Megacities and atmospheric pollution.

About half of the world's population now lives in urban areas because of the opportunity for a better quality of life. Many of these urban centers are expanding rapidly, leading to the growth of megacities, which are defined as metropolitan areas with populations exceeding 10 million inhabitants. These concentrations of people and activity are exerting increasing stress on the natural environment, with impacts at urban, regional and global levels. In recent decades, air pollution has become one of the most important problems of megacities. Initially, the main air pollutants of concern were sulfur compounds, which were generated mostly by burning coal. Today, photochemical smog--induced primarily from traffic, but also from industrial activities, power generation, and solvents--has become the main source of concern for air quality, while sulfur is still a major problem in many cities of the developing world. Air pollution has serious impacts on public health, causes urban and regional haze, and has the potential to contribute significantly to climate change. Yet, with appropriate planning, megacities can efficiently address their air quality problems through measures such as application of new emission control technologies and development of mass transit systems. This review is focused on nine urban centers, chosen as case studies to assess air quality from distinct perspectives: from cities in the industrialized nations to cities in the developing world. While each city--its problems, resources, and outlook--is unique, the need for a holistic approach to the complex environmental problems is the same. There is no single strategy in reducing air pollution in megacities; a mix of policy measures will be needed to improve air quality. Experience shows that strong political will coupled with public dialog is essential to effectively implement the regulations required to address air quality problems.

[1]  S. Kuznets Economic Growth and Income Inequality , 2019, The Gap between Rich and Poor.

[2]  Takashi Imamura,et al.  OH-initiated oxidation of benzene , 2002 .

[3]  D. Dockery,et al.  Air pollution and daily mortality in residential areas of Beijing, China. , 1994, Archives of environmental health.

[4]  Olaf Krüger,et al.  Albedo reduction by absorbing aerosols over China , 2004 .

[5]  Young-Joon Kim,et al.  An overview of ACE‐Asia: Strategies for quantifying the relationships between Asian aerosols and their climatic impacts , 2003 .

[6]  T. Cáceres,et al.  Indoor house pollution: Appliance emissions and indoor ambient concentrations , 1983 .

[7]  D. Loomis,et al.  Air pollution and infant mortality in Mexico City. , 1999, Epidemiology.

[8]  David R. Stauffer,et al.  A Multiscale Four-Dimensional Data Assimilation System Applied in the San Joaquin Valley during SARMAP. Part I: Modeling Design and Basic Performance Characteristics , 1995 .

[9]  David Satterthwaite,et al.  Sustainable Cities or Cities that Contribute to Sustainable Development? , 1997, The Earthscan Reader in Sustainable Cities.

[10]  E. Gramsch,et al.  Traffic and seasonal dependence of the light absorption coefficient in santiago de chile. , 2000, Applied optics.

[11]  V. Ramanathan,et al.  Reduction of tropical cloudiness by soot , 2000, Science.

[12]  H. Paerl Enhancement of marine primary production by nitrogen-enriched acid rain , 1985, Nature.

[13]  A. Knap,et al.  Episodic inputs of atmospheric nitrogen to the Sargasso Sea: Contributions to new production and phytoplankton blooms , 1993 .

[14]  S Tong,et al.  Time-Series Analysis of the Relationship Between Air Pollution and Daily Mortality in Beijing , 2003, Wei sheng yan jiu = Journal of hygiene research.

[15]  Ronald G. Prinn,et al.  Linking local air pollution to global chemistry and climate , 2000 .

[16]  David Satterthwaite,et al.  Environmental Problems in an Urbanizing World , 2001 .

[17]  Douglas R. Lawson,et al.  Comparison of Emission Inventory and Ambient Concentration Ratios of CO, NMOG, and NOx in California's South Coast Air Basin , 1992 .

[18]  Delhi . Planning Dept Economic survey of Delhi , 2002 .

[19]  O. Sánchez-Ccoyllo,et al.  The influence of meteorological conditions on the behavior of pollutants concentrations in São Paulo, Brazil. , 2002, Environmental pollution.

[20]  Nelson L. Seaman,et al.  Meteorological modeling for air-quality assessments , 2000 .

[21]  Claudio Silva,et al.  Optimization of the atmospheric pollution monitoring network at Santiago de Chile , 2003 .

