Lithium–oxygen batteries have been considerably researched due to their potential for high energy density compared to some rechargeable batteries. However, it is known that the stability of a carbon-based oxygen electrode is insufficient owing to the promotion of carbonate formation, which results in capacity fading and large overpotential in lithium–oxygen batteries. To improve the chemical stability in organic-based electrolytes, alternative electrocatalyst support materials are required. The Ti–O crystal system appears to provide a good compromise between electrochemical performance and cost and is thus an interesting material for further investigation. Here, we investigate a carbon-free electrode with the goal of identifying routes for its successful optimization. To replace carbon materials as an electrocatalyst support, Magneli Ti4O7 nanospheres were synthesized from anatase TiO2 nanospheres via a controlled thermochemical reduction. The Magneli Ti4O7 nanospheres demonstrated effective overpotential...