Fluctuations and correlations in a diffusion-reaction system: Exact hydrodynamics

We present an exact closed formulation of the reversible diffusion-limited coagulation-growth reactions 2A ↔ A with irreversible input B → A in one spatial dimension. The treatment here accommodates spatial as well as temporal variations in the particle density with a complete account of microscopic fluctuations and correlations. Moreover, spatial and/or temporal variations in the transport and reaction coefficients can be included in the model. A general solution to the reversible process is presented, and we explore the phenomenon of wavefront propagation.

[1]  C. Doering,et al.  External noise and its interaction with spatial degrees of freedom in nonlinear dissipative systems , 1989 .

[2]  Irene A. Stegun,et al.  Handbook of Mathematical Functions. , 1966 .

[3]  Werner Horsthemke,et al.  Noise-induced transitions , 1984 .

[4]  Joachim Peinke,et al.  A simple morphogenetic reaction-diffusion model describing nonlinear transport phenomena in semiconductors , 1986 .

[5]  D. ben-Avraham,et al.  Statics and dynamics of a diffusion-limited reaction: Anomalous kinetics, nonequilibrium self-ordering, and a dynamic transition , 1990 .

[6]  Redner,et al.  Fluctuation-dominated kinetics in diffusion-controlled reactions. , 1985, Physical review. A, General physics.

[7]  Enrique Merino,et al.  REDOX FRONT PROPAGATION AND BANDING MODALITIES , 1986 .

[8]  ben-Avraham,et al.  Interparticle distribution functions and rate equations for diffusion-limited reactions. , 1988, Physical review. A, General physics.

[9]  K. Kaplan H. Haken, Synergetics. An Introduction. Nonequilibrium Phase Transitions and Self-Organization in Physics, Chemistry, and Biology (2nd Edition). XI + 355 S., 152 Abb. Berlin—Heidelberg—New York 1978. Springer-Verlag. DM 66,00 , 1980 .

[10]  Grégoire Nicolis,et al.  Self-Organization in nonequilibrium systems , 1977 .

[11]  M. A. Burschka,et al.  Fluctuations in diffusion reaction systems. I: Adiabatic elimination of transport modes from a mesoscopicN-body system and the Ω-expansion , 1986 .

[12]  A. Turing The chemical basis of morphogenesis , 1952, Philosophical Transactions of the Royal Society of London. Series B, Biological Sciences.

[13]  Paul C. Fife,et al.  Mathematical Aspects of Reacting and Diffusing Systems , 1979 .