Carbon nanotube-based organic light emitting diodes.

Carbon nanotubes; revolutionary and fascinating from the materials point of view and exceedingly sensational from a research point of view; are standing today at the threshold between inorganic electronics and organic electronics and posing a serious challenge to the big daddies of these two domains in electronics i.e., silicon and indium tin oxide (ITO). In the field of inorganic electronics, carbon nanotubes offer advantages such as high current carrying capacity, ballistic transport, absence of dangling bonds, etc. and on the other hand, in the field of organic electronics, carbon nanotubes offer advantages such as high conductivity, high carrier mobility, optical transparency (in visible and IR spectral ranges), flexibility, robustness, environmental resistance, etc. and hence, they are seriously being considered as contenders to silicon and ITO. This review traces the origin of carbon nanotubes in the field of organic electronics (with emphasis on organic light emitting diodes) and moves on to cover the latest advances in the field of carbon nanotube-based organic light emitting diodes. Topics that are covered within include applications of multi-wall nanotubes and single-wall nanotubes in organic light emitting diodes. Applications of carbon nanotubes as hole-transport layers, as electron-transport layers, as transparent electrodes, etc. in organic light emitting diodes are discussed and the daunting challenges facing this progressive field today are brought into the limelight.

[1]  M. Chhowalla Transparent and conducting SWNT thin films for flexible electronics , 2007 .

[2]  Garry Rumbles,et al.  Organic solar cells with carbon nanotubes replacing In2O3:Sn as the transparent electrode , 2006 .

[3]  H. Stone,et al.  Dip coating for the alignment of carbon nanotubes on curved surfaces , 2004 .

[4]  M. Cardinali,et al.  Solution casting of transparent and conductive carbon nanotubes/poly(3,4-ethylenedioxythiophene)–poly(styrenesulfonate) films under a magnetic field , 2008 .

[5]  Enhanced brightness in organic light-emitting diodes using a carbon nanotube composite as an electron-transport layer , 2001 .

[6]  T. Klapwijk,et al.  Indium contamination from the indium–tin–oxide electrode in polymer light‐emitting diodes , 1996 .

[7]  Anthony J. Miller,et al.  Carbon nanotubes: a multi-functional material for organic optoelectronics , 2008 .

[8]  M. Prato,et al.  Separation of metallic and semiconducting single-walled carbon nanotubes via covalent functionalization. , 2007, Small.

[9]  H. Dai,et al.  Individual single-wall carbon nanotubes as quantum wires , 1997, Nature.

[10]  X. Tao,et al.  Improvement in performance of organic light-emitting devices by inclusion of multi-wall carbon nanotubes , 2007 .

[11]  W. D. de Heer,et al.  Carbon Nanotubes--the Route Toward Applications , 2002, Science.

[12]  Dong Young Kim,et al.  Flexible transparent conducting single-wall carbon nanotube film with network bridging method. , 2008, Journal of colloid and interface science.

[13]  R. Friend,et al.  Electronic interaction between photoexcited poly(p-phenylene vinylene) and carbon nanotubes , 2000 .

[14]  Franco Cacialli,et al.  Workfunction of purified and oxidised carbon nanotubes , 1999 .

[15]  Ricardo Izquierdo,et al.  Carbon nanotube sheets as electrodes in organic light-emitting diodes. , 2006 .

[16]  Munson-McGee,et al.  Estimation of the critical concentration in an anisotropic percolation network. , 1991, Physical review. B, Condensed matter.

[17]  Young Hee Lee,et al.  Effect of acid treatment on carbon nanotube-based flexible transparent conducting films. , 2007, Journal of the American Chemical Society.

[18]  W. F. Peck,et al.  Transparent conducting thin films of GaInO3 , 1994 .

[19]  D. Shin,et al.  Smooth, transparent, conducting and flexible SWCNT films by filtration–wet transfer processes , 2009 .

[20]  M. Pasquali,et al.  Continuous and scalable fabrication of transparent conducting carbon nanotube films. , 2009, ACS nano.

[21]  Minquan Tian,et al.  Semiconductor Carbon Nanotubes as Ultrafast Switching Materials for Optical Telecommunications , 2003 .

[22]  K A Stelson,et al.  Carbon nanotube based transparent conductive thin films. , 2006, Journal of nanoscience and nanotechnology.

[23]  J. C. Scott,et al.  Degradation and failure of MEH‐PPV light‐emitting diodes , 1996 .

[24]  Franco Cacialli,et al.  Work Functions and Surface Functional Groups of Multiwall Carbon Nanotubes , 1999 .

[25]  A. P. Davey,et al.  Optical Absorption and Fluorescence of a Multi-walled Nanotube-Polymer Composite , 1999 .

