A planar electron acceptor for efficient polymer solar cells

A novel planar acceptor IDT-2BR was designed and synthesized. Polymer solar cells (PSCs) based on P3HT:IDT-2BR blended films gave power conversion efficiencies of up to 5.12%, which are much higher than that of PC61BM-based control devices (3.71%) and the highest values reported for P3HT-based fullerene-free PSCs.

[1]  Feng Liu,et al.  Fluoro‐Substituted n‐Type Conjugated Polymers for Additive‐Free All‐Polymer Bulk Heterojunction Solar Cells with High Power Conversion Efficiency of 6.71% , 2015, Advanced materials.

[2]  S. Jenekhe,et al.  Fine‐Tuning the 3D Structure of Nonfullerene Electron Acceptors Toward High‐Performance Polymer Solar Cells , 2015, Advanced materials.

[3]  Bumjoon J. Kim,et al.  High‐Performance All‐Polymer Solar Cells Via Side‐Chain Engineering of the Polymer Acceptor: The Importance of the Polymer Packing Structure and the Nanoscale Blend Morphology , 2015, Advanced materials.

[4]  S. Jenekhe,et al.  n-Type semiconducting naphthalene diimide-perylene diimide copolymers: controlling crystallinity, blend morphology, and compatibility toward high-performance all-polymer solar cells. , 2015, Journal of the American Chemical Society.

[5]  Huiqiong Zhou,et al.  Polymer Homo‐Tandem Solar Cells with Best Efficiency of 11.3% , 2015, Advanced materials.

[6]  Oh Kyu Kwon,et al.  An All‐Small‐Molecule Organic Solar Cell with High Efficiency Nonfullerene Acceptor , 2015, Advanced materials.

[7]  M. Porter,et al.  Synthesis, characterization and photovoltaic properties of azadipyrromethene-based acceptors: effect of pyrrolic substituents , 2015 .

[8]  Daoben Zhu,et al.  High-performance fullerene-free polymer solar cells with 6.31% efficiency , 2015 .

[9]  Yuhang Liu,et al.  High-efficiency non-fullerene organic solar cells enabled by a difluorobenzothiadiazole-based donor polymer combined with a properly matched small molecule acceptor , 2015 .

[10]  Xuhui Huang,et al.  A Tetraphenylethylene Core‐Based 3D Structure Small Molecular Acceptor Enabling Efficient Non‐Fullerene Organic Solar Cells , 2015, Advanced materials.

[11]  Daoben Zhu,et al.  An Electron Acceptor Challenging Fullerenes for Efficient Polymer Solar Cells , 2015, Advanced materials.

[12]  Jianhui Hou,et al.  An electron acceptor based on indacenodithiophene and 1,1-dicyanomethylene-3-indanone for fullerene-free organic solar cells , 2015 .

[13]  J. Yao,et al.  Non-Fullerene Organic Solar Cells with 6.1% Efficiency through Fine-Tuning Parameters of the Film-Forming Process , 2015 .

[14]  C. B. Nielsen,et al.  A rhodanine flanked nonfullerene acceptor for solution-processed organic photovoltaics. , 2015, Journal of the American Chemical Society.

[15]  He Yan,et al.  Aggregation and morphology control enables multiple cases of high-efficiency polymer solar cells , 2014, Nature Communications.

[16]  M. Steigerwald,et al.  Efficient organic solar cells with helical perylene diimide electron acceptors. , 2014, Journal of the American Chemical Society.

[17]  S. Jenekhe,et al.  Beyond fullerenes: design of nonfullerene acceptors for efficient organic photovoltaics. , 2014, Journal of the American Chemical Society.

[18]  Daoben Zhu,et al.  A Twisted Dimeric Perylene Diimide Electron Acceptor for Efficient Organic Solar Cells , 2014 .

[19]  E. Gomez,et al.  Azadipyrromethene‐Based Zn(II) Complexes as Nonplanar Conjugated Electron Acceptors for Organic Photovoltaics , 2014, Advanced materials.