[22]  J. Bossert An Investigation of Flow Regimes Affecting the Mexico City Region , 1995 .

[23]  P. Minnis,et al.  CIMAR-5: A Snapshot of the Lower Troposphere over the Subtropical Southeast Pacific. , 2001 .

[24]  Melissa G. Trainer,et al.  Transport and processing of O3 and O3 precursors over the North Atlantic: An overview of the 1993 North Atlantic Regional Experiment (NARE) summer intensive , 1996 .

[25]  B. R. Gurjar,et al.  Air Quality in Selected Megacities , 2004 .

[26]  L. Shao,et al.  Characterization of airborne individual particles collected in an urban area, a satellite city and a clean air area in Beijing, 2001 , 2003 .

[27]  A. Clappier,et al.  An Urban Surface Exchange Parameterisation for Mesoscale Models , 2002 .

[28]  R. Garreaud,et al.  Cold Air Incursions over Subtropical South America: Mean Structure and Dynamics , 2000 .

[29]  J. Mcinerney Bright Lights, Big City , 1984 .

[30]  John S. Evans,et al.  Health Benefits of Air Pollution Control , 2002 .

[31]  Simon A. Levin,et al.  Fragile Dominion: Complexity and the Commons , 1999 .

[32]  P. Koutrakis,et al.  Source Apportionment of PM10 and PM25 in Five Chilean Cities Using Factor Analysis , 2001, Journal of the Air & Waste Management Association.

[33]  G. Carmichael,et al.  The episodic nature of air pollution transport from Asia to North America , 2000 .

[34]  J. Lamarque,et al.  Tropospheric ozone over the tropical Atlantic: A satellite perspective , 2003 .

[35]  G. McRae,et al.  Air Pollution Science in the MCMA: Understanding Source-Receptor Relationships through Emissions Inventories, Measurements, and Modeling , 2002 .

[36]  Thomas J. Smith,et al.  Vehicle traffic as a source of particulate polycyclic aromatic hydrocarbon exposure in the Mexico City metropolitan area. , 2004, Environmental science & technology.

[37]  A. Hanna,et al.  meteorological conditions leading to air-pollution episodes in greater cairo city (egypt) , 2003 .

[38]  G M Böhm,et al.  Association between air pollution and mortality due to respiratory diseases in children in São Paulo, Brazil: a preliminary report. , 1994, Environmental research.

[39]  Stefan Emeis,et al.  Application of a multiscale, coupled MM5/chemistry model to the complex terrain of the VOTALP valley campaign , 2000 .

[40]  John M. DeCicco Fuel Cell Vehicles: Technology, Market, and Policy Issues , 2002 .

[41]  M. Fenn,et al.  Urban Air Pollution and Forests , 2002, Ecological Studies.

[42]  J. Galloway,et al.  Episodic atmospheric nitrogen deposition to oligotrophic oceans , 1992, Nature.

[43]  A study of the aerosol of Santiago de Chile—II. Mass extinction coefficients, visibilities and Ångström exponents , 1993 .

[44]  W. Palma,et al.  An intervention analysis of air quality data at Santiago, Chile , 2000 .

[45]  E. Cowling,et al.  Introduction to special section: Southern Oxidants Study Nashville/Middle Tennessee Ozone Study , 1998 .

[46]  D. Loomis,et al.  Mortality and ambient fine particles in southwest Mexico City, 1993-1995. , 1998, Environmental health perspectives.

[47]  I. J. Ackermann,et al.  Modeling the formation of secondary organic aerosol within a comprehensive air quality model system , 2001 .

[48]  J C Chow,et al.  Measurement methods to determine compliance with ambient air quality standards for suspended particles. , 1995, Journal of the Air & Waste Management Association.

[49]  Oleg Dubovik,et al.  Microphysical and optical properties of aerosol particles in urban zone during ESCOMPTE , 2003 .

[50]  Yun Qian,et al.  Regional climatic effects of anthropogenic aerosols? The case of southwestern China , 2000 .

[51]  C. Blanchard METHODS FOR ATTRIBUTING AMBIENT AIR POLLUTANTS TO EMISSION SOURCES , 1999 .

[52]  T. S. Panwar,et al.  Predicted and measured concentrations of traffic carbon monoxide over Delhi , 1990 .

[53]  R. Pielke,et al.  A comprehensive meteorological modeling system—RAMS , 1992 .

