Complex formation in pyrosulfate melts. 2. Calorimetric investigations of the [vanadium pentoxide - potassium pyrosulfate] systems V2O5-K2S2O7, V2O5.K2S2O7-K2SO4, V2O5.2K2S2O7-K2SO4, and V2O5.3K2S2O7-K2SO4 at 430.degree.C