Internal structure and linear viscoelastic properties of EVA/asphalt nanocomposites

The effect of the addition of two different organoclays as a third component in polymer-modified asphalts has been investigated. Ternary mixtures were prepared by adding clay and poly(ethylene-co-vinyl acetate) to the asphalt, either separately, or in the form of a premixed master batch. The performed characterizations allowed the determination of how the two methods of mixing influence the interactions between asphalt and polymer and therefore the final rheological properties. In particular, it was shown that the clay had a compatibilizing effect on asphalt and polymer and that a high compatibility between clay and polymer led to a better dispersion of the polymer in the asphalt, thus influencing the final rheological properties of the studied systems.

[1]  C. Ha,et al.  Nanostructure of EVA/organoclay nanocomposites: Effects of kinds of organoclays and grafting of maleic anhydride onto EVA , 2003 .

[2]  G. Montanari,et al.  Electrical treeing in EVA-layered silicate nanocomposites , 2005, CEIDP '05. 2005 Annual Report Conference on Electrical Insulation and Dielectric Phenomena, 2005..

[3]  J. Chung,et al.  Dynamic viscoelastic behavior and molecular mobility of acrylonitrile–butadiene copolymer nanocomposites with various organoclay loadings , 2008 .

[4]  Emmanuel P. Giannelis,et al.  Structure and Dynamics of Polymer-Layered Silicate Nanocomposites , 1996 .

[5]  Mahabir Panda,et al.  ENGINEERING PROPERTIES OF EVA-MODIFIED BITUMEN BINDER FOR PAVING MIXES , 1999 .

[6]  Moisés García-Morales,et al.  Viscous properties and microstructure of recycled eva modified bitumen , 2004 .

[7]  F. Martínez-Boza,et al.  Process rheokinetics and microstructure of recycled EVA/LDPE-modified bitumen , 2006 .

[8]  G. Polacco,et al.  Relation between polymer architecture and nonlinear viscoelastic behavior of modified asphalts , 2006 .

[9]  A. Lele,et al.  A rheological study on the kinetics of hybrid formation in polypropylene nanocomposites , 2001 .

[10]  J. Vermant,et al.  Quantifying dispersion of layered nanocomposites via melt rheology , 2007 .

[11]  Rahul K Gupta,et al.  Shear and extensional rheology of EVA/layered silicate-nanocomposites , 2005 .

[12]  C. Roy,et al.  Rheological properties of bitumen modified with pyrolytic carbon black , 1996 .

[13]  Gordon Airey,et al.  Rheological evaluation of ethylene vinyl acetate polymer modified bitumens , 2002 .

[14]  F. Martínez-Boza,et al.  Linear Viscoelasticity of Recycled EVA-Modified Bitumens , 2004 .

[15]  Hyungmin Lee,et al.  Preparation and Rheological Characteristics of Ethylene‐Vinyl Acetate Copolymer/Organoclay Nanocomposites , 2007 .

[16]  C. Gallegos,et al.  Effect of waste polymer addition on the rheology of modified bitumen , 2006 .

[17]  R. Mülhaupt,et al.  Synthesis and thermal behaviour of layered silicate-EVA nanocomposites , 2001 .

[18]  P. Butler,et al.  Shear Orientation of Viscoelastic Polymer−Clay Solutions Probed by Flow Birefringence and SANS , 2000 .

[19]  M. Huggins Viscoelastic Properties of Polymers. , 1961 .

[20]  Antxon Santamaria,et al.  Rheology and stability of bitumen/EVA blends , 2004 .

[21]  G. Polacco,et al.  Dynamic Master Curves of Polymer Modified Asphalt from Three Different Geometries , 2003 .

[22]  Ramanan Krishnamoorti,et al.  Linear Viscoelasticity of Disordered Polystyrene−Polyisoprene Block Copolymer Based Layered-Silicate Nanocomposites , 2000 .

[23]  H. Pollock,et al.  Modulated differential scanning calorimetry: 4. Miscibility and glass transition behaviour in poly(methyl methacrylate) and poly(epichlorohydrin) blends , 1996 .