[26]  R. Krupke,et al.  Separation of Metallic from Semiconducting Single-Walled Carbon Nanotubes , 2003, Science.

[27]  D. Milliron,et al.  Surface oxidation activates indium tin oxide for hole injection , 2000 .

[28]  Bernard Kippelen,et al.  Stability of Doped Transparent Carbon Nanotube Electrodes , 2008 .

[29]  Werner J. Blau,et al.  Percolation-dominated conductivity in a conjugated-polymer-carbon-nanotube composite , 1998 .

[30]  Jijun Zhao,et al.  Work functions of pristine and alkali-metal intercalated carbon nanotubes and bundles , 2001, cond-mat/0111103.

[31]  Jong-Ho Choi,et al.  Characterization of light emitting devices based on a single-walled carbon nanotube–polymer composite , 2003 .

[32]  Dae Sik Lee,et al.  DEPENDENCE OF MATERIAL QUALITY ON PERFORMANCE OF FLEXIBLE TRANSPARENT CONDUCTING FILMS WITH SINGLE-WALLED CARBON NANOTUBES , 2007 .

[33]  R. Rajamani,et al.  Fabrication of carbon nanotube based transparent conductive thin films using layer-by-layer technology , 2008 .

[34]  John R. Reynolds,et al.  Transparent, Conductive Carbon Nanotube Films , 2004, Science.

[35]  Werner J. Blau,et al.  Experimental observation of scaling laws for alternating current and direct current conductivity in polymer-carbon nanotube composite thin films , 2002 .

[36]  Weihong Zhu,et al.  Langmuir–Blodgett Films of Single-Wall Carbon Nanotubes: Layer-by-layer Deposition and In-plane Orientation of Tubes , 2003 .

[37]  Liangbing Hu,et al.  A method of printing carbon nanotube thin films , 2006 .

[38]  S. Ravi P. Silva,et al.  Interpenetrating multiwall carbon nanotube electrodes for organic solar cells , 2006 .

[39]  B. Hsieh,et al.  Work function of indium tin oxide transparent conductor measured by photoelectron spectroscopy , 1996 .

[40]  H. Okamoto,et al.  Large Optical Nonlinearity of Semiconducting Single-walled Carbon Nanotubes under Resonant Excitations , 2005, 2005 Pacific Rim Conference on Lasers & Electro-Optics.

[41]  C. H. Seager,et al.  Percolation and conductivity: A computer study. II , 1974 .

[42]  Liangbing Hu,et al.  Patternable transparent carbon nanotube films for electrochromic devices , 2007 .

[43]  Sung-Kyoung Kim,et al.  Fabrication of patterned single-walled carbon nanotube films using electrophoretic deposition. , 2008, Ultramicroscopy.

[44]  S. Roth,et al.  Catalytic chemical vapour deposition growth of single wall carbon nanotube films on different substrates for transparent electronic devices , 2007 .

[45]  David L. Carroll,et al.  Evolution and evaluation of the polymer nanotube composite , 1999 .

[46]  Hong‐Zhang Geng,et al.  Transparent Conducting Films by Using Carbon Nanotubes , 2008 .

[47]  Claude M. Penchina,et al.  The physics of amorphous solids , 1983 .

[48]  John A. Rogers,et al.  Solution Casting and Transfer Printing Single-Walled Carbon Nanotube Films , 2004 .

[49]  Heli Jantunen,et al.  Inkjet printing of electrically conductive patterns of carbon nanotubes. , 2006, Small.

[50]  J. M. Kim,et al.  Transparent conductive film based on carbon nanotubes and PEDOT composites , 2005 .

[51]  M. Endo,et al.  Shear-induced preferential alignment of carbon nanotubes resulted in anisotropic electrical conductivity of polymer composites , 2006 .

[52]  Young Hee Lee,et al.  Absorption spectroscopy of surfactant-dispersed carbon nanotube film: Modulation of electronic structures , 2008 .

[53]  S. Kirkpatrick Percolation and Conduction , 1973 .

[54]  M. Stössel,et al.  Work function of ITO substrates and band-offsets at the TPD/ITO interface determined by photoelectron spectroscopy , 2000 .

[55]  T. Marks,et al.  MOCVD-derived highly transparent, conductive zinc- and tin-doped indium oxide thin films: precursor synthesis, metastable phase film growth and characterization, and application as anodes in polymer light-emitting diodes. , 2005, Journal of the American Chemical Society.

[56]  Young Hee Lee,et al.  Effect of Carbon Nanotube Types in Fabricating Flexible Transparent Conducting Films , 2008 .

[57]  Tobin J Marks,et al.  Organic light-emitting diodes having carbon nanotube anodes. , 2006, Nano letters.