[54]  J. L. Martinez,et al.  The IMADA-AVER Boundary Layer Experiment in the Mexico City Area , 1998 .

[55]  Ulrich Platt,et al.  A fast H 2 O total column density product from GOME – Validation with in-situ aircraft measurements , 2003 .

[56]  C. K. Varshney,et al.  Ozone pollution in the urban atmosphere of Delhi , 1992 .

[57]  C. Sharma,et al.  Inventory Of GHGs And Other Urban Pollutants From Energy Sector In Delhi And Calcutta , 2002 .

[58]  Jung-Hun Woo,et al.  The contribution of megacities to regional sulfur pollution in Asia , 2003 .

[59]  W. Mcdonnell,et al.  Long-term inhalable particles and other air pollutants related to mortality in nonsmokers. , 1999, American journal of respiratory and critical care medicine.

[60]  Y. Maeda,et al.  Atmospheric alcohols and aldehydes concentrations measured in Osaka, Japan and in Sao Paulo, Brazil , 2001 .

[61]  P. Goyal,et al.  Predicted and observed concentrations of SO2, SPM and NOχ over Delhi , 1990 .

[62]  W. H. Smith Air pollution and forests. , 1981 .

[63]  G. Bishop,et al.  Emissions reductions as a result of automobile improvement. , 2003, Environmental science & technology.

[64]  P. Koutrakis,et al.  The composition and sources of PM2.5 organic aerosol in two urban areas of Chile , 2002 .

[65]  Teri Environmental Aspects Of Energy Use In Large Indian Metropolises Volume Ii Draft Final Report , 1997 .

[66]  D. D. Lane,et al.  Performance evaluation of the portable MiniVOL particulate matter sampler , 2001 .

[67]  J. Zhang,et al.  Ambient sulfate concentration and chronic disease mortality in Beijing. , 2000, The Science of the total environment.

[68]  C. Gui Study on the associations between ambient air pollutant and hospital outpatient visit or emergency room visit in Beijing , 2003 .

[69]  P. Artaxo,et al.  Wintertime and summertime São Paulo aerosol source apportionment study , 2001 .

[70]  Kebin He,et al.  URBAN AIR POLLUTION IN CHINA: Current Status, Characteristics, and Progress , 2002 .

[71]  B. Rappenglück,et al.  The Evolution of Photochemical Smog in the Metropolitan Area of Santiago de Chile , 2000 .

[72]  Ashutosh Kumar Singh,et al.  Ozone distribution in the urban environment of Delhi during winter months , 1997 .

[73]  J. Lelieveld,et al.  The Indian Ocean Experiment: Widespread Air Pollution from South and Southeast Asia , 2001, Science.

[74]  Paul J. Crutzen,et al.  New Directions: The growing urban heat and pollution "island" effect - impact on chemistry and climate , 2004 .

[75]  E. Fujita,et al.  Overview of the 1997 Southern California Ozone Study (SCOS97-NARSTO) , 2003 .

[76]  D. M. Cunnold,et al.  Evidence for Substantial Variations of Atmospheric Hydroxyl Radicals in the Past Two Decades , 2001, Science.

[77]  Tan Zhu,et al.  Designing monitoring networks to represent outdoor human exposure. , 2002, Chemosphere.

[78]  A. Stohl,et al.  Atmospheric Chemistry and Physics the North Atlantic Oscillation Controls Air Pollution Transport to the Arctic , 2003 .

[79]  Steffen Beirle,et al.  Weekly cycle of NO 2 by GOME measurements: a signature of anthropogenic sources , 2003 .

[80]  K. Thundiyil Rising temperatures and expanding megacities : improving air quality in Mexico City through Urban Heat Island mitigation , 2003 .

[81]  E. Atlas The Tropospheric Ozone Production about the Spring Equinox (TOPSE) Experiment: Introduction and Overview , 2001 .

[82]  Joseph M. Sussman,et al.  Design of Robust Emission Reduction Strategies for Road-Based Public Transportation in Mexico City, Mexico: Multiattribute Trade-Off Analysis for Metropolitan Area , 2004 .

[83]  J. Logan,et al.  Effect of rising Asian emissions on surface ozone in the United States , 1999 .