[20]  Daisuke Mori,et al.  Highly efficient charge-carrier generation and collection in polymer/polymer blend solar cells with a power conversion efficiency of 5.7% , 2014 .

[21]  Xiaowei Zhan,et al.  Non-fullerene acceptors for organic photovoltaics: an emerging horizon , 2014 .

[22]  Eric T. Hoke,et al.  Comparing the Device Physics and Morphology of Polymer Solar Cells Employing Fullerenes and Non‐Fullerene Acceptors , 2014 .

[23]  Yang Yang,et al.  An Efficient Triple‐Junction Polymer Solar Cell Having a Power Conversion Efficiency Exceeding 11% , 2014, Advanced materials.

[24]  Wei Jiang,et al.  Integrated Molecular, Interfacial, and Device Engineering towards High‐Performance Non‐Fullerene Based Organic Solar Cells , 2014, Advanced materials.

[25]  Daoben Zhu,et al.  A Star‐Shaped Perylene Diimide Electron Acceptor for High‐Performance Organic Solar Cells , 2014, Advanced materials.

[26]  Deqing Zhang,et al.  New conjugated molecular scaffolds based on [2,2]paracyclophane as electron acceptors for organic photovoltaic cells. , 2014, Chemical Communications.

[27]  S. Moon,et al.  Rhodanine dye-based small molecule acceptors for organic photovoltaic cells. , 2014, Chemical communications.

[28]  John R. Tumbleston,et al.  Quantification of Nano‐ and Mesoscale Phase Separation and Relation to Donor and Acceptor Quantum Efficiency, Jsc, and FF in Polymer:Fullerene Solar Cells , 2014, Advanced materials.

[29]  A. Jen,et al.  Eleven‐Membered Fused‐Ring Low Band‐Gap Polymer with Enhanced Charge Carrier Mobility and Photovoltaic Performance , 2014 .

[30]  Alberto Salleo,et al.  High Performance All‐Polymer Solar Cell via Polymer Side‐Chain Engineering , 2014, Advanced materials.

[31]  Daoben Zhu,et al.  Acceptor-donor-acceptor small molecules based on indacenodithiophene for efficient organic solar cells. , 2014, ACS applied materials & interfaces.

[32]  Weiwei Li,et al.  Polymer Solar Cells with Diketopyrrolopyrrole Conjugated Polymers as the Electron Donor and Electron Acceptor , 2014, Advanced materials.

[33]  Jianhui Hou,et al.  Molecular design toward highly efficient photovoltaic polymers based on two-dimensional conjugated benzodithiophene. , 2014, Accounts of chemical research.

[34]  Long Ye,et al.  Binary additives synergistically boost the efficiency of all-polymer solar cells up to 3.45% , 2014 .

[35]  Kion Norrman,et al.  New Insights into the Mechanisms of Photodegradation/Stabilization of P3HT:PCBM Active Layers Using Poly(3-hexyl-d13-Thiophene) , 2013 .

[36]  Jian Pei,et al.  Towards rational design of organic electron acceptors for photovoltaics: a study based on perylenediimide derivatives , 2013 .

[37]  Long Ye,et al.  A Potential Perylene Diimide Dimer‐Based Acceptor Material for Highly Efficient Solution‐Processed Non‐Fullerene Organic Solar Cells with 4.03% Efficiency , 2013, Advanced materials.

[38]  Yongsheng Chen,et al.  High performance photovoltaic applications using solution-processed small molecules. , 2013, Accounts of chemical research.

[39]  A. Heeger,et al.  Improved light harvesting and improved efficiency by insertion of an optical spacer (ZnO) in solution-processed small-molecule solar cells. , 2013, Nano letters.

[40]  John R. Tumbleston,et al.  Domain Purity, Miscibility, and Molecular Orientation at Donor/Acceptor Interfaces in High Performance Organic Solar Cells: Paths to Further Improvement , 2013 .

