Biodiesel Production Using Modified Direct Transesterification by Sequential Use of Acid-Base Catalysis and Performance Evaluation of Diesel Engine Using Various Blends

Biodiesel is a seemingly suitable alternative substitute for conventional fossil fuels to run a diesel engine. In the first part of the study, the production of biodiesel by modified direct transesterification (MDT) is reported. An enhancement in the biodiesel yield with a considerable reduction in reaction time with the MDT method was observed. The required duration for diesel and biodiesel blending was minimized including glycerol separation time from biodiesel in the MDT method. The development in the automotive sector mainly focuses on the design of an efficient, economical, and low emission greenhouse gas diesel engine. In the current experimental work Ceiba pentandra/Nigella sativa and diesel blends (CPB10 and NSB10) were used to run the diesel engine. A variety of approaches were implemented to improve the engine performance for these combinations of fuels. The fuel injector opening pressure (IOP) was set at 240 bar, the torriodal re-entrant combustion chamber (TRCC) having a six-hole injector with a 0.2 mm orifice diameter each, provided better brake thermal efficiency (BTE) with lower emissions compared with the hemispherical combustion chamber (HCC) and trapezoidal combustion chamber (TCC) for both CPB10 and NSB10. CPB10 showed better performance compared with NSB10. A maximum BTE of 29.1% and 28.6% were achieved with CPB10 and NSB10, respectively, at all optimized conditions. Diesel engine operation with CPB10 and NSB10 at 23° bTDC fuel injection timing, and 240 bar IOP with TRCC can yield better results, close to a diesel run engine at 23° bTDC fuel injection timing, and 205 bar IOP with HCC.

[1]  B. Das,et al.  Effect of fuel opening injection pressure and injection timing of hydrogen enriched rice bran biodiesel fuelled in CI engine , 2021, International Journal of Hydrogen Energy.

[2]  P. Harari,et al.  Effect of injection pressure, injection timing and nozzle geometry on performance and emission characteristics of diesel engine operated with thevetia peruviana biodiesel , 2021 .

[3]  V. S. Yaliwal,et al.  Effect of injection parameters and producer gas derived from redgram stalk on the performance and emission characteristics of a diesel engine , 2021 .

[4]  T. Khan Direct Transesterification for Biodiesel Production and Testing the Engine for Performance and Emissions Run on Biodiesel-Diesel-Nano Blends , 2021, Nanomaterials.

[5]  D. Mohanty,et al.  Experimental investigations of dairy scum biodiesel in a diesel engine with variable injection timing for performance, emission and combustion , 2020 .

[6]  N. Mahalakshmi,et al.  Influence of high pressure fuel injection system on engine performance and combustion characteristics of Moringa Oleifera biodiesel and its blends , 2020 .

[7]  S. Karthic,et al.  An assessment on injection pressure and timing to reduce emissions on diesel engine powered by renewable fuel , 2020 .

[8]  S. V. Khandal,et al.  Augmented Turbulence for Progressive and Efficient Combustion in Biodiesel–Diesel Engine , 2019, Arabian Journal for Science and Engineering.

[9]  C. Jegadheesan,et al.  A novel study on the effect lemon peel oil as a fuel in CRDI engine at various injection strategies , 2018, Energy Conversion and Management.

[10]  M. A. Kamoji,et al.  Experimental Studies on the Use of Pyrolysis Oil for Diesel Engine Applications and Optimization of Engine Parameters of Injection Timing, Injector Opening Pressure and Injector Nozzle Geometry , 2018 .

[11]  I. Badruddin,et al.  Biodiesel Production by Direct Transesterification Process via Sequential Use of Acid–Base Catalysis , 2018 .

[12]  V. N. Gaitonde,et al.  Effect of exhaust gas recirculation, fuel injection pressure and injection timing on the performance of common rail direct injection engine powered with honge biodiesel (BHO) , 2017 .

[13]  V. N. Gaitonde,et al.  Paradigm shift from mechanical direct injection diesel engines to advanced injection strategies of diesel homogeneous charge compression ignition (HCCI) engines- A comprehensive review , 2017 .

[14]  S. V. Channapattana,et al.  Investigation of DI-CI four-stroke VCR engine at different static injection timings using biofuel derived from non-edible oil source as a fuel , 2016 .

