In situ exsolved FeNi3 nanoparticles on nickel doped Sr2Fe1.5Mo0.5O6−δ perovskite for efficient electrochemical CO2 reduction reaction

In situ exsolved FeNi3 nanoparticles on nickel doped Sr2Fe1.5Mo0.5O6−δ perovskite greatly enhance the performance of the electrochemical CO2 reduction reaction.

[1]  Tong Liu,et al.  In-situ growth of metallic nanoparticles on perovskite parent as a hydrogen electrode for solid oxide cells , 2018, Journal of Power Sources.

[2]  Xiaoming Sun,et al.  Micro‐/Nanohoneycomb Solid Oxide Electrolysis Cell Anodes with Ultralarge Current Tolerance , 2018, Advanced Energy Materials.

[3]  X. Bao,et al.  Enhancing CO2 electrolysis performance with vanadium-doped perovskite cathode in solid oxide electrolysis cell , 2018, Nano Energy.

[4]  Z. Lü,et al.  A Highly Efficient and Robust Perovskite Anode with Iron-Palladium Co-exsolutions for Intermediate-Temperature Solid-Oxide Fuel Cells. , 2018, ChemSusChem.

[5]  Juan Wang,et al.  Exploration of Co-Fe alloy precipitation and electrochemical behavior hysteresis using Lanthanum and Cobalt co-substituted SrFeO3-δ SOFC anode , 2018, Electrochimica Acta.

[6]  Jiewei Yin,et al.  Roles of FeNi nanoparticles and SrLaFeO4 substrate in the performance and reliability of a composite anode prepared through in-situ exsolution for intermediate temperature solid oxide fuel cells (I) , 2018 .

[7]  S. Barnett,et al.  Ni-Substituted Sr(Ti,Fe)O3 SOFC Anodes: Achieving High Performance via Metal Alloy Nanoparticle Exsolution , 2018 .

[8]  J. Lemmon,et al.  Highly efficient electrochemical reforming of CH4/CO2 in a solid oxide electrolyser , 2018, Science Advances.

[9]  X. Bao,et al.  Enhancing electrocatalytic CO 2 reduction in solid oxide electrolysis cell with Ce 0.9 Mn 0.1 O 2−δ nanoparticles-modified LSCM-GDC cathode , 2018 .

[10]  David N. Miller,et al.  Demonstration of chemistry at a point through restructuring and catalytic activation at anchored nanoparticles , 2017, Nature Communications.

[11]  Xinran Chen,et al.  Mixed-Conductor Sr2Fe1.5Mo0.5O6−δ as Robust Fuel Electrode for Pure CO2 Reduction in Solid Oxide Electrolysis Cell , 2017 .

[12]  J. Lemmon,et al.  A novel fuel electrode enabling direct CO2 electrolysis with excellent and stable cell performance , 2017 .

[13]  Xuefeng Zhu,et al.  Perovskites decorated with oxygen vacancies and Fe–Ni alloy nanoparticles as high-efficiency electrocatalysts for the oxygen evolution reaction , 2017 .

[14]  M. Li,et al.  Enhancing Perovskite Electrocatalysis of Solid Oxide Cells Through Controlled Exsolution of Nanoparticles. , 2017, ChemSusChem.

[15]  H. Jeong,et al.  Exsolution trends and co-segregation aspects of self-grown catalyst nanoparticles in perovskites , 2017, Nature Communications.

[16]  Kui Xie,et al.  Enhancing CO2 electrolysis through synergistic control of non-stoichiometry and doping to tune cathode surface structures , 2017, Nature Communications.

[17]  Lei Xu,et al.  A robust high performance cobalt-free oxygen electrode La 0.5 Sr 0.5 Fe 0.8 Cu 0.15 Nb 0.05 O 3−δ for reversible solid oxide electrochemical cell , 2017 .

[18]  Tong Liu,et al.  Exsolved Fe–Ni nano-particles from Sr2Fe1.3Ni0.2Mo0.5O6 perovskite oxide as a cathode for solid oxide steam electrolysis cells , 2016 .

[19]  David N. Miller,et al.  Switching on electrocatalytic activity in solid oxide cells , 2016, Nature.

[20]  L. Gu,et al.  High-Performance Anode Material Sr2FeMo0.65Ni0.35O6-δ with In Situ Exsolved Nanoparticle Catalyst. , 2016, ACS nano.

[21]  Jingli Luo,et al.  Highly Stable and Efficient Catalyst with In Situ Exsolved Fe–Ni Alloy Nanospheres Socketed on an Oxygen Deficient Perovskite for Direct CO2 Electrolysis , 2016 .

[22]  Jun Yu Li,et al.  New Opportunity for in Situ Exsolution of Metallic Nanoparticles on Perovskite Parent. , 2016, Nano letters.

