Convection–diffusion–reaction inside a porous sphere under oscillatory flow including external mass transfer

This study aims to show the effect of oscillation and external mass transfer on nutrient transport inside a porous sphere when the flow external to the porous sphere is of oscillatory nature. Unsteady Stokes equations are used for the flow outside the porous sphere and Darcy's law is used inside the sphere. We employ a complete general solution of oscillatory Stokes equations in order to solve the corresponding hydrodynamic problem. Then the convection–diffusion–reaction problem is formulated and solved analytically for both zeroth- and first-order rates of nutrient uptake. The Robin-type boundary condition is used to quantify the external mass transfer at the porous–liquid interface. Further, in the case of zeroth-order reaction, a general condition is derived between the Peclet number and the Thiele modulus to preclude the nutrient reduction everywhere inside the sphere.

[1]  J. Prakash,et al.  Convection, diffusion and reaction inside a spherical porous pellet in the presence of oscillatory flow , 2010 .

[2]  J. Prakash,et al.  A criterion to avoid starvation zones for convection–diffusion–reaction problem inside a porous biological pellet under oscillatory flow , 2010 .

[3]  J. S. Roberts,et al.  Moisture Transfer in Solid Food Materials: A Review of Mechanisms, Models, and Measurements , 2007 .

[4]  Alírio E. Rodrigues,et al.  Convection, diffusion and reaction in a nonisothermal, porous catalyst slab , 2007 .

[5]  Ashim K. Datta,et al.  Hydraulic Permeability of Food Tissues , 2006 .

[6]  S. Vandewalle,et al.  A permeation-diffusion-reaction model of gas transport in cellular tissue of plant materials. , 2006, Journal of experimental botany.

[7]  P. Murthy,et al.  Viscous Flow Past a Porous Spherical Shell¿Effect of Stress Jump Boundary Condition , 2005 .

[8]  S. Vandewalle,et al.  Simultaneous measurement of oxygen and carbon dioxide diffusivities in pear fruit tissue using optical sensors , 2005 .

[9]  Mark Pritzker,et al.  Shrinking core model for multispecies uptake onto an ion exchange resin involving distinct reaction fronts , 2005 .

[10]  G. Sekhar,et al.  Viscous flow past a porous sphere with an impermeable core : effect of stress jump condition , 2004 .

[11]  B. Nicolai,et al.  Simultaneous measurement of oxygen and carbon dioxide diffusivity in pear fruit tissue , 2003 .

[12]  I. Manas‐Zloczower,et al.  Hydrodynamic analysis of porous spheres with infiltrated peripheral shells in linear flow fields , 2001 .

[13]  T. Amaranath,et al.  Stokes flow inside a porous spherical shell , 2000 .

[14]  Z. Feng,et al.  Motion of a permeable sphere at finite but small Reynolds numbers , 1998 .

[15]  Lanny D. Schmidt,et al.  The engineering of chemical reactions , 1997 .

[16]  M. Markowski Air drying of vegetables : Evaluation of mass transfer coefficient , 1997 .

[17]  G. Sekhar,et al.  Stokes flow past a porous sphere with an impermeable core , 1996 .

[18]  G. Carta,et al.  Diffusion, convection, and reaction in catalyst particles : analogy between slab and sphere geometries , 1993 .

[19]  T. Amaranath,et al.  Stokes flow past a porous sphere using Brinkman's model , 1993 .

[20]  G. Carta,et al.  Diffusion and convection in permeable particles: Analogy between slab and sphere geometries , 1992 .

[21]  Antonio Mulet,et al.  DRYING OF CARROTS. I. DRYING MODELS. , 1989 .

[22]  S. Sokhansanj IMPROVED HEAT AND MASS TRANSFER MODELS TO PREDICT GRAIN QUALITY , 1987 .

[23]  J. Álvarez-Ramírez,et al.  An Approximate Solution for a Transient Two‐Phase Stirred Tank Bioreactor with Nonlinear Kinetics , 2005, Biotechnology progress.

[24]  Jason R. Looker,et al.  The hydrodynamics of an oscillating porous sphere , 2004 .

[25]  Peter Harriott,et al.  Chemical Reactor Design , 2002 .

[26]  J. M. Bunn,et al.  OXYGEN DIFFUSIVITIES OF APPLE FLESH AND SKIN , 2000 .

[27]  G. Sekhar,et al.  Complete General Solution of the Brinkman Equations , 1997 .

[28]  P. Arce,et al.  Convective-diffusive mass transfer with chemical reaction in squeezing flows , 1996 .

[29]  J. G. Brennan,et al.  A Mathematical Model of Simultaneous Heat and Moisture Transfer during Drying of Potato , 1995 .

[30]  Antonio Mulet,et al.  Drying modelling and water diffusivity in carrots and potatoes , 1994 .

[31]  S. Sokhansanj,et al.  Determination of Heat and Mass Transfer Coefficients in Thin Layer Drying of Grain , 1992 .

[32]  Gregory Stephanopoulos,et al.  The effect of intraparticle convection on nutrient transport in porous biological pellets , 1989 .

[33]  N. Pinto,et al.  Application of the shrinking core model for predicting protein adsorption. , 1987 .