Portable room-temperature self-powered/active H2 sensor driven by human motion through piezoelectric screening effect

Abstract Room-temperature high H 2 sensing has been realized from SnO 2 /ZnO nanoarray nanogenerator.Without any external electricity power source, the portable device can be self-powered underthe driving of human motion, in which the piezoelectric output can actively act as both thepower source and H 2 sensing signal. Upon exposure to 800 ppm H 2 at room temperature, thepiezoelectric output voltage of the device under the same applied deformation decreases from0.80 V (in dry air) to 0.14 V, and the sensitivity is up to 471.4. The detection limit is 10 ppmH 2 , and the selectivity against H 2 at room temperature is very high. The excellent room-temperature H 2 sensing performance can be attributed to the coupling of the piezoelectricscreening effect of ZnO nanowires and the conversion of SnO 2 /ZnO heterojunctions. This studycan stimulate a research trend for the development of the next generation of portable room-temperature H 2 sensors.& 2014 Elsevier Ltd. All rights reserved. 1. Introduction

[1]  Zhong Lin Wang The new field of nanopiezotronics , 2007 .

[2]  Wenzhuo Wu,et al.  Piezotronic nanowire-based resistive switches as programmable electromechanical memories. , 2011, Nano letters.

[3]  Zhong‐Lin Wang,et al.  Progress in Piezotronics and Piezo‐Phototronics , 2012, Advanced materials.

[4]  Younan Xia,et al.  A solution-phase, precursor route to polycrystalline SnO2 nanowires that can be used for gas sensing under ambient conditions. , 2003, Journal of the American Chemical Society.

[5]  Vladimir M. Aroutiounian,et al.  Study of sensitivity and response kinetics changes for SnO2 thin-film hydrogen sensors , 2009 .

[6]  Zhong Lin Wang,et al.  Power generation with laterally packaged piezoelectric fine wires. , 2009, Nature nanotechnology.

[7]  Pei Lin,et al.  Functional nanogenerators as vibration sensors enhanced by piezotronic effects , 2014, Nano Research.

[8]  Jim P. Zheng,et al.  Room-temperature low-power hydrogen sensor based on a single tin dioxide nanobelt , 2006 .

[9]  Liwei Lin,et al.  Piezoelectric nanofibers for energy scavenging applications , 2012 .

[10]  C. Rivkin,et al.  An overview of hydrogen safety sensors and requirements , 2011 .

[11]  Subramanian Krishnan,et al.  Advances in materials for room temperature hydrogen sensors. , 2012, The Analyst.

[12]  Jing Wang,et al.  Hollow hierarchical SnO2-ZnO composite nanofibers with heterostructure based on electrospinning method for detecting methanol , 2014 .

[13]  Yugang Sun,et al.  High‐Performance, Flexible Hydrogen Sensors That Use Carbon Nanotubes Decorated with Palladium Nanoparticles , 2007 .

[14]  Zhong Lin Wang,et al.  Taxel-Addressable Matrix of Vertical-Nanowire Piezotronic Transistors for Active and Adaptive Tactile Imaging , 2013, Science.

[15]  Z. Wang Self‐Powered Nanosensors and Nanosystems , 2012, Advanced materials.

[16]  Hiranmay Saha,et al.  ZnO–SnO2 based composite type gas sensor for selective hydrogen sensing , 2014 .

[17]  Long Lin,et al.  A Nanogenerator for Energy Harvesting from a Rotating Tire and its Application as a Self‐Powered Pressure/Speed Sensor , 2011, Advanced materials.

[18]  Jonghyurk Park,et al.  Highly sensitive hydrogen detection of catalyst-free ZnO nanorod networks suspended by lithography-assisted growth , 2011, Nanotechnology.

[19]  Zhong Lin Wang,et al.  Toward self-powered sensor networks , 2010 .

[20]  Byeong Kwon Ju,et al.  Micromachined catalytic combustible hydrogen gas sensor , 2011 .

[21]  Yaguang Wei,et al.  Integrated multilayer nanogenerator fabricated using paired nanotip-to-nanowire brushes. , 2008, Nano letters.

[22]  Ooi Kiang Tan,et al.  Low‐Temperature Growth of SnO2 Nanorod Arrays and Tunable n–p–n Sensing Response of a ZnO/SnO2 Heterojunction for Exclusive Hydrogen Sensors , 2011 .

[23]  Noriya Izu,et al.  Hydrogen-selective thermoelectric gas sensor , 2003 .

[24]  Shun Mao,et al.  Ultrafast hydrogen sensing through hybrids of semiconducting single-walled carbon nanotubes and tin oxide nanocrystals. , 2012, Nanoscale.

[25]  Yan Zhang,et al.  Pyroelectric nanogenerators for driving wireless sensors. , 2012, Nano letters.

[26]  Fang Zhang,et al.  Enhanced Performance of Flexible ZnO Nanowire Based Room‐Temperature Oxygen Sensors by Piezotronic Effect , 2013, Advanced materials.

[27]  C. Liu,et al.  Synthesis of ZnO–SnO2 nanocomposites by microemulsion and sensing properties for NO2 , 2008 .