[41]  Ying Shu,et al.  Indan-1,3-dione electron-acceptor small molecules for solution-processable solar cells: a structure-property correlation. , 2013, Chemical communications.

[42]  Yongfang Li,et al.  A Solution‐Processable Electron Acceptor Based on Dibenzosilole and Diketopyrrolopyrrole for Organic Solar Cells , 2013 .

[43]  Jian Pei,et al.  Non-fullerene acceptors containing fluoranthene-fused imides for solution-processed inverted organic solar cells. , 2013, Chemical communications.

[44]  Antonio Facchetti,et al.  Polymer donor–polymer acceptor (all-polymer) solar cells , 2013 .

[45]  A. Troisi,et al.  What Makes Fullerene Acceptors Special as Electron Acceptors in Organic Solar Cells and How to Replace Them , 2013, Advanced materials.

[46]  Yongfang Li,et al.  Small molecule semiconductors for high-efficiency organic photovoltaics. , 2012, Chemical Society reviews.

[47]  Yongfang Li,et al.  A 3D star-shaped non-fullerene acceptor for solution-processed organic solar cells with a high open-circuit voltage of 1.18 V. , 2012, Chemical communications.

[48]  A. Hexemer,et al.  Soft x-ray scattering facility at the Advanced Light Source with real-time data processing and analysis. , 2012, The Review of scientific instruments.

[49]  F. Krebs,et al.  New Low‐Bandgap Materials with Good Stabilities and Efficiencies Comparable to P3HT in R2R‐Coated Solar Cells , 2012 .

[50]  Yongfang Li Molecular design of photovoltaic materials for polymer solar cells: toward suitable electronic energy levels and broad absorption. , 2012, Accounts of chemical research.

[51]  B. Collins,et al.  Correlating the efficiency and nanomorphology of polymer blend solar cells utilizing resonant soft X-ray scattering. , 2012, ACS nano.

[52]  X. Zhan,et al.  Electron transporting semiconducting polymers in organic electronics. , 2011, Chemical Society reviews.

[53]  Khai Leok Chan,et al.  Organic non-fullerene acceptors for organic photovoltaics , 2011 .

[54]  Ole Hagemann,et al.  Photochemical stability of π-conjugated polymers for polymer solar cells: a rule of thumb , 2011 .

[55]  J. Anthony Small-Molecule, Nonfullerene Acceptors for Polymer Bulk Heterojunction Organic Photovoltaics† , 2011 .

[56]  Yongfang Li,et al.  Fullerene derivative acceptors for high performance polymer solar cells. , 2011, Physical chemistry chemical physics : PCCP.

[57]  Mark A Ratner,et al.  Rylene and Related Diimides for Organic Electronics , 2011, Advanced materials.

[58]  A. Roy,et al.  Recombination in polymer-fullerene bulk heterojunction solar cells , 2010, 1010.5021.

[59]  Seth R. Marder,et al.  n‐Type Organic Semiconductors in Organic Electronics , 2010, Advanced materials.

[60]  Chain‐Shu Hsu,et al.  Synthesis of conjugated polymers for organic solar cell applications. , 2009, Chemical reviews.

[61]  Bernard Kippelen,et al.  A high-mobility electron-transport polymer with broad absorption and its use in field-effect transistors and all-polymer solar cells. , 2007, Journal of the American Chemical Society.

[62]  C. Brabec,et al.  2.5% efficient organic plastic solar cells , 2001 .

[63]  J. Hummelen,et al.  Polymer Photovoltaic Cells: Enhanced Efficiencies via a Network of Internal Donor-Acceptor Heterojunctions , 1995, Science.

[64]  Oh Kyu Kwon,et al.  Soluble Dicyanodistyrylbenzene‐Based Non‐Fullerene Electron Acceptors with Optimized Aggregation Behavior for High‐Efficiency Organic Solar Cells , 2015 .

[65]  Daoben Zhu,et al.  A bipolar small molecule based on indacenodithiophene and diketopyrrolopyrrole for solution processed organic solar cells , 2014 .