The properties and applications of amperometric gas sensors

The properties and applications of amperometric gas sensors are reviewed. An introductory discussion of the general mechanism of electrochemical gas reactions and an outline of the construction of amperometric gas sensors is presented. The performance of sensors and the relationship of the sensor's performance to the materials of construction and sensor components are described. The analytical characteristics of a sensor such as sensitivity, selectivity, response time and noise are intimately related to the materials chosen for membranes, conductive electrolytes, and active electrocatalysts, as well as the choice of effective operating conditions. The applications of amperometric gas sensors to specific analytical problems are discussed in the context of required performance. Finally, this article points out technical gaps and the future direction of amperometric gas sensor research including some potential applications. References that are relevant to the field of amperometric gas sensors are summarized in a table which contains the author's name, the electrochemical reaction, and an exemplary application.

[1]  Joseph R. Stetter,et al.  Electrochemical NO2 gas sensors: Model and mechanism for the electroreduction of NO2 , 1990 .

[2]  A. Sammells,et al.  Ambient Temperature Gas Phase CO 2 Reduction to Hydrocarbons at Solid Polymer Electrolyte Cells , 1988 .

[3]  J. Stetter,et al.  Electrochemical gas chromatographic detection of hydrogen sulfide at PPM and PPB levels. , 1977, Journal of Chromatographic Science.

[4]  P. Gifford,et al.  Pneumatoamperometric determination of parts-per-billion dissolved species by gas evolving reactions , 1980 .

[5]  D. Gough,et al.  Two-dimensional enzyme electrode sensor for glucose. , 1985, Analytical chemistry.

[6]  D. Gough,et al.  Long-term in vitro operation of enzyme electrode-based glucose sensors , 1987 .

[7]  C. Hahn,et al.  A sandwich electrode for multi-gas analysis: a prototype. , 1982, British journal of anaesthesia.

[8]  G. S. Wilson,et al.  Biosensors : fundamentals and applications , 1987 .

[9]  P. Gifford,et al.  Separation and determination of volatile hydrides by gas chromatography with a gold gas-porous electrode detector , 1980 .

[10]  A. Parusiński A generalization of the Milnor number , 1988 .

[11]  J. Stetter,et al.  Gas sensor and permeation apparatus for the determination of chlorinated hydrocarbons in water , 1990 .

[12]  E. Watanabe,et al.  Simultaneous determination of hypoxanthine and inosine with an enzyme sensor , 1986 .

[13]  An integrated amperometric microsensor , 1990 .

[14]  C. Hahn Techniques for measuring the partial pressures of gases in the blood. Part II- in vivo measurements. , 1980, Journal of physics E: Scientific instruments.

[15]  Y. Yamasaki,et al.  Telemetry Glucose Monitoring Device With Needle-Type Glucose Sensor: A Useful Tool for Blood Glucose Monitoring in Diabetic Individuals , 1986, Diabetes Care.

[16]  R. A. Saunders,et al.  Electrochemical determination of hydrazine and methyl- and 1,1-dimethylhydrazine in air. , 1979, Talanta.

[17]  Improved Blood Compatibility at a Glucose Enzyme Electrode Used for Ejctraoorpokeal Monitoring , 1986 .

[18]  S. Bruckenstein,et al.  Pneumatoamperometric determination of nanogram amounts of cyanide , 1980 .

[19]  D. Tallman,et al.  Kel-F-graphite composite electrode as an electrochemical detector for liquid chromatography and application to phenolic compounds , 1981 .

[20]  D. Margineanu,et al.  Kinetic model of amperometric selective electrodes with immobilized bacteria , 1986 .

[21]  K. Blurton,et al.  The Electro‐Oxidation of Carbon Monoxide on Platinum , 1974 .

[22]  B. Danielsson,et al.  A Biosensor for ADP with Internal Substrate Amplification , 1987 .

[23]  D. Gough,et al.  Transient response of an enzyme electrode sensor for glucose. , 1987, Analytical chemistry.

[24]  M. A. Rahni,et al.  Immobilized enzyme electrode for the determination of salicylate in blood serum , 1986 .

[25]  J. R. Stetter,et al.  A dynamic coulometric technique for gas analysis , 1983 .

[26]  Tetsuichi Kudo,et al.  Carbon monoxide gas sensor made of stabilized zirconia , 1980 .

