Molecular‐beam‐epitaxy GaAs regrowth with clean interfaces by arsenic passivation

Clean interfaces between GaAs layers grown by molecular‐beam epitaxy (MBE) have been achieved by deposition of arsenic on the surface of the first layer grown, before removing it from the vacuum. Secondary ion mass spectroscopy, deep level transient spectroscopy, and capacitance‐voltage carrier profiling show that this arsenic passivation procedure results in no measurable impurity incorporation, no deep levels, and no perturbation of carrier profiles in either n‐type or p‐type GaAs growth/regrowth interfaces after exposure to air. This is in contrast to growth over nonpassivated etched surfaces which showed large perturbations in free carrier profiles, deep level densities, and impurity incorporation at the interface. This demonstrates that nearly ideal growth/regrowth interfaces are achievable in MBE if impurity incorporation and nonstoichiometry are controlled.

[1]  N. Newman,et al.  Aluminum Schottky barrier formation on arsenic capped and heat cleaned MBE GaAs(100) , 1984 .

[2]  T. Nakagawa,et al.  Arsenic passivation: a possible remedy for MBE growth-interruption problems , 1984 .

[3]  T. Jackson,et al.  Photoelectrochemical passivation of GaAs surfaces , 1983 .

[4]  L. Eastman,et al.  Carrier compensation at interfaces formed by molecular beam epitaxy , 1982 .

[5]  A. Kahn Comparative LEED studies of AlxGa1-xAs(110) and GaAs(110) Al(vartheta) , 1982 .

[6]  S. P. Kowalczyk,et al.  Protection of molecular beam epitaxy grown AlxGa1−xAs epilayers during ambient transfer , 1981 .

[7]  P. Newman,et al.  Low cost spinner for semiconductor surface preparation prior to MBE growth , 1981 .

[8]  M. Bettini,et al.  Tellurium coating of PbTe surfaces , 1979 .

[9]  S. Ohr Elastic fields of a dislocation loop near a stress‐free surface , 1978 .

[10]  K. Nakai,et al.  Growth of Iron‐Doped Epitaxial Layers for GaAs Field Effect Transistors , 1977 .

[11]  M. Ozeki,et al.  Photo-Ionization Cross Section Measurements of Deep Levels in Iron Doped GaAs , 1976 .

[12]  D. Lang,et al.  A study of deep levels in GaAs by capacitance spectroscopy , 1975 .

[13]  A. Y. Cho,et al.  Interface and doping profile characteristics with molecular‐beam epitaxy of GaAs: GaAs voltage varactor , 1974 .

[14]  Lionel C. Kimerling,et al.  Influence of deep traps on the measurement of free‐carrier distributions in semiconductors by junction capacitance techniques , 1974 .