[84]  P. Kasibhatla,et al.  Growth of Continental-Scale Metro-Agro-Plexes, Regional Ozone Pollution, and World Food Production , 1994, Science.

[85]  Yu Song,et al.  [Source apportionment on fine particles in Beijing]. , 2002, Huan jing ke xue= Huanjing kexue.

[86]  J. Lelieveld,et al.  Interannual variability and trend of CH4 lifetime as a measure for OH changes in the 1979–1993 time period , 2003 .

[87]  R. Garreaud,et al.  Coastal Lows along the Subtropical West Coast of South America: Mean Structure and Evolution , 2002 .

[88]  Stuart A. Penkett,et al.  Preface [to special section on North Atlantic Regional Experiment (NARE II)] , 1998 .

[89]  David D. Nelson,et al.  Cross road and mobile tunable infrared laser measurements of nitrous oxide emissions from motor vehicles , 2000 .

[90]  D. Dockery,et al.  Association of air pollution with hospital outpatient visits in Beijing. , 1995, Archives of environmental health.

[91]  Kebin He,et al.  The characteristics of PM2.5 in Beijing, China , 2001 .

[92]  J. Watson Visibility: Science and Regulation , 2002, Journal of the Air & Waste Management Association.

[93]  H. Ke Characterization of Urban Air Pollution Sources , 2003 .

[94]  Gurumurthy Ramachandran,et al.  THE CAUSES AND CONSEQUENCES OF PARTICULATE AIR POLLUTION IN URBAN INDIA: A Synthesis of the Science , 2000 .

[95]  M. Bergin,et al.  Impact of atmospheric aerosol light scattering and absorption on terrestrial net primary productivity , 2002 .

[96]  F. Giorgi,et al.  Is ozone pollution affecting crop yields in China? , 1999 .

[97]  David J. Briggs,et al.  United Nations Environment Program.: Environmental data report (2nd ed.) Oxford: Basil Blackwell, 1989. 547 pp. £45.00 paperback , 1990 .

[98]  P. Koutrakis,et al.  Source apportionment of urban particulate aliphatic and polynuclear aromatic hydrocarbons (PAHs) using multivariate methods. , 2001, Environmental science & technology.

[99]  Robin L. Dennis,et al.  NARSTO critical review of photochemical models and modeling , 2000 .

[100]  I. Barnes,et al.  FT–IR study of the ring-retaining products from the reaction of OH radicals with phenol, o-, m-, and p-cresol , 2002 .

[101]  D. Blake,et al.  Impact of the leakage of liquefied petroleum gas (LPG) on Santiago Air Quality , 2001 .

[102]  R. Derwent,et al.  Atmospheric Chemistry and Physics Protocol for the Development of the Master Chemical Mechanism, Mcm V3 (part B): Tropospheric Degradation of Aromatic Volatile Organic Compounds , 2022 .

[103]  D. Dockery,et al.  Particulate air pollution as a predictor of mortality in a prospective study of U.S. adults. , 1995, American journal of respiratory and critical care medicine.

[104]  James F. Meagher,et al.  Ozone formation and transport in southeastern United States: Overview of the SOS Nashville/Middle Tennessee Ozone Study , 1998 .

[105]  A. Trier,et al.  A time series investigation of visibility in an urban atmosphere - I , 1994 .

[106]  Gene Bazan Our Ecological Footprint: Reducing Human Impact on the Earth , 1997 .

[107]  P. Roberts,et al.  Mathematical modeling of photochemical air pollution. II. A model and inventory of pollutant emissions. , 1974, Atmospheric environment.

[108]  I. Romieu,et al.  Association between Levels of Fine Particulate and Emergency Visits for Pneumonia and other Respiratory Illnesses among Children in Santiago, Chile. , 1999, Journal of the Air & Waste Management Association.

[109]  M. Memmesheimer,et al.  Modal aerosol dynamics model for Europe: development and first applications , 1998 .

[110]  William L. Chameides,et al.  Aerosol radiative, physical, and chemical properties in Beijing during June 1999 , 2001 .

[111]  Thomas W. Kirchstetter,et al.  Impact of California Reformulated Gasoline On Motor Vehicle Emissions. 1. Mass Emission Rates , 1999 .

[112]  M. Molina,et al.  Air quality in the Mexico megacity : an integrated assessment , 2002 .

