Atmospheric corrosion of electro-electronics metals in urban desert simulated indoor environment

Abstract The corrosion of pure Ag, Cu, Ni, and Sn specimens exposed for 1 to 24 months in a simulated indoor environment, consisting of a rain sheltered atmospheric corrosion test chamber placed in an urban desert environment (Baja California) has been measured. The corrosion rates of the metals were determined by mass loss measurement and the environment was thus classified in the low to medium indoor corrosivity category (IC2–IC3) according to ISO. Silver and copper weight losses were found to be very similar, while the nickel and tin weight losses were several times lower. The silver surface was tarnished in a non-uniform manner, presenting Ag2S and AgCl corrosion products, while the copper specimens corrode uniformly, being covered with Cu2O corrosion product. Owing to the presence of chloride contamination, the nickel and tin oxide corrosion films show fracture and pitting corrosion, developed over the first few months of exposure.

[1]  L. Veleva,et al.  Classification of atmospheric corrosivity in humid tropical climates , 1998 .

[2]  G. G. Stokes "J." , 1890, The New Yale Book of Quotations.

[3]  T. Sasaki,et al.  The influence of oxide layers on initial corrosion behavior of copper in air containing water vapor and sulfur dioxide , 2000 .

[4]  M. Graham,et al.  On the Mechanism of Low‐Temperature Oxidation (23°–450°C) of Polycrystalline Nickel , 1972 .

[5]  Development of a Gentle Accelerated Corrosion Test , 1978 .

[6]  P. J. Peterson Corrosion of electronic and magnetic materials , 1992 .

[7]  C. Leygraf,et al.  GILDES Model Studies of Aqueous Chemistry VI. Initial S O 2 ∕ O 3 - and S O 2 ∕ N O 2 -Induced Atmospheric Corrosion of Copper , 2005 .

[8]  W. C. Shumay Corrosion in electronics , 1987 .

[9]  J. L. Polo,et al.  Study of the Effect of Acetic Acid Vapor on Copper Corrosion at 40 and 80% Relative Humidity , 2001 .

[10]  Francisco Corvo,et al.  Outdoor and indoor atmospheric corrosion of non-ferrous metals , 2000 .

[11]  H. Eyring,et al.  Atmospheric Corrosion , 1991 .

[12]  K. R. Zlatev,et al.  Corrosion of metals at indoor conditions in the electronics manufacturing industry , 2007 .

[13]  S. Sharma Reaction of Copper and Copper Oxide with H 2 S , 1980 .

[14]  P. Quintana,et al.  Mechanism of copper patina formation in marine environments , 1996 .

[15]  Statistical analysis of the temperature-humidity complex and time of wetness of a tropical climate in the Yucatán Peninsula in Mexico , 1997 .

[16]  T. Sasaki,et al.  Corrosion products of tin in humid air containing sulfur dioxide and nitrogen dioxide at room temperature , 2003 .

[17]  J. P. Franey,et al.  On the mechanism of silver and copper sulfidation by atmospheric H2S and OCS , 1985 .