Water desalination by forward (direct) osmosis phenomenon: A comprehensive review

Abstract Forward osmosis (FO) is a developing technology, which is thought to have a potential of producing potable water in an energy-efficient manner. FO is driven by the natural osmotic pressure difference across a semi-permeable membrane. Despite a number of patents and peer-reviewed papers published for different methods and systems for water desalination by FO, this technology is still in its infancy because of some serious limitations and challenges. Due to many environment and energy related challenges, FO-based desalination has recently gained worldwide attention because it operates at low levels of pressure and temperature. Compared to traditional pressure-driven membrane processes, FO offers recognized advantages including reversible membrane fouling, and potentially less operation energy. The purpose of this review paper is to provide the state-of-the-art of the physical principles, recent developments, and applications of forward osmosis in the area of water desalination. Strengths and limitations of the applications of FO processes in the area of water desalination are highlighted and the future of FO technology is considered.

[1]  Fenglin Yang,et al.  Use of a spacer to mitigate concentration polarization during forward osmosis process , 2014 .

[2]  M. Elimelech,et al.  Organic fouling of forward osmosis membranes: Fouling reversibility and cleaning without chemical reagents , 2010 .

[3]  Ahmad Fauzi Ismail,et al.  Synthesis of thin film nanocomposite forward osmosis membrane with enhancement in water flux without sacrificing salt rejection , 2013 .

[4]  S. Loeb,et al.  Production of energy from concentrated brines by pressure-retarded osmosis : II. Experimental results and projected energy costs , 1976 .

[5]  Sidney Loeb,et al.  Production of energy from concentrated brines by pressure-retarded osmosis , 1976 .

[6]  K. Petrotos,et al.  Direct osmotic concentration of tomato juice in tubular membrane – module configuration. II. The effect of using clarified tomato juice on the process performance , 1999 .

[7]  Andrew G. Livingston,et al.  Method for the preparation of cellulose acetate flat sheet composite membranes for forward osmosis—Desalination using MgSO4 draw solution , 2011 .

[8]  Sui Zhang,et al.  Forward osmosis: an emerging technology for sustainable supply of clean water , 2012, Clean Technologies and Environmental Policy.

[9]  Peng Wang,et al.  A Dendrimer-Based Forward Osmosis Draw Solute for Seawater Desalination , 2014 .

[10]  Ali Altaee,et al.  Comparison between Forward Osmosis-Reverse Osmosis and Reverse Osmosis processes for seawater desalination , 2014 .

[11]  Chuyang Y. Tang,et al.  Direct microscopic observation of forward osmosis membrane fouling by microalgae: Critical flux and the role of operational conditions , 2013 .

[12]  May-Britt Hägg,et al.  Pressure Retarded Osmosis and Forward Osmosis Membranes: Materials and Methods , 2013 .

[13]  Tai‐Shung Chung,et al.  The role of sulphonated polymer and macrovoid-free structure in the support layer for thin-film comp , 2011 .

[14]  Tai‐Shung Chung,et al.  Thin film composite forward-osmosis membranes with enhanced internal osmotic pressure for internal concentration polarization reduction , 2014 .

[15]  D. Zarzo,et al.  Desalination techniques — A review of the opportunities for desalination in agriculture , 2015 .

[16]  Menachem Elimelech,et al.  A novel ammonia-carbon dioxide forward (direct) osmosis desalination process , 2005 .

[17]  Tai‐Shung Chung,et al.  Draw solutions for forward osmosis processes: Developments, challenges, and prospects for the future , 2013 .

[18]  Shuaifei Zhao,et al.  Relating solution physicochemical properties to internal concentration polarization in forward osmos , 2011 .

[19]  W. Pusch,et al.  Relation between salt rejection r and reflection coefficient σ of asymmetric cellulose acetate membranes , 1974 .

[20]  Menachem Elimelech,et al.  Mitigating biofouling on thin-film composite polyamide membranes using a controlled-release platform , 2014 .

[21]  Minkyu Park,et al.  Modeling of colloidal fouling in forward osmosis membrane: Effects of reverse draw solution permeation , 2013 .

[22]  Rong Wang,et al.  Towards temperature driven forward osmosis desalination using Semi-IPN hydrogels as reversible draw agents. , 2013, Water research.

[23]  Laura Chekli,et al.  A review of draw solutes in forward osmosis process and their use in modern applications , 2012 .

[24]  P. Sukitpaneenit,et al.  High performance thin-film composite forward osmosis hollow fiber membranes with macrovoid-free and highly porous structure for sustainable water production. , 2012, Environmental science & technology.

