On the Effect of Wave Signal Input via Zero Charge Corrosion Protection in 3.5% NaCl Solution

The technique of zero charge corrosion potential (ZCCP) acts as a new alternative of cathodic protection technique. A study of wave signal input in ZCCP technique was carried out on pure Mg steel in the 3.5% NaCl solution. This experiment was conducted within 48 hours. The wave signals input that had been used in this experiment are square, triangle, and sine wave. These waveforms have an impact on the corrosion protection of the ZCCP system. The effectiveness of waveform in ZCCP technique on corrosion protection was determined by morphology observation using stereomicroscope. It is found that, the lowest consumption of current density took placed at the square wave signal which is-0.99μA/cm2. Meanwhile, for triangle and sine wave, the current density recorded were-1.694μA/cm2 and-1.756μA/cm2, respectively. From the morphology observations, it is clearly seen that the square wave signal provides better corrosion protection as compared to the triangle and sine wave signal. There is no formation of localised corrosion detected on the Mg surface using square wave signal. This is because the % ‘ON’ and % ‘OFF’ in ZCCP system allows to set it to the desired value of potential.

[1]  R. A. Malek,et al.  The hydrogen evolution of pure magnesium in different electrolytes , 2021 .

[2]  Linhua Jiang,et al.  A comparative investigation on cathodic protections of three sacrificial anodes on chloride-contaminated reinforced concrete , 2020 .

[3]  Zhenglin Tang A review of corrosion inhibitors for rust preventative fluids , 2019, Current Opinion in Solid State and Materials Science.

[4]  Syed Owais Athar,et al.  Efficiency and Cost Analysis of Power Sources in Impressed Current Cathodic Protection System for Corrosion Prevention in Buried Pipelines of Balochistan, Pakistan , 2018, IOP Conference Series: Materials Science and Engineering.

[5]  Faisal Khan,et al.  Economic risk analysis of pitting corrosion in process facilities , 2017 .

[6]  Yingwei Song,et al.  Pitting corrosion of a Rare Earth Mg alloy GW93 , 2017 .

[7]  Y. F. Cheng,et al.  Accelerated corrosion of pipeline steel and reduced cathodic protection effectiveness under direct current interference , 2017 .

[8]  R. Martinez-Duarte,et al.  Assessing the Advantages of Using Square Wave Signals for Particle Trapping in Carbon-Electrode Dielectrophoresis , 2016 .

[9]  Fabio Scenini,et al.  A study on magnesium corrosion by real-time imaging and electrochemical methods: relationship between local processes and hydrogen evolution , 2016 .

[10]  Murat Ates,et al.  A review on conducting polymer coatings for corrosion protection , 2016 .

[11]  Song-mei Li,et al.  Metastable pitting corrosion of 304 stainless steel in 3.5% NaCl solution , 2014 .

[12]  Yingchao Su,et al.  A Chemical Conversion Hydroxyapatite Coating on AZ60 Magnesium Alloy and Its Electrochemical Corrosion Behaviour , 2012, International Journal of Electrochemical Science.

[13]  El-Sayed M. Sherif Corrosion Behavior of Magnesium in Naturally Aerated Stagnant Seawater and 3.5% Sodium Chloride Solutions , 2012, International Journal of Electrochemical Science.

[14]  A. Mathiazhagan,et al.  Design and Programming of Cathodic Protection for SHIPS , 2010 .