[113]  R. Garreaud,et al.  Meteorological air pollution potential for Santiago, Chile: Towards an objective episode forecasting , 1995, Environmental monitoring and assessment.

[114]  A. Nenes,et al.  ISORROPIA: A New Thermodynamic Equilibrium Model for Multiphase Multicomponent Inorganic Aerosols , 1998 .

[115]  A. Volz-Thomas,et al.  Schauinsland Ozone Precursor Experiment (SLOPE96): Scientific background and main results , 2000 .

[116]  S. Ruiz-Velasco,et al.  Daily respiratory mortality and PM10 pollution in Mexico City: importance of considering place of death. , 2000, The European respiratory journal.

[117]  Frank McGovern,et al.  The 2nd Aerosol Characterization Experiment (ACE-2): general overview and main results , 2000 .

[118]  D. Blake,et al.  Chemical characteristics of continental outflow from Asia to the troposphere over the western Pacific Ocean during February‐March 1994: Results from PEM‐West B , 1997 .

[119]  Andrés Rivera,et al.  Rapid urban growth, land-use changes and air pollution in Santiago, Chile , 1999 .

[120]  Roberto Casati,et al.  On-road measurement of particle emission in the exhaust plume of a diesel passenger car. , 2003, Environmental science & technology.

[121]  M. C. Dodge,et al.  A photochemical kinetics mechanism for urban and regional scale computer modeling , 1989 .

[122]  Bonyoung Koo,et al.  Integrated approaches to modeling the organic and inorganic atmospheric aerosol components , 2003 .

[123]  E. Robinson,et al.  The Mauna Loa Observatory photochemistry experiment , 1992 .

[124]  M. Jenkin,et al.  Evaluation of detailed aromatic mechanisms (MCMv3 and MCMv3.1) against environmental chamber data , 2004 .

[125]  Philip B. Russell,et al.  Aerosol properties and radiative effects in the United States East Coast haze plume: An overview of the Tropospheric Aerosol Radiative Forcing Observational Experiment (TARFOX) , 1999 .

[126]  D. Grosjean,et al.  Urban air pollution in Brazil: acetaldehyde and other carbonyls , 1990 .

[127]  J. Burrows,et al.  Tropospheric sulfur dioxide observed by the ERS‐2 GOME instrument , 1998 .

[128]  J. Jiménez,et al.  [Daily mortality in Santiago and its relationship with air pollution]. , 1999, Revista medica de Chile.

[129]  A. Hofzumahaus,et al.  Introduction to Special Section: Photochemistry Experiment in BERLIOZ , 2003 .

[130]  R. Burnett,et al.  The effect of the urban ambient air pollution mix on daily mortality rates in 11 Canadian cities. , 1998, Canadian journal of public health = Revue canadienne de sante publique.

[131]  B. Doddridge,et al.  Transport of ozone and pollutants from North America to the North Atlantic Ocean during the 1996 Atmosphere/Ocean Chemistry Experiment (AEROCE) intensive , 1999 .

[132]  J. Burrows,et al.  Atmospheric Chemistry and Physics Transport and Build-up of Tropospheric Trace Gases during the Minos Campaign: Comparision of Gome, in Situ Aircraft Measurements and Match-mpic-data , 2022 .

[133]  Judith C. Chow,et al.  Review of volatile organic compound source apportionment by chemical mass balance , 2001 .

[134]  P. Perez,et al.  Statistical modelling and prediction of atmospheric pollution by particulate material : two nonparametric approaches , 2001 .

[135]  A. Stohl,et al.  A textbook example of long‐range transport: Simultaneous observation of ozone maxima of stratospheric and North American origin in the free troposphere over Europe , 1999 .

[136]  Ulrich Platt,et al.  Primary and Secondary Glyoxal Formation from Aromatics: Experimental Evidence for the Bicycloalkyl−Radical Pathway from Benzene, Toluene, and p-Xylene , 2001 .

[137]  J. Brook,et al.  Identification of the major sources contributing to PM2.5 observed in Toronto. , 2003, Environmental science & technology.

[138]  A. Gertler,et al.  Comparison of the SCAQS Tunnel Study with Other On Road Vehicle Emission Data , 1990 .

[139]  J. Goldemberg,et al.  CETESB Companhia de Tecnologia de Saneamento Ambiental , 2004 .

