Nano-Processing with Gas Cluster Ion Beams

Abstract This paper describes the fundamental principles and experimental status of gas cluster ion beam (GCIB) processing as a new technique with promise for practical industrial applications. A review is presented of the theoretical and experimental characteristics of new gas cluster ion bombardment processes and of related equipment development. The impacts of accelerated cluster ions upon substrate surfaces impart very high-energy densities in the impact regions of individual clusters and produce non-linear processes that are not present in the impacts of individual atomic ions. These unique bombardment characteristics are expected to facilitate new industrial applications that would not be possible by traditional ion beam processing. Among these are shallow ion implantation, high rate sputtering, surface cleaning and smoothing, and low-temperature thin film formation.

[1]  I. Yamada,et al.  MOLECULAR DYNAMICS SIMULATION OF DAMAGE FORMATION BY CLUSTER ION IMPACT , 1997 .

[2]  A. J. Cable,et al.  High-velocity impact phenomena , 1970 .

[3]  C. Boragno,et al.  Ripple Structure on Ag(110) Surface Induced by Ion Sputtering , 1997 .

[4]  J. Matsuo,et al.  Shallow junction formation by polyatomic cluster ion implantation , 1996, Proceedings of 11th International Conference on Ion Implantation Technology.

[5]  I. Yamada,et al.  Incident angle dependence of the sputtering effect of Ar-cluster-ion bombardment , 1997 .

[6]  M. Current,et al.  Practical Aspects of Forming Ultra-Shallow Junctions by Sub-keV Boron Implants , 1999 .

[7]  Mayer,et al.  Roughening instability and evolution of the Ge(001) surface during ion sputtering. , 1994, Physical review letters.

[8]  I. Yamada,et al.  Surface modification with gas cluster ion beams , 1993 .

[9]  I. Yamada,et al.  Gas cluster ion beam equipments for industrial applications , 1995 .

[10]  D. Thompson High density cascade effects , 1981 .

[11]  I. Yamada,et al.  Surface smoothing effects with reactive cluster ion beams , 1998 .

[12]  I. Yamada,et al.  Irradiation effects of gas-cluster CO2 ion beams on Si , 1993 .

[13]  R. Zubarev,et al.  Multiplicities of secondary ions emitted in macromolecular ion impact events , 1994 .

[14]  I. Koponen,et al.  Simulations of Ripple Formation on Ion-Bombarded Solid Surfaces , 1997 .

[15]  Y. Zel’dovich,et al.  Gas Dynamics. (Book Reviews: Physics of Shock Waves and High-Temperature Hydrodynamic Phenomena. Vol. 1) , 1970 .

[16]  I. Yamada,et al.  Low-temperature formation of perovskite PbTiO3 films by O2 cluster ion-assisted deposition , 1998 .

[17]  S. Eliezer,et al.  Scaling laws for pressure, temperature, and ionization with two-temperature equation-of-state effects in laser-produced plasmas , 1992 .

[18]  L. Friedman,et al.  Larger cluster ion impact phenomena , 1986 .

[19]  S. Runcorn Book Review: Impact and Explosion Cratering. Proceedings of the Symposium on Planetary Cratering Mechanics. Pergamon Press, 1977, 1299 pp., US $150.00, £98.00, ISBN 0-08-022050-9 , 1984 .

[20]  I. Yamada,et al.  Surface processing with ionized cluster beams: computer simulation , 1999 .

[21]  G. K. Wehner,et al.  Angular Distribution of Sputtered Material , 1960 .

[22]  Y. Yamamura,et al.  Hydrodynamical approach to non-linear effects in sputtering yields , 1980 .

[23]  Meier,et al.  Ion-beam-induced surface instability of glassy Fe40Ni40B20. , 1995, Physical review letters.

[24]  R. Behrisch,et al.  Sputtering by Particle Bombardment III , 1981 .

[25]  A. J. Howard,et al.  Roughening instability and ion‐induced viscous relaxation of SiO2 surfaces , 1994 .

[26]  T. Aoki,et al.  Cluster ion implantation for shallow junction formation , 1996, Proceedings of 11th International Conference on Ion Implantation Technology.

[27]  I. Yamada,et al.  STM observation of HOPG surfaces irradiated with Ar cluster ions , 1997 .

[28]  T. Sugii,et al.  Ultra Shallow Junction Formation by Cluster Ion Implantation , 1998 .

[29]  I. Yamada,et al.  Lateral Sputtering by Gas Cluster Ion Beams and its Applications to Atomic Level Surface Modification , 1995 .

[30]  C. Deutsch Ion cluster interaction with cold targets for ICF: Fragmentation and stopping , 1992 .

[31]  I. Yamada,et al.  Computer simulation of crystal surface modification by accelerated cluster ion impacts , 1997 .

[32]  I. Yamada,et al.  Non-linear processes in the gas cluster ion beam modification of solid surfaces , 1998 .

[33]  G. Rozgonyi,et al.  5 – Extended Defects from Ion Implantation and Annealing , 1993 .

[34]  M. Sosnowski,et al.  Cluster-solid interaction experiments , 1995 .

[35]  I. Yamada,et al.  Molecular dynamics study of shock wave generation by cluster impact on solid targets , 1996 .

[36]  T. E. Haynes,et al.  Transient enhanced diffusion from decaborane molecular ion implantation , 1998 .

[37]  I. Yamada,et al.  Smoothing of YBa2Cu3O7−δ films by ion cluster beam bombardment , 1998 .

[38]  H. H. Andersen,et al.  Nonlinear effects in heavy-ion sputtering , 1974 .

[39]  I. Yamada,et al.  Sputterring and smoothing of metal surface with energetic gas cluster beams , 1998 .

[40]  Isao Yamada,et al.  Molecular dynamics simulation of cluster ion bombardment of solid surfaces , 1995 .