论文信息 - The template-directed synthesis of porphyrin-stoppered[2]rotaxanes

The template-directed synthesis of porphyrin-stoppered[2]rotaxanes

Two [2]rotaxanes, composed of (i) a polyether chain intercepted by (a) one centrally-located and (b) two symmetrically-located π-electron-rich hydroquinol rings and terminated by free-base and metallated (Zn) tetraaryl-porphyrin groups respectively and (ii) a tetracationic cyclophane constructed of two π-electron-deficient bipyridinium units linked by paraphenylenedimethyl residues, have been self-assembled by a clipping procedure.

[1] J. Ibers,et al. The synthesis of some substituted tetraarylporphyrins , 1975 .

[2] G. Whitesides,et al. Molecular self-assembly and nanochemistry: a chemical strategy for the synthesis of nanostructures. , 1991, Science.

[3] G. Wenz,et al. Threading Cyclodextrin Rings on Polymer Chains , 1992 .

[4] David J. Williams,et al. Molecular meccano. 1. [2]Rotaxanes and a [2]catenane made to order , 1992 .

[5] Akira Harada,et al. The molecular necklace: a rotaxane containing many threaded α-cyclodextrins , 1992, Nature.

[6] David J. Williams,et al. The template-directed synthesis of a [2]rotaxane , 1991 .

[7] Martin R. Johnson,et al. Synthesis and characterization of quinone-substituted octaalkyl porphyrin monomers and dimers , 1990 .

[8] S. Gellman,et al. On the use of AM1 calculations for the study of intramolecular hydrogen bonding phenomena in simple amides , 1992 .

[9] J Fraser Stoddart,et al. A molecular shuttle. , 1991, Journal of the American Chemical Society.

[10] Angel E. Kaifer,et al. Novel class of asymmetric zwitterionic rotaxanes based on α-cyclodextrin , 1991 .

[11] Jonathan S. Lindsey,et al. Self-Assembly in Synthetic Routes to Molecular Devices. Biological Principles and Chemical Perspectives: A Review , 1991 .

[12] H. Gibson,et al. Synthesis and some properties of polyrotaxanes comprised of polyurethane backbone and crown ethers , 1992 .