[25]  J. Post,et al.  Salinity-gradient power : Evaluation of pressure-retarded osmosis and reverse electrodialysis , 2007 .

[26]  Rong Wang,et al.  Fabrication of novel poly(amide–imide) forward osmosis hollow fiber membranes with a positively charged nanofiltration-like selective layer , 2011 .

[27]  Markku J. Lampinen,et al.  Thermodynamic optimizing of pressure-retarded osmosis power generation systems , 1999 .

[28]  Rong Wang,et al.  High performance flat sheet forward osmosis membrane with an NF-like selective layer on a woven fabric embedded substrate , 2012 .

[29]  Johannes S. Vrouwenvelder,et al.  Water harvesting from municipal wastewater via osmotic gradient: An evaluation of process performance , 2013 .

[30]  Chuyang Y. Tang,et al.  Removal of boron and arsenic by forward osmosis membrane: Influence of membrane orientation and organic fouling , 2012 .

[31]  Ligia Damasceno Ferreira Marczak,et al.  Membrane concentration of liquid foods by forward osmosis: Process and quality view , 2012 .

[32]  Mohsen Jahanshahi,et al.  The effect of SiO2 nanoparticles on morphology and performance of thin film composite membranes for forward osmosis application , 2014 .

[33]  Robert W. Field,et al.  Mass transfer limitations in forward osmosis: Are some potential applications overhyped? , 2013 .

[34]  Kaitlin Johnson,et al.  Poly(vinyl) alcohol coating of the support layer of reverse osmosis membranes to enhance performance in forward osmosis , 2014 .

[35]  Peng Wang,et al.  Sustainable water recovery from oily wastewater via forward osmosis-membrane distillation (FO-MD). , 2014, Water research.

[36]  Rong Wang,et al.  Synthesis and characterization of flat-sheet thin film composite forward osmosis membranes , 2011 .

[37]  N. Rastogi,et al.  Influence of concentration polarization on flux behavior in forward osmosis during desalination using ammonium bicarbonate , 2013 .

[38]  Tzahi Y Cath,et al.  Removal of natural steroid hormones from wastewater using membrane contactor processes. , 2006, Environmental science & technology.

[39]  S. Loeb Energy production at the Dead Sea by pressure-retarded osmosis: challenge or chimera? , 1998 .

[40]  H. Ngo,et al.  A mini-review on membrane fouling. , 2012, Bioresource technology.

[41]  Linda Zou,et al.  Effects of working temperature on separation performance, membrane scaling and cleaning in forward osmosis desalination , 2011 .

[42]  J. McCutcheon,et al.  Influence of concentrative and dilutive internal concentration polarization on flux behavior in forward osmosis , 2006 .

[43]  Chuyang Y. Tang,et al.  Computational fluid dynamics simulations of flow and concentration polarization in forward osmosis membrane systems , 2011 .

[44]  Menachem Elimelech,et al.  Post-fabrication modification of forward osmosis membranes with a poly(ethylene glycol) block copolymer for improved organic fouling resistance , 2015 .

[45]  Kai Yu Wang,et al.  Highly Water-Soluble Magnetic Nanoparticles as Novel Draw Solutes in Forward Osmosis for Water Reuse , 2010 .

[46]  Chuyang Y. Tang,et al.  Synthesis and characterization of novel forward osmosis membranes based on layer-by-layer assembly. , 2011, Environmental science & technology.

[47]  Menachem Elimelech,et al.  Coupled reverse draw solute permeation and water flux in forward osmosis with neutral draw solutes , 2012 .

[48]  Tong Zhan,et al.  Flux patterns and membrane fouling propensity during desalination of seawater by forward osmosis. , 2012, Water research.

[49]  R. G. Raluy,et al.  Life cycle assessment of desalination technologies integrated with renewable energies , 2005 .

[50]  Ngai Yin Yip,et al.  Thermodynamic and energy efficiency analysis of power generation from natural salinity gradients by pressure retarded osmosis. , 2012, Environmental science & technology.

[51]  Dan Li,et al.  Composite polymer hydrogels as draw agents in forward osmosis and solar dewatering , 2011 .

[52]  J. Schultz,et al.  Hindered Diffusion in Microporous Membranes with Known Pore Geometry , 1970, Science.

[53]  D.J.H. Harmsen,et al.  Membrane fouling and process performance of forward osmosis membranes on activated sludge , 2008 .

[54]  Gang Han,et al.  Thin-film composite forward osmosis membranes with novel hydrophilic supports for desalination , 2012 .

