Hydrogen Purification through a Membrane–Cryogenic Integrated Process: A 3 E’s (Energy, Exergy, and Economic) Assessment

Hydrogen (H2) is known for its clean energy characteristics. Its separation and purification to produce high-purity H2 is becoming essential to promoting a H2 economy. There are several technologies, such as pressure swing adsorption, membrane, and cryogenic, which can be adopted to produce high-purity H2; however, each standalone technology has its own pros and cons. Unlike standalone technology, the integration of technologies has shown significant potential for achieving high purity with a high recovery. In this study, a membrane–cryogenic process was integrated to separate H2 via the desublimation of carbon dioxide. The proposed process was designed, simulated, and optimized in Aspen Hysys. The results showed that the H2 was separated with a 99.99% purity. The energy analysis revealed a net-specific energy consumption of 2.37 kWh/kg. The exergy analysis showed that the membranes and multi-stream heat exchangers were major contributors to the exergy destruction. Furthermore, the calculated total capital investment of the proposed process was 816.2 m$. This proposed process could be beneficial for the development of a H2 economy.

[1]  E. Jannelli,et al.  Current standards and configurations for the permitting and operation of hydrogen refueling stations , 2023, International Journal of Hydrogen Energy.

[2]  A. Yaroslavtsev,et al.  Modern Technologies of Hydrogen Production , 2022, Processes.

[3]  Moonyong Lee,et al.  Separation and purification of syngas-derived hydrogen: A comparative evaluation of membrane- and cryogenic-assisted approaches. , 2022, Chemosphere.

[4]  Moonyong Lee,et al.  Thermodynamic, economic, and emissions assessment of integrated power to methanol concept with membrane-based biogas up-gradation and plasma electrolysis , 2022, Journal of Cleaner Production.

[5]  F. Javed,et al.  An Overview of Hydrogen Production: Current Status, Potential, and Challenges , 2022, Fuel.

[6]  Moonyong Lee,et al.  Hydrogen enrichment by CO2 anti-sublimation integrated with triple mixed refrigerant-based liquid hydrogen production process , 2022, Journal of Cleaner Production.

[7]  A. Hawkes,et al.  Hydrogen supply chain optimisation for the transport sector – Focus on hydrogen purity and purification requirements , 2022, Applied Energy.

[8]  I. Dincer,et al.  A review on hydrogen production and utilization: Challenges and opportunities , 2021, International Journal of Hydrogen Energy.

[9]  A. Al-Muhtaseb,et al.  Hydrogen production, storage, utilisation and environmental impacts: a review , 2021, Environmental Chemistry Letters.

[10]  Muhammad Abdul Qyyum,et al.  100% saturated liquid hydrogen production: Mixed-refrigerant cascaded process with two-stage ortho-to-para hydrogen conversion , 2021, Energy Conversion and Management.

[11]  Moonyong Lee,et al.  Renewable LNG production: Biogas upgrading through CO2 solidification integrated with single-loop mixed refrigerant biomethane liquefaction process , 2021 .

[12]  Congmin Liu,et al.  A Review of Hydrogen Purification Technologies for Fuel Cell Vehicles , 2021, Catalysts.

[13]  Muhammad Abdul Qyyum,et al.  Availability, versatility, and viability of feedstocks for hydrogen production: Product space perspective , 2021, Renewable and Sustainable Energy Reviews.

[14]  H. Neomagus,et al.  Recent Advances in Membrane-Based Electrochemical Hydrogen Separation: A Review , 2021, Membranes.

[15]  Xiangping Zhang,et al.  Carbon membranes for CO2 removal: Status and perspectives from materials to processes , 2020, Chemical Engineering Journal.

[16]  Chongqi Chen,et al.  Techno-economic analysis and comprehensive optimization of anon-sitehydrogen refuelling station system using ammonia: hybrid hydrogen purification with both high H2purity and high recovery , 2020 .

