论文信息 - TRANSITION METAL COMPLEXES MEDIATED EFFICIENT AND FACILE CLEAVAGE OF OXIMES AND PHENYLHYDRAZONE TO CARBONYL COMPOUNDS

TRANSITION METAL COMPLEXES MEDIATED EFFICIENT AND FACILE CLEAVAGE OF OXIMES AND PHENYLHYDRAZONE TO CARBONYL COMPOUNDS

Graphical Abstract Purpose: To report a new and efficient method for the regeneration of carbonyl compounds from their oximes and phenylhydrazones by employing transition metal complexes under mild conditions. Methods: Different oxime and phenylhydrazone complexes have been examined for this regeneration process and found effective. Results: A new method for the cleavage of oximes and phenylhydrazone into their corresponding carbonyl compounds has been done successfully. Conclusion: The present method is of practical significance as it is rapid, high yielding, involves simple work-up under the very mild condition, and it applicable to both aldehydes and ketones. Thus, it is believed that the present method appears to be viable alternative to existing procedures.

S. Wajid | Tasneem Mohammed | M. Arifuddin | Mohamed Al-Arifi

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