[28]  Ibrahim Dincer,et al.  On hydrogen and hydrogen energy strategies. I: current status and needs , 2005 .

[29]  Zhong Lin Wang,et al.  Nanotechnology-enabled energy harvesting for self-powered micro-/nanosystems. , 2012, Angewandte Chemie.

[30]  Zhong Lin Wang,et al.  One-dimensional ZnO nanostructures: Solution growth and functional properties , 2011 .

[31]  Nicola Donato,et al.  Room-temperature hydrogen sensing with heteronanostructures based on reduced graphene oxide and tin oxide. , 2012, Angewandte Chemie.

[32]  Zhong Lin Wang,et al.  Self-powered nanowire devices. , 2010, Nature nanotechnology.

[33]  P. Ngene,et al.  Seeing Hydrogen in Colors: Low‐Cost and Highly Sensitive Eye Readable Hydrogen Detectors , 2014 .

[34]  Caofeng Pan,et al.  Enhanced Performance of a ZnO Nanowire‐Based Self‐Powered Glucose Sensor by Piezotronic Effect , 2013 .

[35]  Zhong Lin Wang,et al.  Self-powered system with wireless data transmission. , 2011, Nano letters.

[36]  Zhong Lin Wang,et al.  Direct-Current Nanogenerator Driven by Ultrasonic Waves , 2007, Science.

[37]  Zhong Lin Wang,et al.  Piezoelectric Nanogenerators Based on Zinc Oxide Nanowire Arrays , 2006, Science.

[38]  Youqi Tang,et al.  A New Highly Selective H2 Sensor Based on TiO2/PtO−Pt Dual-Layer Films , 2002 .

[39]  Long Lin,et al.  Replacing a Battery by a Nanogenerator with 20 V Output , 2012, Advanced materials.

[40]  Zhong Lin Wang,et al.  Piezoelectric-nanowire-enabled power source for driving wireless microelectronics. , 2010, Nature communications.

[41]  Jacek Rynkowski,et al.  The effect of oxygen adsorption on catalytic activity of SnO2 in CO oxidation , 2011 .

[42]  Hyoung J. Cho,et al.  Room temperature hydrogen response kinetics of nano–micro-integrated doped tin oxide sensor , 2007 .

[43]  U. Diebold,et al.  The surface and materials science of tin oxide , 2005 .

[44]  Ghenadii Korotcenkov,et al.  Review of electrochemical hydrogen sensors. , 2009, Chemical reviews.

[45]  H. K. Abdel-Aal,et al.  A new approach to utilize Hydrogen as a safe fuel , 2005 .

[46]  Zhaoxiong Xie,et al.  High-sensitivity humidity sensor based on a single SnO(2) nanowire. , 2007, Journal of the American Chemical Society.

[47]  S. S. Kim,et al.  Synthesis and gas sensing performance of ZnO–SnO2 nanofiber–nanowire stem-branch heterostructure , 2013 .

[48]  O K Tan,et al.  High sensitivity SnO2 single-nanorod sensors for the detection of H2 gas at low temperature , 2009, Nanotechnology.

[49]  Junhong Chen,et al.  Room‐Temperature Gas Sensing Based on Electron Transfer between Discrete Tin Oxide Nanocrystals and Multiwalled Carbon Nanotubes , 2009 .

[50]  Marian W. Urbanczyk,et al.  Bilayer structure for hydrogen detection in a surface acoustic wave sensor system , 2002 .

[51]  Teng Fei,et al.  A class of hierarchical nanostructures: ZnO surface-functionalized TiO2 with enhanced sensing properties , 2013 .

[52]  Guangjin Li,et al.  Relationships between sensitivity, catalytic activity, and surface areas of SnO2 gas sensors , 1999 .

[53]  Lili Xing,et al.  Core–Shell In2O3/ZnO Nanoarray Nanogenerator as a Self-Powered Active Gas Sensor with High H2S Sensitivity and Selectivity at Room Temperature , 2014 .

[54]  J. T. Ranney,et al.  The Surface Science of Metal Oxides , 1995 .

[55]  Ion Tiginyanu,et al.  Selective hydrogen gas nanosensor using individual ZnO nanowire with fast response at room temperature , 2010 .

[56]  Guowei Yang,et al.  Fabrication of a SnO2 Nanowire Gas Sensor and Sensor Performance for Hydrogen , 2008 .

[57]  T. Seiyama,et al.  Chemical sensor technology , 1988 .

[58]  Mireille Mouis,et al.  Ultrathin Nanogenerators as Self‐Powered/Active Skin Sensors for Tracking Eye Ball Motion , 2014 .

[59]  Ulrich Banach,et al.  Hydrogen Sensors - A review , 2011 .

[60]  Minbaek Lee,et al.  Self-powered environmental sensor system driven by nanogenerators , 2011 .

[61]  Yan Zhang,et al.  Surface free-carrier screening effect on the output of a ZnO nanowire nanogenerator and its potential as a self-powered active gas sensor , 2013, Nanotechnology.