[27]  M. M. Benedetti,et al.  Lactate and pyruvate electrochemical biosensors for whole blood in extracorporeal experiments with an endocrine artificial pancreas. , 1987, Clinical chemistry.

[28]  M. Massi-Benedetti,et al.  An L-lactate sensor with immobilized enzyme for use in in vivo studies with an endocrine artificial pancreas. , 1985, Clinical chemistry.

[29]  A. Sammells,et al.  Electrochemical reduction of carbon dioxide to methane at high current densities , 1987 .

[30]  P. Vadgama,et al.  Enzyme electrode for the measurement of lactate in undiluted blood. , 1986, Clinica chimica acta; international journal of clinical chemistry.

[31]  S. Brummer,et al.  Surface Oxidation of Gold Electrodes , 1964 .

[32]  Joseph R. Stetter,et al.  A chemical concentration modulation sensor for selective detection of airborne chemicals , 1987 .

[33]  A. Sammells,et al.  Efficient High Rate Carbon Dioxide Reduction to Methane and Ethylene at in situ Electrodeposited Copper Electrode , 1987 .

[34]  A. Finazzi-Agro’,et al.  Determination of ascorbic acid with immobilized green zucchini ascorbate oxidase. , 1985, Analytical biochemistry.

[35]  D. L. Short,et al.  Fundamentals of Clark membrane configuration oxygen sensors: some confusion clarified , 1984 .

[36]  J. Lankelma,et al.  Design and characterization of a coulometric detector with a glassy carbon electrode for high-performance liquid chromatography , 1976 .

[37]  W. J. Albery,et al.  A mebrane electrode for the determination of CO2 and O2 , 1982 .

[38]  D. M. Morgan,et al.  Noise and signal-to-noise ratio in electrochemical detectors. , 1984, Analytical chemistry.

[39]  A. Laconti,et al.  Electrochemical Detection of H2, CO, and Hydrocarbons in Inert or Oxygen Atmospheres , 1971 .

[40]  F. Opekar Analytical applications of metallized membrane electrodes , 1989 .

[41]  J. R. Stetter,et al.  Determination of carbon monoxide in air by dynamic coulometry , 1983 .

[42]  K. Blurton,et al.  Electrochemical technique for the measurement of carbon monoxide. , 1974, Analytical chemistry.

[43]  W. Heineman,et al.  Laboratory techniques in electroanalytical chemistry , 1984 .

[44]  Joseph R. Stetter,et al.  Use of time-dependent chemical sensor signals for selective identification , 1989 .

[45]  Joseph R. Stetter,et al.  A room-temperature electrochemical sensor and instrument for monitoring methane , 1985 .

[46]  K. Blurton,et al.  A new electrochemical analyser for nitric oxide and nitrogen dioxide. , 1976, Talanta.

[47]  Robin F. B. Turner,et al.  A CMOS potentiostat for amperometric chemical sensors , 1987 .

[48]  G. Guilbault,et al.  Immobilized enzyme electrode for the determination of oxalate in urine. , 1986, Analytical chemistry.

[49]  P. Hale,et al.  Amperometric glycolate sensors based on glycolate oxidase and polymeric electron transfer mediators , 1990 .

[50]  J. Stetter,et al.  Electrochemical Oxidation of Methane in Nonaqueous Electrolytes at Room Temperature Application to Gas Sensors , 1985 .

[51]  K. Blurton,et al.  Electrochemical determination of hydrogen sulphide in air. , 1976, Talanta.

[52]  Performance and modeling of oxygen probe for glucose analysis , 1985 .

[53]  Joseph R. Stetter,et al.  Microfabricated amperometric gas sensors , 1988 .

[54]  A. F. Bugakov Installing laboratories in two-axle trailers , 1959 .

[55]  Fumio Mizutani,et al.  An enzyme electrode forl-lactate with a chemically-amplified response , 1985 .

[56]  J. Stetter,et al.  Sensitive electrochemical detector for gas chromatography , 1978 .

[57]  John Evans,et al.  Amperometric sensor for carbon dioxide: design, characteristics, and performance , 1989 .

[58]  K. Blurton,et al.  Electrochemical Measurements of Blood Alcohol Levels , 1972, Nature.

[59]  G. Bélanger Determination of sulfur dioxide by anodic oxidation on lead dioxide electrodes. , 1974, Analytical chemistry.

[60]  H. Poppe,et al.  Noise and Drift Phenomena in Amperometric and Coulometric Detectors for HPLC and FIA , 1983 .