PM2.5 and Associated Polycyclic Aromatic Hydrocarbon and Mutagenicity Emissions from Motorcycles

In this study, PM2.5 in diluted exhausts of motorcycles are collected and emission characteristics of PM2.5-associated polycyclic aromatic hydrocarbons (PAHs) and mutagenicities are investigated. The measured mutagenicity emission factors with metabolic activation for new fuel injection, used fuel injection, new carburetor and used carburetor motorcycles are 7.77 × 104, 1.18 × 105, 1.32 × 105 and 1.15 × 105 rev/km, respectively. The mutagenicity emission factors with metabolic activation are higher than the corresponding values without metabolic activation. The average PAH emission factors are 12.3, 16.3, 25.5 and 26.5 μg/km for new and used fuel-injection motorcycles, and new and used carburetor-operated motorcycles, respectively. The correlation coefficients between PAHs and mutagenicity emission factors are higher with metabolic activation (0.59) than that without metabolic activation (0.31).

[1]  R. Burnett,et al.  Lung cancer, cardiopulmonary mortality, and long-term exposure to fine particulate air pollution. , 2002, JAMA.

[2]  Takahiro Kobayashi,et al.  Bioassay-directed fractionation and salmonella mutagenicity of automobile and forklift diesel exhaust particles. , 2003, Environmental health perspectives.

[3]  M. Maricq Chemical characterization of particulate emissions from diesel engines: A review , 2007 .

[4]  S. Greaves Variability of Personal Exposure to Fine Particulates for Urban Commuters inside Automobiles , 2006 .

[5]  Jiamo Fu,et al.  Atmospheric levels and cytotoxicity of PAHs and heavy metals in TSP and PM2.5 at an electronic waste recycling site in southeast China , 2006 .

[6]  D. Bleyl,et al.  IARC Monographs on the Evaluation of Carcinogenic Risks to Humans. Overall Evaluations of Carcinogenicity: An Updating of IARC Monographs vol. 1 to 42. Supplement 7. 440 Seiten. International Agency for Research on Cancer, Lyon 1987. Preis: 65, – s.Fr , 1989 .

[7]  J S Lighty,et al.  Combustion Aerosols: Factors Governing Their Size and Composition and Implications to Human Health , 2000, Journal of the Air & Waste Management Association.

[8]  Leonidas Ntziachristos,et al.  Particulate matter regulation for two-stroke two wheelers: Necessity or haphazard legislation? , 2005 .

[9]  K. Grägg,et al.  Chemical and biological characterization of particulate-, semivolatile-, and gas-phase-associated compounds in diluted heavy-duty diesel exhausts: a comparison of three different semivolatile-phase samplers , 1991 .

[10]  Hsi-Hsien Yang,et al.  Polycyclic aromatic hydrocarbon emissions from motorcycles , 2005 .

[11]  C. Matthies,et al.  Targeting ERK1/2 activation and proliferation in human primary schwannoma cells with MEK1/2 inhibitor AZD6244 , 2010, Neurobiology of Disease.

[12]  K. Prather,et al.  Comparison of oil and fuel particle chemical signatures with particle emissions from heavy and light duty vehicles , 2006 .

[13]  B. Ames,et al.  Revised methods for the Salmonella mutagenicity test. , 1983, Mutation research.

[14]  R. K. Larsen,et al.  Source apportionment of polycyclic aromatic hydrocarbons in the urban atmosphere: a comparison of three methods. , 2003, Environmental science & technology.

[15]  Hsi-Hsien Yang,et al.  Particle size distribution of polycyclic aromatic hydrocarbons in motorcycle exhaust emissions. , 2005, Journal of hazardous materials.