New Developments and Applications of Handheld Raman, Mid-Infrared, and Near-Infrared Spectrometers

Abstract: Recently, miniaturization of Raman, mid-infrared (IR), and near-infrared (NIR) spectrometers has made substantial progress. Though mid-infrared systems are based exclusively on attenuated total reflection (ATR) measurements, near-infrared spectrometers operate in the diffuse reflection or transmission mode. The reduction in size, however, must not be accompanied by deterioration in measurement performance, and portable instrumentation will only have a real impact on quality and process control if Raman, IR, and NIR spectra of comparable quality to laboratory spectrometers can be obtained. In the present communication, a short overview on the building principles of novel handheld systems will be provided and the results of qualitative and quantitative analyses of selected liquid and solid sample systems obtained with these Raman, Fourier transform infrared (FTIR), and NIR spectrometers will be evaluated in terms of their comparability with laboratory instruments and their suitability for on-site and field measurements.

[1]  Heinz W. Siesler,et al.  Quantitative Analysis by a Portable near Infrared Spectrometer: Can it Replace Laboratory Instrumentation for in situ Analysis? , 2010 .

[2]  Ulf Isacsson,et al.  Testing and appraisal of polymer modified road bitumens—state of the art , 1995 .

[3]  D. Sybilski Non-newtonian viscosity of polymer-modified bitumens , 1993 .

[4]  Richard L. McCreery,et al.  Raman Spectroscopy for Chemical Analysis , 2000 .

[5]  J. Chalmers,et al.  Handbook of vibrational spectroscopy , 2002 .

[6]  Anthony C. Moffat,et al.  Identifying Counterfeit Medicines Using near Infrared Spectroscopy , 2010 .

[7]  Michael D. Morris,et al.  Modern Raman Spectroscopy: A Practical Approach , 2006 .

[8]  Miguel de la Guardia,et al.  Evaluation of extraction alternatives for Fourier transform infrared spectrometric determination of oil and greases in water , 1997 .

[9]  S. Siggia,et al.  Quantitative Analysis of Mixtures of Primary, Secondary, and Tertiary Aromatic Amines , 1950 .

[10]  Cédric Camps,et al.  Determination of Artemisinin and Moisture Content of Artemisia Annua L. Dry Powder Using a Hand-Held near Infrared Spectroscopy Device , 2011 .

[11]  R. McCreery,et al.  Raman Spectroscopy for Chemical Analysis: McCreery/Raman Spectroscopy , 2005 .

[12]  Emil W. Ciurczak,et al.  Handbook of Near-Infrared Analysis , 1992 .

[13]  N. Sheppard Hydrogen Bonding , 1971, Nature.

[14]  P. Geladi,et al.  Quantitative Determination of Pharmaceutical Drug Formulations by Near-Infrared Spectroscopic Imaging , 2008, Applied spectroscopy.

[15]  M Smith,et al.  Near infrared spectroscopy. , 1999, British journal of anaesthesia.

[16]  H. Martens,et al.  Light scattering and light absorbance separated by extended multiplicative signal correction. application to near-infrared transmission analysis of powder mixtures. , 2003, Analytical chemistry.

[17]  Yves Mouton,et al.  Organic Materials in Civil Engineering , 2006 .

[18]  Peter Collins,et al.  Rapid FTIR method for quantification of styrene‐butadiene type copolymers in bitumen , 2001 .