Biosorption of Pb(II) ions from aqueous solution using alginates extracted from Djiboutian seaweeds and deposited on silica particles

Abstract High-molecular alginates were extracted from Djiboutian brown seaweeds, Sargassum sp. (S) and Turbinaria (T) and isolated as sodium salts in 31.0 and 42.7% yield by weight. 1H NMR analysis of the uronic acid block-structure indicates mannuronic/guluronic M/G ratios of 0.49 and 3.0 for the alginates extracts, respectively. The resulting alginates were deposited onto native Aerosil 200 silica, amine-functionalized and carboxyl-functionalized silica particles to enhance the mechanical strength providing Alg.(T/S)+SiO2) Alg.(T/S)+SiO2NH2) and Alg.(T)+SiO2CO2H) composites. Taking Pb(II) as examples for toxic heavy metal ions, the effects of the pH, adsorption kinetics, and isotherms have been studied systematically. The best uptake achieved was 585 mg Pb2+ ion/g using Alg.S+SiO2NH2. Furthermore, the Pb(II) ions were successfully desorbed in several cycles from Alg.T+SiO2 using 0.5 M hydrochloric acid. Therefore, Alg.T+SiO2 may be considered as a low-cost biosorbent that quickly adsorbs and easily desorbs analyte lead ions. A comparison of the adsorption capacity of our biopolymer-coated particles with that of other adsorbents reported in the literature reveals that our materials are among the best performing for the adsorption of Pb(II).