Synthesis and Electromagnetic Wave Absorption Properties of Micro Composites Reduced Graphene Oxide/Ferrite Based Dendrocalamus Asper Charcoal and Natural Ferrite

Keywords: bamboo, micro composite, natural ferrite, reduced graphene oxideAbstract. Reduced graphene oxide/ferrite (rGO/Fe3O4) micro composites as radar absorber materials have been successfully synthesized from Petung bamboo (Dendrocalamus Asper) and iron sand using a mechanical mixing method. Reduced graphene oxide (rGO) as dielectric material was synthesized from Petung bamboo charcoal using the carbonization method, and Fe3O4 as magnetic material was synthesized from iron sand using the extraction-milling method. The as-prepared samples rGO/Fe3O4 (1:1, 1:2, 1:3, 2:1, 3:1 wt%) was made by dry mixing and mechanically pressed. Magnetics and morphology of samples were characterized by vibrating sample magnetometry (VSM) and scanning electron microscopy (SEM). Microwave absorption was measured using a vector network analyzer (VNA) at 8 – 12 GHz. The results of measurement by using VNA showed that at the micro-scale, rGO had a higher absorption power with maximum reflection loss (RLm) value of -12.98 dB at matching frequency (fm) 10.15 GHz compared with Fe3O4 (RLm value of -4.25 dB at fm 10.42 GHz) at a thickness of 2 mm. The rGO/Fe3O4 (3:1 wt.%) microcomposites radar wave absorber shows the best absorption with maximum reflection loss (RLm) value of −14.30 dB at matching frequency (fm) 10.15 GHz at a thickness of 2 mm. Natural materials and the controlled rGO/Fe3O4 microcomposites structure with simple synthesis methods shows the great potential application in high performance microwave absorbing materials.

[1]  N. C. Murmu,et al.  Synergistic effect of Fe3O4 anchored N-doped rGO hybrid on mechanical, thermal and electromagnetic shielding properties of epoxy composites , 2019, Composites Part B: Engineering.

[2]  Ying Huang,et al.  Magnetic reduced graphene oxide nanocomposite as an effective electromagnetic wave absorber and its absorbing mechanism , 2016 .

[3]  Zheng Peng,et al.  Controlled synthesis of Fe3O4@SnO2/RGO nanocomposite for microwave absorption enhancement , 2016 .

[4]  P. Saini Intrinsically Conducting Polymer‐Based Blends and Composites for Electromagnetic Interference Shielding: Theoretical and Experimental Aspects , 2015 .

[5]  Kongjun Zhu,et al.  Enhanced electromagnetic wave absorption properties of polyaniline-coated Fe3O4/reduced graphene oxide nanocomposites , 2014, Journal of Materials Science: Materials in Electronics.

[6]  Ying Huang,et al.  One-pot simplified co-precipitation synthesis of reduced graphene oxide/Fe3O4 composite and its microwave electromagnetic properties , 2013 .

[7]  C. Shi,et al.  Preparation of reduced graphene oxide/Fe3O4 nanocomposite and its microwave electromagnetic properties , 2013 .

[8]  V. Choudhary,et al.  Improved Electromagnetic Interference Shielding Response of Poly(aniline)-Coated Fabrics Containing Dielectric and Magnetic Nanoparticles , 2012 .

[9]  Ping Xu,et al.  The electromagnetic property of chemically reduced graphene oxide and its application as microwave absorbing material , 2011 .

[10]  M. Cao,et al.  Synthesis, magnetic and electromagnetic wave absorption properties of porous Fe3O4/Fe/SiO2 core/shell nanorods , 2009 .

[11]  K. Wu,et al.  Synthesis and microwave electromagnetic characteristics of bamboo charcoal/polyaniline composites in 2–40 GHz , 2008 .