Electron transport through metal-multiwall carbon nanotube interfaces

In this paper, we examine mechanisms of electron transport across the metal-carbon nanotube (CNT) interface for two different types of multiwall carbon nanotube (MWNT) architectures, horizontal or side-contacted MWNTs and vertical or end-contacted MWNTs. Horizontally aligned nanotube growth and electrical characteristics are examined with respect to their potential applications in silicon-based technologies. Recent advances in the synthesis techniques of vertical MWNTs have also enhanced the possibility for a manufacturable solution incorporating this novel material as on-chip interconnects or vias as copper interconnect feature sizes are scaled into the sub-100-nm regime. A vertical MWNT architecture is presented that may be suitable for integration into silicon-based technologies. The growth method for this architecture and its effect on electrical characteristics are examined. Through simulations, dc measurements, and comparison of our results with previous studies, we explain why high contact resistance is observed in metal-CNT-metal systems.

[1]  P. Ajayan,et al.  Reliability and current carrying capacity of carbon nanotubes , 2001 .

[2]  R. Fowler,et al.  Electron Emission in Intense Electric Fields , 1928 .

[3]  M. Meyyappan,et al.  Growth of multiwall carbon nanotubes in an inductively coupled plasma reactor , 2002 .

[4]  Franz Kreupl,et al.  Carbon nanotubes in interconnect applications , 2002 .

[5]  M. Meyyappan,et al.  Carbon nanotube interconnects: a process solution , 2003, Proceedings of the IEEE 2003 International Interconnect Technology Conference (Cat. No.03TH8695).

[6]  Madhu Menon,et al.  Various bonding configurations of transition-metal atoms on carbon nanotubes: Their effect on contact resistance , 2000 .

[7]  Phaedon Avouris,et al.  Optimized contact configuration for the study of transport phenomena in ropes of single-wall carbon nanotubes , 2001 .

[8]  G. Xu,et al.  Synthesis of vertically aligned carbon nanotubes films on silicon wafers by pyrolysis of ethylenediamine , 2002 .

[9]  M. Anantram Which nanowire couples better electrically to a metal contact: Armchair or zigzag nanotube? , 2001, cond-mat/0102366.

[10]  Leo Esaki,et al.  Electron Tunneling between a Metal and a Semiconductor: Characteristics of Al‐Al2O3‐SnTe and −GeTe Junctions , 1967 .

[11]  Hongjie Dai,et al.  Electrical measurements of individual semiconducting single-walled carbon nanotubes of various diameters , 2000 .

[12]  S. Datta,et al.  Coupling of Carbon Nanotubes to Metallic Contacts , 1999, cond-mat/9907357.

[13]  Bin Chen,et al.  Multiwalled Carbon Nanotubes by Chemical Vapor Deposition Using Multilayered Metal Catalysts , 2002 .

[14]  M. Meyyappan,et al.  Bottom-up approach for carbon nanotube interconnects , 2003 .

[15]  Christoph Strunk,et al.  Contacting carbon nanotubes selectively with low-ohmic contacts for four-probe electric measurements , 1998 .

[16]  Supriyo Datta,et al.  A simple, reliable technique for making electrical contact to multiwalled carbon nanotubes , 1999 .

[17]  J. Tersoff Contact resistance of carbon nanotubes , 1999 .

[18]  Jijun Zhao,et al.  Work functions of pristine and alkali-metal intercalated carbon nanotubes and bundles , 2001, cond-mat/0111103.

[19]  L. Delzeit,et al.  Electronic properties of multiwalled carbon nanotubes in an embedded vertical array , 2002 .

[20]  R. Landauer,et al.  Generalized many-channel conductance formula with application to small rings. , 1985, Physical review. B, Condensed matter.

[21]  R. M. Swanson,et al.  Modeling and measurement of contact resistances , 1987, IEEE Transactions on Electron Devices.

[22]  Y. Aoyagi,et al.  Electron transport in metal/multiwall carbon nanotube/metal structures (metal=Ti or Pt/Au) , 2001 .

[23]  J. Simmons Generalized Formula for the Electric Tunnel Effect between Similar Electrodes Separated by a Thin Insulating Film , 1963 .

[24]  Otto Zhou,et al.  Plasma-induced alignment of carbon nanotubes , 2000 .

[25]  P. Ajayan,et al.  Electrical behavior of isolated multiwall carbon nanotubes characterized by scanning surface potential microscopy , 2002 .

[26]  Herbert Shea,et al.  Single- and multi-wall carbon nanotube field-effect transistors , 1998 .

[27]  S. Iijima Helical microtubules of graphitic carbon , 1991, Nature.

[28]  Zhifeng Ren,et al.  Growth of Highly-Oriented Carbon Nanotubes by Plasma-Enhanced Hot Filament Chemical Vapor Deposition , 1998 .