2(C7H7S)2(CO)2], as one of the products. Three independent molecules exist in the asymmetric unit of the triclinic unit cell; one is related to another by a false inversion center and is related to the third by a false translation. In each dinuclear entity, each Mo atom is bonded to a cyclopentadienyl anion and a carbon monoxide molecule; the phenylmethanethiolate groups bridge a pair of Mo atoms, as does the sulfide atom.