[140]  Chhemendra Sharma,et al.  Inventory Of GHGs And Other Urban Pollutants From Agriculture and Waste Sectors In Delhi And Calcutta , 2002 .

[141]  J. A. Listorti Is environmental health really a part of economic development - or only an afterthought? , 1999 .

[142]  Sandy Cairncross,et al.  The poor die young : housing and health in Third World cities , 1992 .

[143]  Héctor Jorquera Air quality at Santiago, Chile: a box modeling approach—I. Carbon monoxide, nitrogen oxides and sulfur dioxide , 2002 .

[144]  E. Atlas,et al.  The Mauna Loa Observatory Photochemistry Experiment: Introduction , 1996 .

[145]  John H. Seinfeld,et al.  Photochemical modeling of the Southern California air quality study , 1993 .

[146]  J. Hansen,et al.  Climate Effects of Black Carbon Aerosols in China and India , 2002, Science.

[147]  David B. Kittelson,et al.  Nanoparticle emissions on Minnesota highways , 2004 .

[148]  H. Jorquera Air quality at Santiago, Chile: a box modeling approach II. PM2.5, coarse and PM10 particulate matter fractions , 2002 .

[149]  Barbara Zielinska,et al.  Diurnal and Weekday Variations in the Source Contributions of Ozone Precursors in California’s South Coast Air Basin , 2003, Journal of the Air & Waste Management Association.

[150]  Rosenfeld,et al.  Suppression of rain and snow by urban and industrial air pollution , 2000, Science.

[151]  L. Kleinman,et al.  An overview of the airborne activities during the Southern Oxidants Study (SOS) 1995 Nashville/Middle Tennessee Ozone Study , 1998 .

[152]  J C Chow,et al.  Validation of the chemical mass balance receptor model applied to hydrocarbon source apportionment in the southern california air quality study. , 1994, Environmental science & technology.

[153]  J. Seinfeld,et al.  Development of a second-generation mathematical model for Urban air pollution—I. Model formulation , 1982 .

[154]  Bernhard Vogel,et al.  Sensitivity of photooxidant production in the Milan Basin: An overview of results from a EUROTRAC‐2 Limitation of Oxidant Production field experiment , 2002 .

[155]  John B. Heywood,et al.  ON THE ROAD IN 2020 - A LIFE-CYCLE ANALYSIS OF NEW AUTOMOBILE TECHNOLOGIES , 2000 .

[156]  Judith C. Chow,et al.  Receptor model and emissions inventory source apportionments of nonmethane organic gases in California's San Joaquin valley and San Francisco bay area , 1995 .

[157]  S. Zhong,et al.  Meteorological factors associated with inhomogeneous ozone concentrations within the Mexico City basin , 1998 .

[158]  G. McRae,et al.  Modeling ozone photochemistry and evaluation of hydrocarbon emissions in the Mexico City metropolitan area , 2004 .

[159]  D. Dockery,et al.  Air pollution and mortality in elderly people: a time-series study in Sao Paulo, Brazil. , 1995, Archives of environmental health.

[160]  S I Bangdiwala,et al.  Ozone, suspended particulates, and daily mortality in Mexico City. , 1997, American journal of epidemiology.

[161]  J. Galloway ANTHROPOGENIC MOBILIZATION OF SULPHUR AND NITROGEN: Immediate and Delayed Consequences , 1996 .

[162]  M. Molina,et al.  The MCMA Transportation System: Mobility and Air Pollution , 2002 .

[163]  John H. Seinfeld,et al.  Development of a second-generation mathematical model for urban air pollution—II. Evaluation of model performance , 1983 .

[164]  Division on Earth Air Quality Management in the United States , 2004 .

[165]  J D Spengler,et al.  Estimating the mortality impacts of particulate matter: what can be learned from between-study variability? , 1999, Environmental health perspectives.

[166]  G. Mcgranahan Household environmental problems in low-income cities , 1993 .

[167]  John P. Burrows,et al.  New Directions: New Developments in Satellite Capabilities for Probing the Chemistry of the Troposphere☆ , 2003 .

[168]  Brett C. Singer,et al.  A fuel-based inventory of motor vehicle exhaust emissions in the Los Angeles area during summer 1997 , 2000 .

[169]  P. Padhy,et al.  Total volatile organic compounds in the urban environment of Delhi. , 1998, Journal of the Air & Waste Management Association.

