Liquid crystal device with 50 nm nanogroove structure fabricated by nanoimprint lithography

We have investigated the alignment of nematic liquid crystals (NLCs) using 50 nm ultrafine nanogrooves fabricated by electron-beam (EB) lithography and nanoimprint lithography. To improve the wettability of NLCs, silicon dioxide was sputtered onto the NLCs after nanogroove fabrication. The azimuthal and polar anchoring energies obtained were 9.4×10−5 J/m2 and 3.6×10−4 J/m2, respectively. From the electro-optical characteristic of a twisted nematic (TN) liquid crystal (LC) cell, the contrast ratio of the TN cell was found to be 44:1, which is a relatively low value because of the misalignment of the EB exposure. However, a steeper and common threshold voltage was obtained for the TN LC cell.

[1]  VAN DER WAALS DISPERSION FORCE CONTRIBUTION TO THE INTERFACIAL FREE ENERGY OF NEMATIC LIQUID CRYSTALS , 1979 .

[2]  E Marom,et al.  Phase-only modulation with twisted nematic liquid-crystal spatial light modulators. , 1988, Optics letters.

[3]  H. Yokoyama,et al.  Critical Reexamination of Berreman's Theory on Surface Anchoring , 2010 .

[4]  Hiroshi Yokoyama,et al.  Surface-groove-induced azimuthal anchoring of a nematic liquid crystal: Berreman's model reexamined. , 2007, Physical review letters.

[5]  T. Kawamura,et al.  High Surface Ordering of Nematic Liquid Crystal Using Periodicity Grating , 1981 .

[6]  Noel A. Clark,et al.  Alignment of liquid crystals by topographically patterned polymer films prepared by nanoimprint lithography , 2007 .

[7]  D. C. Shaver,et al.  Alignment of liquid crystals using submicrometer periodicity gratings , 1978 .

[8]  M. Scalerandi,et al.  Effects of weak anchoring on the equivalent anchoring energy in a nematic cell with large amplitude of the grooves , 2008 .

[9]  K. Okano Anisotropic Excluded Volume Effect and Alignment of Nematic Liquid Crystal in a Sandwich Cell , 1983 .

[10]  H. Tarry,et al.  The optical properties of twisted nematic liquid crystal structures with twist angles ⩽90 degrees , 1975 .

[11]  Hiroshi Hiroshima,et al.  Room temperature replication in spin on glass by nanoimprint technology , 2001 .

[12]  J. Cliff Jones,et al.  The Zenithal Bistable Display: From concept to consumer , 2008 .

[13]  D. W. Berreman,et al.  Alignment of Liquid Crystals by Grooved Surfaces , 1973 .

[14]  H. Okada,et al.  Alignment of Nematic Liquid Crystal Molecules Using Nanometer-Sized Ultrafine Patterns By Electron Beam Exposure Method , 2005 .

[15]  Hiroshi Yokoyama,et al.  A novel method for determining the anchoring energy function at a nematic liquid crystal‐wall interface from director distortions at high fields , 1985 .

[16]  Tatsuo Uchida,et al.  Control of Liquid Crystal Alignment Using Stamped-Morphology Method , 1993 .

[17]  Tatsuo Uchida,et al.  Relationship between Rubbing Strength and Surface Anchoring of Nematic Liquid Crystal , 1992 .

[18]  Generalization of Berreman's model to the case of large amplitude of the grooves. , 2008, Physical review. E, Statistical, nonlinear, and soft matter physics.

[19]  Min Jiang,et al.  Method of Studying Surface Torsional Anchoring of Nematic Liquid Crystal , 1994 .

[20]  Color plastic bistable nematic display fabricated by imprint and ink‐jet technology , 2009 .

[21]  Wayne M. Gibbons,et al.  Surface-mediated alignment of nematic liquid crystals with polarized laser light , 1991, Nature.

[22]  Stephen Y. Chou,et al.  Imprint of sub-25 nm vias and trenches in polymers , 1995 .

[23]  Jan Haisma,et al.  Mold‐assisted nanolithography: A process for reliable pattern replication , 1996 .

[24]  Michinori Honma,et al.  Influence of Elastic Constants on the Optical Properties of Liquid Crystal Microlenses , 1997 .