[23]  Xiaomin Zhang,et al.  Insight into the oxygen reduction reaction on the LSM|GDC interface of solid oxide fuel cells through impedance spectroscopy analysis , 2016 .

[24]  M. Koper,et al.  In Situ Spectroscopic Study of CO2 Electroreduction at Copper Electrodes in Acetonitrile , 2016 .

[25]  Jingli Luo,et al.  Double-Layered Perovskite Anode with in Situ Exsolution of a Co–Fe Alloy To Cogenerate Ethylene and Electricity in a Proton-Conducting Ethane Fuel Cell , 2016 .

[26]  Ning Wang,et al.  Performance enhancement of solution impregnated nanostructured La0.8Sr0.2Co0.8Ni0.2O3-δ oxygen electrode for intermediate temperature solid oxide electrolysis cells , 2016 .

[27]  Michele Pavone,et al.  First-Principles Design of New Electrodes for Proton-Conducting Solid-Oxide Electrochemical Cells: A-Site Doped Sr2Fe1.5Mo0.5O6−δ Perovskite , 2016 .

[28]  M. Mogensen,et al.  Evolution of the electrochemical interface in high-temperature fuel cells and electrolysers , 2016, Nature Energy.

[29]  Satoshi Hashigami,et al.  Feasibility of alternative electrode materials for high temperature CO 2 reduction on solid oxide electrolysis cell , 2015 .

[30]  Dragos Neagu,et al.  Nano-socketed nickel particles with enhanced coking resistance grown in situ by redox exsolution , 2015, Nature Communications.

[31]  B. Pan,et al.  Ultrathin Spinel-Structured Nanosheets Rich in Oxygen Deficiencies for Enhanced Electrocatalytic Water Oxidation. , 2015, Angewandte Chemie.

[32]  Zhe Zhao,et al.  Enhanced oxygen reduction activity and solid oxide fuel cell performance with a nanoparticles-loaded cathode. , 2015, Nano letters.

[33]  M. Hävecker,et al.  Enhancing Electrochemical Water-Splitting Kinetics by Polarization-Driven Formation of Near-Surface Iron(0): An In Situ XPS Study on Perovskite-Type Electrodes , 2014, Angewandte Chemie.

[34]  Yong Zhang,et al.  Chromate cathode decorated with in-situ growth of copper nanocatalyst for high temperature carbon dioxide electrolysis , 2014 .

[35]  Siwei Wang,et al.  Releasing metal catalysts via phase transition: (NiO)0.05-(SrTi0.8Nb0.2O3)0.95 as a redox stable anode material for solid oxide fuel cells. , 2014, ACS applied materials & interfaces.

[36]  David W. Rooney,et al.  Investigation into the effect of Fe-site substitution on the performance of Sr2Fe1.5Mo0.5O6−δ anodes for SOFCs , 2014 .

[37]  Yong Zhang,et al.  A composite cathode based on scandium doped titanate with enhanced electrocatalytic activity towards direct carbon dioxide electrolysis. , 2014, Physical chemistry chemical physics : PCCP.

[38]  N P Brandon,et al.  A Raman spectroscopic study of the carbon deposition mechanism on Ni/CGO electrodes during CO/CO2 electrolysis. , 2014, Physical chemistry chemical physics : PCCP.

[39]  Yucheng Wu,et al.  Remarkable chemical adsorption of manganese-doped titanate for direct carbon dioxide electrolysis , 2014 .

[40]  T. He,et al.  Characterization and evaluation of double perovskites LnBaCoFeO 5+δ (Ln = Pr and Nd) as intermediate-temperature solid oxide fuel cell cathodes , 2013 .

[41]  Xiaomin Zhang,et al.  High- and low- temperature behaviors of La0.6Sr0.4Co0.2Fe0.8O3−δ cathode operating under CO2/H2O-containing atmosphere , 2013 .

[42]  Dragos Neagu,et al.  In situ growth of nanoparticles through control of non-stoichiometry. , 2013, Nature chemistry.

[43]  G. Meng,et al.  Electrolysis of H2O and CO2 in an oxygen-ion conducting solid oxide electrolyzer with a La0.2Sr0.8TiO3+δ composite cathode , 2012 .

[44]  M. Benamira,et al.  Effect of Ce‐Doping on the Electrical and Electrocatalytical Behavior of La/Sr Chromo‐Manganite Perovskite as New SOFC Anode , 2012 .

[45]  Chenghao Yang,et al.  Sulfur‐Tolerant Redox‐Reversible Anode Material for Direct Hydrocarbon Solid Oxide Fuel Cells , 2012, Advanced materials.