[55]  Rong Wang,et al.  Preparation of polyamide thin film composite forward osmosis membranes using electrospun polyvinylidene fluoride (PVDF) nanofibers as substrates , 2013 .

[56]  Bhekie B. Mamba,et al.  Organic fouling in forward osmosis membranes: the role of feed solution chemistry and membrane structural properties , 2014 .

[57]  S. Loeb,et al.  Internal polarization in the porous substructure of a semipermeable membrane under pressure-retarded osmosis , 1978 .

[58]  Menachem Elimelech,et al.  Modeling water flux in forward osmosis: Implications for improved membrane design , 2007 .

[59]  Qibo Jia,et al.  Effects of CTAC micelles on the molecular structures and separation performance of thin-film composite (TFC) membranes in forward osmosis processes , 2014 .

[60]  How Yong Ng,et al.  Modified models to predict flux behavior in forward osmosis in consideration of external and internal concentration polarizations , 2008 .

[61]  Menachem Elimelech,et al.  Comparison of fouling behavior in forward osmosis (FO) and reverse osmosis (RO) , 2010 .

[62]  Dan Li,et al.  Stimuli-responsive polymer hydrogels as a new class of draw agent for forward osmosis desalination. , 2011, Chemical communications.

[63]  Kees Roest,et al.  Water recovery from sewage using forward osmosis. , 2011, Water science and technology : a journal of the International Association on Water Pollution Research.

[64]  Menachem Elimelech,et al.  Comparison of the removal of hydrophobic trace organic contaminants by forward osmosis and reverse osmosis. , 2012, Water research.

[65]  B. Freeman,et al.  Surface modification of thin film composite membrane support layers with polydopamine: Enabling use , 2011 .

[66]  Tai‐Shung Chung,et al.  Novel thin-film composite tri-bore hollow fiber membrane fabrication for forward osmosis , 2014 .

[67]  Ming Ming Ling,et al.  Desalination process using super hydrophilic nanoparticles via forward osmosis integrated with ultrafiltration regeneration , 2011 .

[68]  Minkyu Park,et al.  Simulation of forward osmosis membrane process: Effect of membrane orientation and flow direction of feed and draw solutions , 2011 .

[69]  Gary L. Amy,et al.  Hydrophilic Superparamagnetic Nanoparticles: Synthesis, Characterization, and Performance in Forward Osmosis Processes , 2011 .

[70]  Dana Karl Anderson Concentration of Dilute Industrial Wastes by Direct Osmosis , 1977 .

[71]  Jincai Su,et al.  Exploration of polyelectrolytes as draw solutes in forward osmosis processes. , 2012, Water research.

[72]  Ho Kyong Shon,et al.  Physicochemical pretreatment of seawater: fouling reduction and membrane characterization , 2009 .

[73]  Chuyang Y. Tang,et al.  Network modeling for studying the effect of support structure on internal concentration polarization , 2011 .

[74]  Raphael Semiat,et al.  Energy issues in desalination processes. , 2008, Environmental science & technology.

[75]  Hasan F. Makki,et al.  Forward Osmosis Process for the Treatment of Wastewater from Textile Industries , 2013 .

[76]  Menachem Elimelech,et al.  Relating rejection of trace organic contaminants to membrane properties in forward osmosis: measurements, modelling and implications. , 2014, Water research.

[77]  Michael D. Guiver,et al.  Polyamide thin-film composite membranes based on carboxylated polysulfone microporous support membranes for forward osmosis , 2013 .

[78]  Mohammad Badruzzaman,et al.  Energy minimization strategies and renewable energy utilization for desalination: a review. , 2011, Water research.

[79]  Seungkwan Hong,et al.  Fouling distribution in forward osmosis membrane process. , 2014, Journal of environmental sciences.

[80]  Nidal Hilal,et al.  A review on the applicability of integrated/hybrid membrane processes in water treatment and desalination plants , 2015 .

[81]  Amy E. Childress,et al.  Forward osmosis: Principles, applications, and recent developments , 2006 .

[82]  Sui Zhang,et al.  Molecular design of the cellulose ester-based forward osmosis membranes for desalination , 2011 .

[83]  Jeffrey R. McCutcheon,et al.  Electrospun nanofiber supported thin film composite membranes for engineered osmosis , 2011 .

[84]  Panagiotis D. Christofides,et al.  Analysis of forward osmosis desalination via two-dimensional FEM model , 2014 .

[85]  Mark L. Stone,et al.  SWITCHABLE POLARITY SOLVENTS AS DRAW SOLUTES FOR FORWARD OSMOSIS , 2013 .