[58]  John J Boland,et al.  Transparent, flexible, and highly conductive thin films based on polymer-nanotube composites. , 2009, ACS nano.

[59]  Daihua Zhang,et al.  Transparent, conductive, and flexible carbon nanotube films and their application in organic light-emitting diodes. , 2006, Nano letters.

[60]  J. Coleman,et al.  A carbon nanotube composite as an electron transport layer for M3EH-PPV based light-emitting diodes , 2001 .

[61]  P. Avouris,et al.  Mechanical Properties of Carbon Nanotubes , 2001 .

[62]  G. Crawford,et al.  Strain-dependent electrical resistance of tin-doped indium oxide on polymer substrates , 2000 .

[63]  Richard E. Smalley,et al.  Single-Wall Carbon Nanotube Films , 2003 .

[64]  J. Trancik,et al.  Transparent and catalytic carbon nanotube films. , 2008, Nano letters.

[65]  M. Prato,et al.  Carbon nanotubes in electron donor-acceptor nanocomposites. , 2005, Accounts of chemical research.

[66]  G. Eda,et al.  Improved conductivity of transparent single-wall carbon nanotube thin films via stable postdeposition functionalization , 2007 .

[67]  Yi Chen,et al.  Electrostatic layer-by-layer assembled carbon nanotube multilayer film and its electrocatalytic activity for O2 reduction. , 2004, Langmuir : the ACS journal of surfaces and colloids.

[68]  W. Blau,et al.  Hole blocking in carbon nanotube–polymer composite organic light-emitting diodes based on poly (m-phenylene vinylene-co-2, 5-dioctoxy-p-phenylene vinylene) , 2000 .

[69]  L. Zuppiroli,et al.  A carbon nanotube/organic semiconducting polymer heterojunction , 1996 .

[70]  T. Lutz,et al.  Macroscopic scale separation of metallic and semiconducting nanotubes by dielectrophoresis , 2005 .

[71]  M. Shiraishi,et al.  Work function of carbon nanotubes , 2001 .

[72]  Edgar Muñoz,et al.  Fabrication and characterization of thin films of single-walled carbon nanotube bundles on flexible plastic substrates. , 2004, Journal of the American Chemical Society.

[73]  David L. Carroll,et al.  Organic light emitting diodes fabricated with single wall carbon nanotubes dispersed in a hole conducting buffer: the role of carbon nanotubes in a hole conducting polymer , 2001 .

[74]  Satoru Suzuki,et al.  Work functions and valence band states of pristine and Cs-intercalated single-walled carbon nanotube bundles , 2000 .

[75]  Paul L. McEuen,et al.  Single-wall carbon nanotubes , 2000 .

[76]  E. Kymakis,et al.  Carbon nanotube/PEDOT:PSS electrodes for organic photovoltaics , 2006 .

[77]  Xiaoming Tao,et al.  Fabrication and characterization of OLEDs using PEDOT:PSS and MWCNT nanocomposites , 2008 .

[78]  G. Gruner,et al.  Quasi-Langmuir–Blodgett thin film deposition of carbon nanotubes , 2003, cond-mat/0307712.

[79]  J. Hafner,et al.  Fabry - Perot interference in a nanotube electron waveguide , 2001, Nature.

[80]  Young-Geun Ha,et al.  Fabrication and characterization of OLEDs using MEH-PPV and SWCNT nanocomposites , 2005 .

[81]  Jong-Ho Choi,et al.  Electrical and optical studies of organic light emitting devices using SWCNTs-polymer nanocomposites , 2003 .

[82]  Heli Jantunen,et al.  Inkjet printing of transparent and conductive patterns of single‐walled carbon nanotubes and PEDOT‐PSS composites , 2007 .

[83]  Cheolmin Park,et al.  Transparent, Low‐Electric‐Resistance Nanocomposites of Self‐Assembled Block Copolymers and SWNTs , 2008 .

[84]  K. R. Atkinson,et al.  Strong, Transparent, Multifunctional, Carbon Nanotube Sheets , 2005, Science.

[85]  A. Kulik,et al.  Mechanical properties of carbon nanotubes , 1999 .

[86]  S. Iijima Helical microtubules of graphitic carbon , 1991, Nature.

[87]  M. in het Panhuis,et al.  Inkjet printing of transparent, electrically conducting single-walled carbon-nanotube composites. , 2007, Small.

[88]  Makoto Kanda,et al.  Large-scale separation of metallic and semiconducting single-walled carbon nanotubes. , 2005, Journal of the American Chemical Society.

[89]  David L. Carroll,et al.  A Composite from Poly(m‐phenylenevinylene‐co‐2,5‐dioctoxy‐p‐phenylenevinylene) and Carbon Nanotubes: A Novel Material for Molecular Optoelectronics , 1998 .