Dendritic Ni‐P‐Coated Melamine Foam for a Lightweight, Low‐Cost, and Amphipathic Three‐Dimensional Current Collector for Binder‐Free Electrodes

A highly conductive 3D current collector that is dendritic, lightweight, and robust is synthesized for binder-free electrodes in lithium-ion batteries. It has excellent chemical/electrochemical stability in a wide voltage window (0-5 V) and robust mechanical behavior even after 600 cycles of compression. When active materials are grown in situ on the as-obtained current collector, the resulting cycling stability and rate capability far exceed those of conventional electrodes and other 3D current collectors.

[1]  Yi Cui,et al.  Lithium‐Ion Textile Batteries with Large Areal Mass Loading , 2011 .

[2]  Chan‐Jin Park,et al.  Electrochemical Performance of GeO2/C Core Shell based Electrodes for Li-ion Batteries , 2014 .

[3]  J. Banhart Manufacture, characterisation and application of cellular metals and metal foams , 2001 .

[4]  A. J. Frank,et al.  Ni-NiO core-shell inverse opal electrodes for supercapacitors. , 2011, Chemical communications.

[5]  Y. Gotoh,et al.  A new electroless Ni plating procedure of iodine-treated aramid fiber , 2013, Journal of Coatings Technology and Research.

[6]  Deren Yang,et al.  Cu–Ge core–shell nanowire arrays as three-dimensional electrodes for high-rate capability lithium-ion batteries , 2012 .

[7]  M. Chi,et al.  Soft‐Templated Mesoporous Carbon‐Carbon Nanotube Composites for High Performance Lithium‐ion Batteries , 2011, Advanced materials.

[8]  C. Li,et al.  Ultralight, flexible, and fire-resistant carbon nanofiber aerogels from bacterial cellulose. , 2013, Angewandte Chemie.

[9]  G. Shi,et al.  Graphene Hydrogels Deposited in Nickel Foams for High‐Rate Electrochemical Capacitors , 2012, Advanced materials.

[10]  Jixiang Chen,et al.  Hydroisomerization of n-dodecane on a new kind of bifunctional catalyst: Nickel phosphide supported on SAPO-11 molecular sieve , 2014 .

[11]  Xinping Ai,et al.  High capacity Na-storage and superior cyclability of nanocomposite Sb/C anode for Na-ion batteries. , 2012, Chemical communications.

[12]  K. Cho,et al.  Graphite/Silicon Hybrid Electrodes using a 3D Current Collector for Flexible Batteries , 2014, Advanced materials.

[13]  Jian Jiang,et al.  Recent Advances in Metal Oxide‐based Electrode Architecture Design for Electrochemical Energy Storage , 2012, Advanced materials.

[14]  K. Amine,et al.  GeO2–SnCoC Composite Anode Material for Lithium-Ion Batteries , 2014 .

[15]  Haitao Hu,et al.  Heat transfer measurements and correlation of refrigerant flow boiling in tube filled with copper foam , 2014 .

[16]  Fengjia Fan,et al.  Stretchable conductors based on silver nanowires: improved performance through a binary network design. , 2013, Angewandte Chemie.

[17]  Callie W. Babbitt,et al.  A future perspective on lithium-ion battery waste flows from electric vehicles , 2014 .

[18]  W. Sha,et al.  Electroless nickel, alloy, composite and nano coatings – A critical review , 2013 .

[19]  Yan Yu,et al.  Three‐Dimensional (3D) Bicontinuous Au/Amorphous‐Ge Thin Films as Fast and High‐Capacity Anodes for Lithium‐Ion Batteries , 2013 .

[20]  Akihiko Hirata,et al.  Nanoporous metal/oxide hybrid electrodes for electrochemical supercapacitors. , 2011, Nature nanotechnology.

[21]  Linsen Li,et al.  High-capacity lithium-ion battery conversion cathodes based on iron fluoride nanowires and insights into the conversion mechanism. , 2012, Nano letters.

[22]  H. Hng,et al.  Ultrahigh Rate Capabilities of Lithium‐Ion Batteries from 3D Ordered Hierarchically Porous Electrodes with Entrapped Active Nanoparticles Configuration , 2014, Advanced materials.