[86]  A. Al-Ibrahim,et al.  Seawater desalination: the strategic choice for Saudi Arabia , 2013 .

[87]  Qingchun Ge,et al.  Ferric and cobaltous hydroacid complexes for forward osmosis (FO) processes. , 2014, Water research.

[88]  Marcel Mulder,et al.  Basic Principles of Membrane Technology , 1991 .

[89]  Frank R. Rijsberman,et al.  Water scarcity: Fact or fiction? , 2006 .

[90]  Linda Zou,et al.  Recent developments in forward osmosis : opportunities and challenges. , 2012 .

[91]  In-Chul Kim,et al.  Nanoporous polyethersulfone (PES) membrane with enhanced flux applied in forward osmosis process , 2011 .

[92]  Markku J. Lampinen,et al.  On the non-linearity of osmotic flow , 2004 .

[93]  Menachem Elimelech,et al.  In situ formation of silver nanoparticles on thin-film composite reverse osmosis membranes for biofouling mitigation. , 2014, Water research.

[94]  S. Loeb Large-scale power production by pressure-retarded osmosis, using river water and sea water passing through spiral modules , 2002 .

[95]  Benny D. Freeman,et al.  Solute and water transport in forward osmosis using polydopamine modified thin film composite membranes , 2014 .

[96]  How Yong Ng,et al.  Fabrication of layered silica–polysulfone mixed matrix substrate membrane for enhancing performance of thin-film composite forward osmosis membrane , 2015 .

[97]  H. Lazarides,et al.  Osmotic concentration of liquid foods , 2001 .

[98]  Nicholas P. Hankins,et al.  Water flux dynamics in closed-loop, batch-mode forward osmosis systems , 2015 .

[99]  Chuyang Y. Tang,et al.  Characteristics and potential applications of a novel forward osmosis hollow fiber membrane , 2010 .

[100]  E. Drioli,et al.  Recent advances on membrane processes for the concentration of fruit juices: a review , 2004 .

[101]  K. Petrotos,et al.  A study of the direct osmotic concentration of tomato juice in tubular membrane – module configuration. I. The effect of certain basic process parameters on the process performance , 1998 .

[102]  Li Gang,et al.  Forward Osmosis and Concentration Polarization , 2010 .

[103]  Seeram Ramakrishna,et al.  Multifunctional carbon nanotubes in water treatment: The present, past and future , 2014 .

[104]  Chengbo Hu,et al.  A study of poly (sodium 4-styrenesulfonate) as draw solute in forward osmosis , 2015 .

[105]  Guojun Zhang,et al.  Self-assembly of polyelectrolyte multilayer pervaporation membranes by a dynamic layer-by-layer technique on a hydrolyzed polyacrylonitrile ultrafiltration membrane , 2007 .

[106]  Linda Zou,et al.  Effects of membrane orientation on process performance in forward osmosis applications , 2011 .

[107]  Rong Wang,et al.  Fabrication of novel functionalized multi-walled carbon nanotube immobilized hollow fiber membranes for enhanced performance in forward osmosis process , 2013 .

[108]  Tzahi Y. Cath,et al.  Selection of inorganic-based draw solutions for forward osmosis applications , 2010 .

[109]  Qian Yang,et al.  Cellulose acetate nanofiltration hollow fiber membranes for forward osmosis processes , 2010 .

[110]  Peter Grathwohl,et al.  Diffusion in Natural Porous Media: Contaminant Transport, Sorption/Desorption and Dissolution Kinetics , 1998 .

[111]  Rong Wang,et al.  A modeling investigation on optimizing the design of forward osmosis hollow fiber modules , 2012 .

[112]  Chuyang Y. Tang,et al.  Forward osmosis with a novel thin-film inorganic membrane. , 2013, Environmental science & technology.

[113]  Tzahi Y. Cath,et al.  The sweet spot of forward osmosis: Treatment of produced water, drilling wastewater, and other complex and difficult liquid streams , 2014 .

[114]  Sato Yuya,et al.  Forward osmosis using dimethyl ether as a draw solute , 2014 .

[115]  M. Elimelech,et al.  The Future of Seawater Desalination: Energy, Technology, and the Environment , 2011, Science.

[116]  S. Loeb,et al.  Performance of permasep B-9 and B-10 membranes in various osmotic regions and at high osmotic pressures , 1978 .

[117]  Menachem Elimelech,et al.  Removal of trace organic contaminants by the forward osmosis process , 2013 .

