Optimizing MOX sensor array performances with a reconfigurable self-adaptive temperature modulation interface

Abstract The temperature modulation effects of metal oxide based gas sensors have been widely investigated for the volatile compounds detection and, to this aim, several interface circuits were designed for optimization of the sensors properties. In this paper instead of improving only the sensors operation, we propose a novel interface that can also maximize the information that can be collected from the sensor, through a feedback-based thermal modulation method and an active digital control. The self-adaptive modulation method exploits the changes of the sensor resistance to drive its operating temperature. This is implemented in a novel digital interface based on a microcontroller that can drive an array of four sensors independently and provides a real-time control over the modulation parameters. In this way, the behavior of the sensor can be changed during the measurements, enabling the drift compensation, the fault identification and more importantly the minimization of the mutual information between similar sensors. The proposed interface has been tested in two different scenarios: a lab calibration experiment, by recognizing different concentrations of known gases and a practical application, by distinguishing complex VOCs to evaluate the stress level of plants. A multivariate data analysis has been conducted, highlighting a clear effectiveness of the proposed approach and better performances with respect to the standard thermal modulation techniques.

[1]  Jordi Fonollosa,et al.  Pulsed-Temperature Metal Oxide Gas Sensors for Microwatt Power Consumption , 2020, IEEE Access.

[2]  Ananya Dey,et al.  Semiconductor metal oxide gas sensors: A review , 2018 .

[3]  Russell Binions,et al.  Metal Oxide Semi-Conductor Gas Sensors in Environmental Monitoring , 2010, Sensors.

[4]  Optimizing an array of self adapted temperature modulated metal oxide sensors for biomedical application , 2017, 2017 ISOCS/IEEE International Symposium on Olfaction and Electronic Nose (ISOEN).

[5]  Santiago Marco,et al.  Low Power Operation of Temperature-Modulated Metal Oxide Semiconductor Gas Sensors , 2018, Sensors.

[6]  Eugenio Martinelli,et al.  Self-adapted temperature modulation in metal-oxide semiconductor gas sensors , 2012 .

[7]  R. Tauler,et al.  Multivariate curve resolution applied to temperature-modulated metal oxide gas sensors , 2010 .

[8]  Udo Weimar,et al.  Gas identification by modulating temperatures of SnO2-based thick film sensors , 1997 .

[9]  S. Neelima,et al.  A Reconfigurable Smart Sensor Interface for Industrial WSN in IOT Environment , 2015 .

[10]  Gabriele Magna,et al.  Unsupervised On-Line Selection of Training Features for a robust classification with drifting and faulty gas sensors , 2018 .

[11]  Jung-Sik Kim,et al.  Recent advances on H2 sensor technologies based on MOX and FET devices: A review , 2018, Sensors and Actuators B: Chemical.

[12]  Amir Amini,et al.  A breakthrough in gas diagnosis with a temperature-modulated generic metal oxide gas sensor , 2012 .

[13]  Roberto Paolesse,et al.  Investigation of VOCs associated with different characteristics of breast cancer cells , 2015, Scientific Reports.

[14]  Quan Quan,et al.  Novel anti-thrombotic agent for modulation of protein disulfide isomerase family member ERp57 for prophylactic therapy , 2015, Scientific Reports.

[15]  D. Ballabio,et al.  Classification tools in chemistry. Part 1: linear models. PLS-DA , 2013 .

[16]  Sam Emaminejad,et al.  Fully integrated wearable sensor arrays for multiplexed in situ perspiration analysis , 2016, Nature.

[17]  Vincenzo Stornelli,et al.  A single-chip integrated interfacing circuit for wide-range resistive gas sensor arrays , 2009 .

[18]  A. Amini,et al.  Recognition of complex odors with a single generic tin oxide gas sensor , 2014 .

[19]  Liangtian Wan,et al.  Electronic Noses: From Advanced Materials to Sensors Aided with Data Processing , 2018, Advanced Materials Technologies.

[20]  Yiyong Chen,et al.  Regulation of formation of volatile compounds of tea (Camellia sinensis) leaves by single light wavelength , 2015, Scientific Reports.

[21]  Gang Xu,et al.  MOF Thin Film‐Coated Metal Oxide Nanowire Array: Significantly Improved Chemiresistor Sensor Performance , 2016, Advanced materials.

[22]  P. Alderson,et al.  Solar irradiance level alters the growth of basil (Ocimum basilicum L.) and its content of volatile oils , 2008 .

[23]  P. Varona,et al.  An active, inverse temperature modulation strategy for single sensor odorant classification , 2015 .

[24]  N. Bârsan,et al.  Metal oxide-based gas sensor research: How to? , 2007 .

[25]  R. Piedrahita,et al.  Approach for quantification of metal oxide type semiconductor gas sensors used for ambient air quality monitoring , 2015 .

[26]  Anita Lloyd Spetz,et al.  Discrimination and quantification of volatile organic compounds in the ppb-range with gas sensitive SiC-FETs using multivariate statistics , 2015 .

[27]  Ting-I Chou,et al.  A Gas Mixture Prediction Model Based on the Dynamic Response of a Metal-Oxide Sensor , 2019, Micromachines.

[28]  B. Reedy,et al.  Temperature modulation in semiconductor gas sensing , 1999 .

[29]  M. Siadat,et al.  Reduction of drift impact in gas sensor response to improve quantitative odor analysis , 2017, 2017 IEEE International Conference on Industrial Technology (ICIT).

[30]  Fanli Meng,et al.  Gas sensing behavior of a single tin dioxide sensor under dynamic temperature modulation , 2004 .

[31]  Gabriele Magna,et al.  Self-repairing Classification Algorithms for Chemical Sensor Array , 2019 .

[32]  Harry L. Tuller,et al.  Novel deposition techniques for metal oxide: Prospects for gas sensing , 2010 .

[33]  Amir Amini,et al.  Improving gas identification accuracy of a temperature-modulated gas sensor using an ensemble of classifiers , 2013 .