[23]  M. Lain,et al.  A prelithiated carbon anode for lithium-ion battery applications , 2006 .

[24]  Jaephil Cho,et al.  3D amorphous silicon on nanopillar copper electrodes as anodes for high-rate lithium-ion batteries. , 2014, ACS nano.

[25]  Hsueh-Chuan Hsu,et al.  Design and characterization of highly porous titanium foams with bioactive surface sintering in air , 2013 .

[26]  Xin-bo Zhang,et al.  Homogeneous CoO on Graphene for Binder‐Free and Ultralong‐Life Lithium Ion Batteries , 2013 .

[27]  Bruce Dunn,et al.  Enhancing pseudocapacitive charge storage in polymer templated mesoporous materials. , 2013, Accounts of chemical research.

[28]  Yogendra Kumar Mishra,et al.  Aerographite: Ultra Lightweight, Flexible Nanowall, Carbon Microtube Material with Outstanding Mechanical Performance , 2012, Advanced materials.

[29]  Yong‐Sheng Hu,et al.  Porous Li4Ti5O12 Coated with N‐Doped Carbon from Ionic Liquids for Li‐Ion Batteries , 2011, Advanced materials.

[30]  Feng Li,et al.  Flexible graphene-based lithium ion batteries with ultrafast charge and discharge rates , 2012, Proceedings of the National Academy of Sciences.

[31]  Di Hu,et al.  Ideal Three‐Dimensional Electrode Structures for Electrochemical Energy Storage , 2014, Advanced materials.

[32]  Yunhui Huang,et al.  Nitrogen‐Doped Porous Carbon Nanofiber Webs as Anodes for Lithium Ion Batteries with a Superhigh Capacity and Rate Capability , 2012, Advanced materials.

[33]  J. Goodenough Challenges for Rechargeable Li Batteries , 2010 .

[34]  S. Jiang,et al.  Electroless nickel deposition of a palladium‐activated self‐assembled monolayer on polyester fabric , 2013 .

[35]  P. Ajayan,et al.  Conformal coating of thin polymer electrolyte layer on nanostructured electrode materials for three-dimensional battery applications. , 2011, Nano letters.

[36]  Yifu Shen,et al.  A comparative study of pure nickel and the Ni–CeO2 nanocrystalline coatings: microstructural evolution, oxidation behavior, and thermodynamic stability , 2014, Journal of Materials Science.

[37]  Yi Cui,et al.  Prelithiated silicon nanowires as an anode for lithium ion batteries. , 2011, ACS nano.

[38]  M. Durstock,et al.  Nanostructured 3D Electrode Architectures for High‐Rate Li‐Ion Batteries , 2013, Advanced materials.

[39]  Hui‐Ming Cheng,et al.  Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition. , 2011, Nature materials.

[40]  P. He,et al.  Raising the cycling stability of aqueous lithium-ion batteries by eliminating oxygen in the electrolyte. , 2010, Nature chemistry.

[41]  Y. Bando,et al.  Coaxial Cu-Si@C array electrodes for high-performance lithium ion batteries. , 2011, Chemical communications.

[42]  Guihua Yu,et al.  Three-dimensional hierarchical ternary nanostructures for high-performance Li-ion battery anodes. , 2013, Nano letters.

[43]  Weidong Wu,et al.  Template-dealloying synthesis of ultralow density Au foams with bimodal porous structure , 2014 .

[44]  Paul V. Braun,et al.  Three-dimensional bicontinuous ultrafast-charge and -discharge bulk battery electrodes. , 2011, Nature nanotechnology.

[45]  Siyang Liu,et al.  Facile ultrasonic synthesis of CoO quantum dot/graphene nanosheet composites with high lithium storage capacity. , 2012, ACS nano.

[46]  P. Bruce,et al.  TiO2‐(B) Nanotubes as Anodes for Lithium Batteries: Origin and Mitigation of Irreversible Capacity , 2012 .

[47]  M. Armand,et al.  Building better batteries , 2008, Nature.

[48]  Ya‐Xia Yin,et al.  Low-cost and large-scale synthesis of alkaline earth metal germanate nanowires as a new class of lithium ion battery anode material , 2012 .