[46]  F. Chen,et al.  Sr 2 Fe 1.5 Mo 0.5 O 6-δ as a Regenerative Anode for solid Oxide Fuel Cells , 2011 .

[47]  Joongmyeon Bae,et al.  Electrochemical performance of solid oxide electrolysis cell electrodes under high-temperature coele , 2011 .

[48]  Scott A. Barnett,et al.  Pd-substituted (La,Sr)CrO3−δ–Ce0.9Gd0.1O2−δ solid oxide fuel cell anodes exhibiting regenerative behavior , 2011 .

[49]  B. Liu,et al.  Analysis of Impedance Spectra for Segmented-in-Series Tubular Solid Oxide Fuel Cells , 2010 .

[50]  Andrea R. Gerson,et al.  Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Sc, Ti, V, Cu and Zn , 2010 .

[51]  Scott A. Barnett,et al.  Nickel- and Ruthenium-Doped Lanthanum Chromite Anodes: Effects of Nanoscale Metal Precipitation on Solid Oxide Fuel Cell Performance , 2010 .

[52]  S. Ebbesen,et al.  Electrolysis of carbon dioxide in Solid Oxide Electrolysis Cells , 2009 .

[53]  L. Marks,et al.  La0.8Sr0.2Cr1 − xRuxO3 − δ–Gd0.1Ce0.9O1.95 solid oxide fuel cell anodes: Ru precipitation and electrochemical performance , 2009 .

[54]  G. Henkelman,et al.  A grid-based Bader analysis algorithm without lattice bias , 2009, Journal of physics. Condensed matter : an Institute of Physics journal.

[55]  Zongping Shao,et al.  Synthesis and assessment of La0.8Sr0.2ScyMn1−yO3−δ as cathodes for solid-oxide fuel cells on scandium-stabilized zirconia electrolyte , 2008 .

[56]  L. Marks,et al.  Nucleation of nanometer-scale electrocatalyst particles in solid oxide fuel cell anodes , 2007 .

[57]  L. Cadús,et al.  La1−xCaxCoO3 perovskite-type oxides: Identification of the surface oxygen species by XPS , 2006 .

[58]  Stefan Grimme,et al.  Semiempirical GGA‐type density functional constructed with a long‐range dispersion correction , 2006, J. Comput. Chem..

[59]  Qing Xu,et al.  X-ray photoelectron spectroscopy investigation on chemical states of oxygen on surfaces of mixed electronic–ionic conducting La0.6Sr0.4Co1−yFeyO3 ceramics , 2004 .

[60]  B. Dabrowski,et al.  Evolution of Oxygen-Vacancy Ordered Crystal Structures in the Perovskite Series SrnFenO3n−1 (n=2, 4, 8, and ∞), and the Relationship to Electronic and Magnetic Properties , 2000 .

[61]  G. Kresse,et al.  From ultrasoft pseudopotentials to the projector augmented-wave method , 1999 .

[62]  Burke,et al.  Generalized Gradient Approximation Made Simple. , 1996, Physical review letters.

[63]  Kresse,et al.  Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set. , 1996, Physical review. B, Condensed matter.

[64]  G. Kresse,et al.  Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set , 1996 .

[65]  P. Blöchl.  Projector augmented-wave method. , 1994, Physical review. B, Condensed matter.

[66]  Jackson,et al.  Atoms, molecules, solids, and surfaces: Applications of the generalized gradient approximation for exchange and correlation. , 1992, Physical review. B, Condensed matter.

[67]  H. Monkhorst,et al.  SPECIAL POINTS FOR BRILLOUIN-ZONE INTEGRATIONS , 1976 .

[68]  Linus Pauling,et al.  THE NATURE OF THE CHEMICAL BOND. IV. THE ENERGY OF SINGLE BONDS AND THE RELATIVE ELECTRONEGATIVITY OF ATOMS , 1932 .

[69]  Jun Zhao,et al.  Role of Cu and Sr in Improving the Electrochemical Performance of Cobalt-Free Pr1-xSrxFe1-yCuyO3-δ Cathode for Intermediate Temperature Solid Oxide Fuel Cells , 2016 .

[70]  T. Ishihara,et al.  Ni–Fe–La(Sr)Fe(Mn)O3 as a New Active Cermet Cathode for Intermediate‐Temperature CO2 Electrolysis Using a LaGaO3‐Based Electrolyte , 2015 .

[71]  Fanglin Chen,et al.  In situ fabrication of CoFe alloy nanoparticles structured (Pr0.4Sr0.6)3(Fe0.85Nb0.15)2O7 ceramic anode for direct hydrocarbon solid oxide fuel cells , 2015 .

[72]  A. Manivannan,et al.  Single crystalline La0.5Sr0.5MnO3 microcubes as cathode of solid oxide fuel cell , 2011 .