[24]  P. Dubois,et al.  Polymer-layered silicate nanocomposites: preparation, properties and uses of a new class of materials , 2000 .

[25]  Alexander B. Morgan,et al.  Rheological characterization of polystyrene–clay nanocomposites to compare the degree of exfoliation and dispersion , 2005 .

[26]  F. Mantia,et al.  Eva copolymer-based nanocomposites: Rheological behavior under shear and isothermal and non-isothermal elongational flow , 2006 .

[27]  P. Dubois,et al.  Polyethylene organo-clay nanocomposites: the role of the interface chemistry on the extent of clay intercalation/exfoliation. , 2006, Journal of nanoscience and nanotechnology.

[28]  Suprakas Sinha Ray,et al.  POLYMER/LAYERED SILICATE NANOCOMPOSITES: A REVIEW FROM PREPARATION TO PROCESSING , 2003 .

[29]  Jiri Stastna,et al.  Rheology of bitumen modified by EVA—Organoclay nanocomposites , 2010 .

[30]  J. C. Petersen,et al.  Impact of Lime Modification of Asphalt and Freeze–Thaw Cycling on the Asphalt–Aggregate Interaction and Moisture Resistance to Moisture Damage , 2005 .

[31]  I. B. Kazatchkov,et al.  Relationship between chemical and rheological properties of two asphalts of different origins , 2008 .

[32]  F. Martínez-Boza,et al.  Processing, rheology, and storage stability of recycled EVA/LDPE modified bitumen , 2007 .

[33]  T. Kurauchi,et al.  Fine structure of nylon-6 : clay hybrid , 1994 .

[34]  R. Vaia,et al.  Time-resolved shear behavior of end-tethered Nylon 6–clay nanocomposites followed by non-isothermal crystallization , 2001 .

[35]  P R Herrington,et al.  Rheological modification of bitumen with maleic anhydride and dicarboxylic acids , 1999 .

[36]  M. Zanetti,et al.  Thermal degradation and rheological behaviour of EVA/montmorillonite nanocomposites , 2002 .

[37]  Thomas J. Pinnavaia,et al.  Polymer-clay nanocomposites , 2000 .

[38]  Philippe Dubois,et al.  Preparation and Properties of Layered Silicate Nanocomposites Based on Ethylene Vinyl Acetate Copolymers , 2001 .

[39]  Xiaoyan Ma,et al.  Morphology and properties of nanocomposites formed from ethylene-vinyl acetate copolymers and organoclays , 2007 .

[40]  M. Shaw,et al.  Polymer-Polymer Miscibility , 1979 .

[41]  T. Kurauchi,et al.  Novel preferred orientation in injection‐molded nylon 6‐clay hybrid , 1995 .

[42]  S. Ray Rheology of Polymer/Layered Silicate Nanocomposites , 2006 .

[43]  H. Pollock,et al.  Modulated differential scanning calorimetry , 1997 .

[44]  R. E. Smallman,et al.  An assessment of high voltage electron microscopy (HVEM). An invited review , 1977 .

[45]  R. J. Forbes Bitumen and petroleum in antiquity , 1936 .

[46]  M. V. Gurp,et al.  TIME-TEMPERATURE SUPERPOSITION FOR POLYMERIC BLENDS , 1998 .

[47]  Pavel Kříž,et al.  Rheological Properties of Asphalt/SBS/Clay Blends , 2008 .

[48]  Ibnelwaleed A. Hussein,et al.  Influence of Mw of LDPE and vinyl acetate content of EVA on the rheology of polymer modified asphalt , 2005 .

[49]  R. Krishnamoorti,et al.  Shear response of layered silicate nanocomposites , 2001 .

[50]  D. R. Paul,et al.  Nanocomposites formed from polypropylene/EVA blends , 2009 .

[51]  Ulf Isacsson,et al.  Testing and appraisal of polymer modified road bitumens—state of the art , 1995 .

[52]  T. Kotaka,et al.  A House of Cards Structure in Polypropylene/Clay Nanocomposites under Elongational Flow , 2001 .