[17]  A. Guwy,et al.  Simulation of integrated novel PSA/EHP/C process for high-pressure hydrogen recovery from Coke Oven Gas , 2020 .

[18]  Xiangcun Li,et al.  A Novel Process of H2/CO2 Membrane Separation of Shifted Syngas Coupled with Gasoil Hydrogenation , 2020 .

[19]  C. Deng,et al.  Hybrid Separation Process of Refinery Off-gas toward Near-Zero Hydrogen Emission: Conceptual Design and Techno-economic Analysis , 2020 .

[20]  F. You,et al.  Systematic Design and Optimization of a Membrane–Cryogenic Hybrid System for CO2 Capture , 2019, ACS Sustainable Chemistry & Engineering.

[21]  Meng Lu,et al.  Feasibility and sustainability analyses of carbon dioxide – hydrogen separation via de-sublimation process in comparison with other processes , 2019, International Journal of Hydrogen Energy.

[22]  Yong-ki Park,et al.  Analysis of Multistage Membrane and Distillation Hybrid Processes for Propylene/propane Separation , 2019 .

[23]  Sven Schmitz,et al.  Membrane based purification of hydrogen system (MEMPHYS) , 2019, International Journal of Hydrogen Energy.

[24]  Matthias Wessling,et al.  Optimizing hybrid membrane-pressure swing adsorption processes for biogenic hydrogen recovery , 2019, Chemical Engineering Journal.

[25]  Zuwei Liao,et al.  Optimal design of hybrid cryogenic flash and membrane system , 2018 .

[26]  M. Mehrpooya,et al.  Large-scale liquid hydrogen production methods and approaches: A review , 2018 .

[27]  Simón Reif-Acherman,et al.  Peng-Robinson equation of state: 40 years through cubics , 2017 .

[28]  Thomas Morel,et al.  Start-up of Port-Jérôme CRYOCAP™ Plant: Optimized Cryogenic CO2 Capture from H2 Plants , 2017 .

[29]  Yan Dai,et al.  Pressure swing adsorption/membrane hybrid processes for hydrogen purification with a high recovery , 2016, Frontiers of Chemical Science and Engineering.

[30]  T. Merkel,et al.  CO2-selective membranes for hydrogen production and CO2 capture - Part II: Techno-economic analysis , 2015 .

[31]  Matthias Wessling,et al.  Techno-economic Analysis of Membrane-Based Argon Recovery in a Silicon Carbide Process , 2013 .

[32]  A. Friedl,et al.  Simulation Study on the Applicability and Performance of Conventional and Reverse-selective Membranes for Upgrading of H2/co2 Mixtures via Gas-permeation , 2012 .

[33]  Yongping Yang,et al.  A novel CO2 cryogenic liquefaction and separation system , 2012 .

[34]  Faizan Ahmad,et al.  Process simulation and optimal design of membrane separation system for CO2 capture from natural gas , 2012, Comput. Chem. Eng..

[35]  P. Wankat,et al.  Hybrid Membrane-Cryogenic Distillation Air Separation Process for Oxygen Production , 2011 .

[36]  Henning Struchtrup,et al.  Hybrid membrane/cryogenic separation of oxygen from air for use in the oxy-fuel process , 2010 .

[37]  V. Teplyakov,et al.  Integrated membrane/PSA systems for hydrogen recovery from gas mixtures , 2010 .

[38]  Richard W. Baker,et al.  The design of membrane vapor–gas separation systems , 1998 .

[39]  R. Agrawal,et al.  Membrane/cryogenic hybrid processes for hydrogen purification , 1988 .

[40]  D. Peng,et al.  A New Two-Constant Equation of State , 1976 .

[41]  P. Chiang,et al.  Energy Consumption Analysis of Cryogenic-membrane Hybrid Process for CO2 Capture from CO2-EOR Extraction Gas , 2020 .

[42]  E. Drioli,et al.  Molecular Weight Cutoff , 2015 .

[43]  Thomas Morel,et al.  CO2 Capture from H2 Plants: Implementation for EOR , 2014 .