[170]  M. Molina,et al.  Air Quality in the Mexico Megacity , 2002 .

[171]  Y. Qian,et al.  Decreasing trends in sunshine duration over China for 1954–1998: Indication of increased haze pollution? , 2002 .

[172]  G. Streit,et al.  Atmospheric chemistry of aldehydes: enhanced peroxyacetyl nitrate formation from ethanol-fueled vehicular emissions. , 1988, Environmental science & technology.

[173]  Raúl Benítez Zenteno Comentarios en la presentación del libro La Ciudad de México [en el] fin del segundo milenio, de Gustavo Garza (coord.), 29 de noviembre de 2000, en El Colegio de México , 2001 .

[174]  E. Atlas,et al.  Effect of petrochemical industrial emissions of reactive alkenes and NOx on tropospheric ozone formation in Houston, Texas , 2003 .

[175]  G. Santos Road Pricing on the Basis of Congestion Costs: Consistent Results from Two Historic U.K. Towns , 2000 .

[176]  Daniel A. Jaffe,et al.  Influence of Asian emissions on the composition of air reaching the north western United States , 1999 .

[177]  Inhalable urban atmospheric particulate matter in a semi-arid climate: The case of Santiago De Chile , 1987 .

[178]  Fu Li-xin Integrated Analysis of Urban Air Pollution Control , 2003 .

[179]  H. Horvath,et al.  A study of the aerosol of Santiago de Chile III: Light absorption measurements , 1997 .

[180]  X. Xu,et al.  Synergistic effects of air pollution and personal smoking on adult pulmonary function. , 1998, Archives of environmental health.

[181]  David Henry,et al.  Development of an operational model-based warning system for tropospheric ozone concentrations in Bordeaux, France , 2004, Environ. Model. Softw..

[182]  C. Stevens,et al.  Impact of Nitrogen Deposition on the Species Richness of Grasslands , 2004, Science.

[183]  Xiping Xu,et al.  Acute effects of total suspended particles and sulfur dioxides on preterm delivery: a community-based cohort study. , 1995, Archives of environmental health.

[184]  X. Bian,et al.  Boundary layer evolution and regional‐scale diurnal circulations over the and Mexican plateau , 2000 .

[185]  Zhou Jin Study on the Association Between Ambient Air Quality and Daily Death in Beijing , 2003 .

[186]  Jitendra J. Shah,et al.  Urban air quality management strategy in Asia : guidebook , 1997 .

[187]  A. Trier Observations on inhalable atmospheric particulates in Santiago, Chile , 1984 .

[188]  D. Lowenthal,et al.  A preliminary apportionment of the sources of ambient PM10, PM2.5, and VOCs in Cairo , 2002 .

[189]  M. Préndez,et al.  Elemental Composition of Airborne Particulate Matter from Santiago City, Chile, 1976 , 1984 .

[190]  Jack G. Calvert,et al.  The mechanisms of atmospheric oxidation of aromatic hydrocarbons , 2002 .

[191]  J. Arey,et al.  Products of the OH radical-initiated reaction of 3-hexene-2,5-dione. , 2001, Environmental science & technology.

[192]  Jimy Dudhia,et al.  Development of a next-generation regional weather research and forecast model. , 2001 .

[193]  Tan Zhu,et al.  Receptor modeling application framework for particle source apportionment. , 2002, Chemosphere.

[194]  J. Burrows,et al.  Rapid intercontinental air pollution transport associated with a meteorological bomb , 2003 .

[195]  L. Lave,et al.  Effect of the Fine Fraction of Particulate Matter versus the Coarse Mass and Other Pollutants on Daily Mortality in Santiago, Chile , 2000, Journal of the Air & Waste Management Association.

[196]  H. Akimoto Global Air Quality and Pollution , 2003, Science.

[197]  John C. Gille,et al.  Transport and Chemical Evolution over the Pacific (TRACE-P) aircraft mission: Design, execution, and first results , 2003 .

[198]  G. Bishop,et al.  On-Road Remote Sensing of Vehicle Emissions in Mexico , 1997 .

[199]  R. Pandey,et al.  Outdoor air pollution and emergency room visits at a hospital in Delhi. , 2002, The Indian journal of chest diseases & allied sciences.