[15]  Bhaskor J. Bora,et al.  Optimisation of injection timing and compression ratio of a raw biogas powered dual fuel diesel engine , 2016 .

[16]  Ghulam Abdul Quadir,et al.  Effects of engine variables and heat transfer on the performance of biodiesel fueled IC engines , 2015 .

[17]  Ahmad Badarudin,et al.  Ceiba pentandra, Nigella sativa and their blend as prospective feedstocks for biodiesel , 2015 .

[18]  Balaji Mohan,et al.  Optimization of biodiesel fueled engine to meet emission standards through varying nozzle opening pressure and static injection timing , 2014 .

[19]  A. E. Atabani,et al.  Recent scenario and technologies to utilize non-edible oils for biodiesel production , 2014 .

[20]  M. V. Martínez-Huerta,et al.  Synthesis of biodiesel from Nigella sativa seed oil using surfactant-Brønsted acidic-combined ionic liquid as catalyst , 2014 .

[21]  Wen Tong Chong,et al.  Experimental study on performance and exhaust emissions of a diesel engine fuelled with Ceiba pentandra biodiesel blends , 2013 .

[22]  Teuku Meurah Indra Mahlia,et al.  Production and comparative fuel properties of biodiesel from non-edible oils: Jatropha curcas, Sterculia foetida and Ceiba pentandra , 2013 .

[23]  Teuku Meurah Indra Mahlia,et al.  Characterization and production of Ceiba pentandra biodiesel and its blends. , 2013 .

[24]  Mustafa Canakci,et al.  The impact of fuel injection pressure on the exhaust emissions of a direct injection diesel engine fueled with biodiesel–diesel fuel blends , 2012 .

[25]  R. Gakkhar,et al.  Influence of injection timing on performance, combustion and emission characteristics of Jatropha biodiesel engine , 2011 .

[26]  Michael T. Leick,et al.  Effect of EGR and injection timing on combustion and emission characteristics of split injection strategy DI-diesel engine fueled with biodiesel , 2011 .

[27]  S. Harrison,et al.  Selection of Direct Transesterification as the Preferred Method for Assay of Fatty Acid Content of Microalgae , 2010, Lipids.

[28]  T. Balusamy,et al.  Effect of Injection Time and Injection Pressure on CI Engine Fuelled with Methyl Ester of Thevetia Peruviana Seed Oil , 2010 .

[29]  A. Koca,et al.  Comparison of performance and emissions of diesel fuel, rapeseed and soybean oil methyl esters injected at different pressures , 2010 .

[30]  N. S. Rathore,et al.  Experimental investigation of the effect of compression ratio and injection pressure in a direct injection diesel engine running on Jatropha methyl ester , 2010 .

[31]  G. Nagarajan,et al.  Influence of injection timing on performance, emission and combustion characteristics of a DI diesel engine running on waste plastic oil , 2009 .

[32]  G. Nagarajan,et al.  Effect of injection pressure on performance, emission and combustion characteristics of high linolenic linseed oil methyl ester in a DI diesel engine , 2009 .

[33]  Nagaraj R. Banapurmath,et al.  Effect of biodiesel derived from Honge oil and its blends with diesel when directly injected at different injection pressures and injection timings in single-cylinder water-cooled compression ignition engine , 2009 .

[34]  Hifjur Raheman,et al.  Performance of diesel engine with biodiesel at varying compression ratio and ignition timing , 2008 .

[35]  Saiful Bari,et al.  Effect of Fuel injection timing with waste cooking oil as a fuel in a direct injection diesel engine , 2004 .

[36]  A. I. Ogbonna,et al.  Effect of advanced injection timing on the performance of rapeseed oil in diesel engines , 2000 .

[37]  D. B. Ganesh,et al.  Experimental exploration on the influence of different piston geometry and injection timing by using bio-diesel , 2017 .

[38]  P. Sivakumar,et al.  Optimization and kinetic studies on biodiesel production from underutilized Ceiba Pentandra oil , 2013 .

[39]  Dipti Singh,et al.  Biodiesel production through the use of different sources and characterization of oils and their esters as the substitute of diesel: A review , 2010 .