Eddy covariance mapping and quantification of surface CO2 leakage fluxes

We present eddy covariance measurements of net CO{sub 2} flux (F{sub c}) made during a controlled release of CO{sub 2} (0.3 t d{sup -1} from 9 July to 7 August 2008) from a horizontal well {approx}100 m in length and {approx}2.5 m in depth located in an agricultural field in Bozeman, MT. We isolated fluxes arising from the release (F{sub cr}) by subtracting fluxes corresponding to a model for net ecosystem exchange from F{sub c}. A least-squares inversion of 611 F{sub cr} and corresponding modeled footprint functions recovered the location, length, and magnitude of the surface CO{sub 2} flux leakage signal, although high wavenumber details of the signal were poorly resolved. The estimated total surface CO{sub 2} leakage rate (0.32 t d{sup ?1}) was within 7% of the release rate.

[1]  J. Wyngaard,et al.  Monitoring volcanic hazard using eddy covariance at Solfatara volcano, Naples, Italy , 2003 .

[2]  Robin K. S. Hankin,et al.  A shallow‐layer model for heavy gas dispersion from natural sources: Application and hazard assessment at Caldara di Manziana, Italy , 2008 .

[3]  Curtis M. Oldenburg,et al.  Surface CO2 leakage during two shallow subsurface CO2 releases , 2007 .

[4]  A. Palmer,et al.  SUMMARY OF THE IPCC SPECIAL REPORT ON CARBON DIOXIDE CAPTURE AND STORAGE , 2006 .

[5]  T. W. Horst,et al.  Footprint estimation for scalar flux measurements in the atmospheric surface layer , 1992 .

[6]  D. Tedesco,et al.  Soil gas emanations as precursory indicators of volcanic eruptions , 1991, Journal of the Geological Society.

[7]  W. C. Evans,et al.  Forest-killing diffuse CO2 emission at Mammoth Mountain as a sign of magmatic unrest , 1995, Nature.

[8]  F. Goff,et al.  Elevated carbon dioxide flux at the Dixie Valley geothermal field, Nevada; relations between surface phenomena and the geothermal reservoir , 2001 .

[9]  P. Segall,et al.  Detection of a locked zone at depth on the Parkfield, California, segment of the San Andreas Fault , 1987 .

[10]  Curtis M. Oldenburg,et al.  Eddy covariance observations of surface leakage during shallow subsurface CO2 releases , 2009 .

[11]  J. Wyngaard,et al.  Eddy‐correlation measurement of hydrothermal gases , 2000 .

[12]  D. E. Anderson,et al.  Eddy covariance measurement of CO2 flux to the atmosphere from an area of high volcanogenic emissions, Mammoth Mountain, California , 2001 .

[13]  Giovanni Chiodini,et al.  Quantification of deep CO2 fluxes from Central Italy. Examples of carbon balance for regional aquifers and of soil diffuse degassing , 1999 .

[14]  Luigi Marini,et al.  Soil CO2 flux measurements in volcanic and geothermal areas , 1998 .

[15]  Ü. Rannik,et al.  Gap filling strategies for defensible annual sums of net ecosystem exchange , 2001 .

[16]  Giovanni Chiodini,et al.  Numerical model of gas dispersion emitted from volcanic sources , 2005 .

[17]  J. Lewicki Six-week time series of eddy covariance CO2 flux at Mammoth Mountain, California: performance evaluation and role of meteorological forcing , 2008 .

[18]  C. Cardellini,et al.  Comparison of carbon dioxide emissions with fluid upflow, chemistry, and geologic structures at the Rotorua geothermal system, New Zealand , 2006 .

[19]  Hans Peter Schmid,et al.  Experimental design for flux measurements: matching scales of observations and fluxes , 1997 .

[20]  D. Baldocchi Assessing the eddy covariance technique for evaluating carbon dioxide exchange rates of ecosystems: past, present and future , 2003 .

[21]  B. Metz IPCC special report on carbon dioxide capture and storage , 2005 .

[22]  P. Hernández,et al.  Diffuse CO2 efflux from Iwojima volcano, Izu-Ogasawara arc, Japan , 2005 .

[23]  Curtis M. Oldenburg,et al.  Near-surface monitoring strategies for geologic carbon dioxide storage verification , 2003 .

[24]  G. Natale,et al.  Carbon Dioxide Degassing by Advective Flow from Usu Volcano, Japan , 2001, Science.

[25]  J. L. Lewickia,et al.  Six-week time series of eddy covariance CO 2 flux at Mammoth Mountain , 4 California : performance evaluation and role of meteorological forcing 5 6 7 8 , 2022 .

[26]  C. M. Oldenburg,et al.  Surface CO2 leakage during two shallow subsurface CO2 releases , 2007 .