An analytical flow model for PTFE paste through annular dies

An approximate mathematical model for polytetrafluoroethylene (PTFE) paste extrusion through annular dies is developed. The model takes into account the elastic–plastic and viscous nature of the material in its nonmelt state arising from the formation of fibrils and the presence of lubricant. The radial flow hypothesis has been used to describe the flow kinematics of PTFE paste in the conical annular section of the die. The validity of this hypothesis is demonstrated by performing numerical simulations using a model recently developed for PTFE paste extrusion. Model predictions are presented for various cases and are found to be consistent with experimental results of macroscopic pressure drop measurements in rod and tube extrusion. © 2006 American Institute of Chemical Engineers AIChE J, 2006

[1]  L. G. Leal,et al.  Flow birefringence of dilute polymer solutions in two-dimensional flows , 1980 .

[2]  W. Drugan,et al.  Theory of plasticity , 1987 .

[3]  Kurt F. Wissbrun,et al.  Melt Rheology and Its Role in Plastics Processing: Theory and Applications , 1990 .

[4]  R. Larson Constitutive equations for polymer melts and solutions , 1988 .

[5]  J. Bridgwater,et al.  The influence of formulation on extrudate structure and strength , 1987 .

[6]  A. Rozhkov,et al.  Dynamics and disintegration of drops of polymeric liquids , 2006 .

[7]  Christopher J. Lawrence,et al.  On the interpretation of orifice extrusion data for viscoplastic materials , 2005 .

[8]  M. Narkis,et al.  Polymer powder technology , 1995 .

[9]  S. Hatzikiriakos,et al.  Polytetrafluoroethylene paste preforming: viscosity and surface tension effects , 2004 .

[10]  James J. Feng,et al.  Constitutive modeling and flow simulation of polytetrafluoroethylene (PTFE) paste extrusion , 2006 .

[11]  S. Hatzikiriakos,et al.  Paste Extrusion of Polytetrafluoroethylene (PTFE) Fine Powder Resins , 2002 .

[12]  S. Hatzikiriakos,et al.  Preforming behavior of polytetrafluoroethylene paste , 2001 .

[13]  S. Hatzikiriakos,et al.  Paste extrusion of polytetrafluoroethylene (PTFE): Surface tension and viscosity effects , 2005 .

[14]  J. Bridgwater,et al.  The extrusion mechanics of pastes—the influence of paste formulation on extrusion parameters , 1987 .

[15]  L. G. Leal,et al.  Dilute polystyrene solutions in extensional flows: Birefringence and flow modification , 1987 .

[16]  M. Mooney Explicit Formulas for Slip and Fluidity , 1931 .

[17]  L. G. Leal,et al.  The measurement of velocity gradients in laminar flow by homodyne light-scattering spectroscopy , 1980, Journal of Fluid Mechanics.

[18]  Paul Ludwik,et al.  Elemente der technologischen Mechanik , 1909 .

[19]  J. E. Adkins,et al.  Large Elastic Deformations , 1971 .

[20]  Christopher W. Macosko,et al.  Rheology: Principles, Measurements, and Applications , 1994 .

[21]  J. Bridgwater,et al.  Prediction of past extrusion pressure , 1989 .

[22]  S. Ebnesajjad Non-melt processible fluoroplastics : the definitive user's guide and databook , 2000 .

[23]  R. Rivlin Large Elastic Deformations of Isotropic Materials , 1997 .