[200]  C. D. Alonso,et al.  São Paulo aerosol characterization study. , 1997, Journal of the Air & Waste Management Association.

[201]  Richard G. Derwent,et al.  Radiative forcing in the 21st century due to ozone changes in the troposphere and the lower stratosphere , 2003 .

[202]  T. L. Schneider,et al.  Climate forcing due to tropospheric and stratospheric ozone , 1999 .

[203]  T. Dawson,et al.  Urbanization effects on tree growth in the vicinity of New York City , 2003, Nature.

[204]  G. Garza Uncontrolled air pollution in Mexico City , 1996 .

[205]  H. Horvath,et al.  The relationship between outdoor and indoor soot concentrations in an urban environment , 1989 .

[206]  Francisco Álvarez Inventario de Emisiones de Fuentes Móviles para el área Metropolitana de Monterrey Basado en la Experiencia de la Zona Metropilitana del Valle de México-Edición Única , 2004 .

[207]  Paul J. Crutzen,et al.  New Directions: Atmospheric Brown “Clouds”☆ , 2003 .

[208]  Michael J. Pilling,et al.  Development of a detailed chemical mechanism (MCMv3.1) for the atmospheric oxidation of aromatic hydrocarbons , 2004 .

[209]  W. Stockwell,et al.  The second generation regional acid deposition model chemical mechanism for regional air quality modeling , 1990 .

[210]  H. Matsushita,et al.  Polynuclear Aromatic Hydrocarbon Concentration and Mutagenicity of Airborne Particles in Urban Air: Comparison of Tokyo Area and Santiago , 2002 .

[211]  M. Molina,et al.  Forces Driving Pollutant Emissions in the MCMA , 2002 .

[212]  I. Schifter,et al.  Remote sensing study of emissions from motor vehicles in the Metropolitan Area of Mexico City. , 2003, Environmental science & technology.

[213]  Zhang Shuyu,et al.  A biogenic volatile organic compounds emission inventory for Beijing , 2003 .

[214]  S. C. Liu,et al.  Case study of the effects of atmospheric aerosols and regional haze on agriculture: an opportunity to enhance crop yields in China through emission controls? , 1999, Proceedings of the National Academy of Sciences of the United States of America.

[215]  E. M. Bailey,et al.  Markets for Clean Air: The U.S. Acid Rain Program , 2000 .

[216]  J. Seinfeld,et al.  Mathematical modeling of photochemical air pollution--3. Evaluation of the model. , 1974, Atmospheric environment.

[217]  J. Seinfeld,et al.  Secondary organic aerosol 1. Atmospheric chemical mechanism for production of molecular constituents , 2002 .

[218]  A. Stohl,et al.  Around the world in 17 days - hemispheric-scale transport of forest fire smoke from Russia in May 2003 , 2004 .

[219]  D. Dockery,et al.  An association between air pollution and mortality in six U.S. cities. , 1993, The New England journal of medicine.

[220]  Patricio Perez,et al.  Prediction of NO and NO2 concentrations near a street with heavy traffic in Santiago, Chile , 2001 .

[221]  Who Collaborating Research on the relationship between air pollution and daily mortality in Beijing urban residents in 1990~1991 , 1995 .

[222]  Timothy J Lomax,et al.  HIGHWAY CONGESTION WORSENS : TRAFFIC SOLUTIONS AND IMPACTS EXAMINED , 2003 .

[223]  G. Bishop,et al.  Emission Characteristics of Mexico City Vehicles , 1992 .

[224]  J. Seinfeld,et al.  Atmospheric gas−aerosol equilibrium. II: Analysis of common approximations and activity coefficient calculation methods , 1993 .

[225]  P. Barber,et al.  On-road measurement of automotive particle emissions by ultraviolet lidar and transmissometer: instrument. , 2003, Environmental science & technology.

[226]  R. Bose ENERGY DEMAND AND ENVIRONMENTAL IMPLICATIONS IN URBAN TRANSPORT - CASE OF DELHI , 1996 .

[227]  Ulrich Platt,et al.  Satellite detection of a continental‐scale plume of nitrogen oxides from boreal forest fires , 2001 .

[228]  Jung-Hun Woo,et al.  Measurements of sulfur dioxide, ozone and ammonia concentrations in Asia, Africa, and South America using passive samplers , 2003 .