[118]  John J. Kozak,et al.  Solute‐Solute Interactions in Aqueous Solutions , 1968 .

[119]  Andrew L. Zydney,et al.  Stagnant film model for concentration polarization in membrane systems , 1997 .

[120]  Nawshad Akther,et al.  Recent advancements in forward osmosis desalination: A review , 2015 .

[121]  Menachem Elimelech,et al.  High performance thin-film composite forward osmosis membrane. , 2010, Environmental science & technology.

[122]  Menachem Elimelech,et al.  Fouling control in a forward osmosis process integrating seawater desalination and wastewater reclamation , 2013 .

[123]  Menachem Elimelech,et al.  Performance limiting effects in power generation from salinity gradients by pressure retarded osmosis. , 2011, Environmental science & technology.

[124]  L. Rietveld,et al.  Forward osmosis for application in wastewater treatment: a review. , 2014, Water research.

[125]  Seockheon Lee,et al.  Modeling reverse draw solute flux in forward osmosis with external concentration polarization in both sides of the draw and feed solution , 2013 .

[126]  Menachem Elimelech,et al.  Amine enrichment and poly(ethylene glycol) (PEG) surface modification of thin-film composite forward osmosis membranes for organic fouling control , 2014 .

[127]  A. Ismail,et al.  A novel thin film composite forward osmosis membrane prepared from PSf–TiO2 nanocomposite substrate for water desalination , 2014 .

[128]  Tai-Shung Chung,et al.  Forward osmosis processes: Yesterday, today and tomorrow , 2012 .

[129]  Amy E. Childress,et al.  Power generation with pressure retarded osmosis: An experimental and theoretical investigation , 2009 .

[130]  Tongwen Xu,et al.  Preparation of polyethersulfone/carbon nanotube substrate for high-performance forward osmosis membrane , 2013 .

[131]  E R Cornelissen,et al.  The innovative osmotic membrane bioreactor (OMBR) for reuse of wastewater. , 2011, Water science and technology : a journal of the International Association on Water Pollution Research.

[132]  Fenglin Yang,et al.  Forward osmosis using electric-responsive polymer hydrogels as draw agents: Influence of freezing–thawing cycles, voltage, feed solutions on process performance , 2015 .

[133]  Menachem Elimelech,et al.  In situ surface chemical modification of thin-film composite forward osmosis membranes for enhanced organic fouling resistance. , 2013, Environmental science & technology.

[134]  T. Holt,et al.  The potential for power production from salinity gradients by pressure retarded osmosis , 2009 .

[135]  H. Ng,et al.  Revised external and internal concentration polarization models to improve flux prediction in forward osmosis process , 2013 .

[136]  Kai Yu Wang,et al.  Study of draw solutes using 2-methylimidazole-based compounds in forward osmosis , 2010 .

[137]  Isabel C. Escobar,et al.  Chapter 14 Conclusion: A Summary of Challenges still Facing Desalination and Water Reuse , 2010 .

[138]  A. Haute,et al.  The use of direct osmosis tests as complementary experiments to determine the water and salt permeabilities of reinforced cellulose acetate membranes , 1978 .

[139]  William A. Phillip,et al.  Forward Osmosis Processes in the Limit of Osmotic Equilibrium , 2015 .

[140]  Sui Zhang,et al.  POSS-containing delamination-free dual-layer hollow fiber membranes for forward osmosis and osmotic power generation , 2013 .

[141]  Tzahi Y. Cath,et al.  Membrane contactor processes for wastewater reclamation in space: II. Combined direct osmosis, osmotic distillation, and membrane distillation for treatment of metabolic wastewater , 2005 .

[142]  Chuyang Y. Tang,et al.  Coupled effects of internal concentration polarization and fouling on flux behavior of forward osmosis membranes during humic acid filtration , 2010 .

[143]  Joseph G Jacangelo,et al.  Emerging desalination technologies for water treatment: a critical review. , 2015, Water research.

[144]  J. McCutcheon,et al.  Internal concentration polarization in forward osmosis: role of membrane orientation , 2006 .

[145]  Clark K. Colton,et al.  The osmotic pressure of concentrated protein solutions: Effect of concentration and ph in saline solutions of bovine serum albumin , 1981 .

[146]  Chuyang Y. Tang,et al.  Synthesis of high flux forward osmosis membranes by chemically crosslinked layer-by-layer polyelectr , 2011 .

[147]  Mark L. Stone,et al.  An initial study of hexavalent phosphazene salts as draw solutes in forward osmosis , 2013 .

[148]  Ronan K. McGovern,et al.  On the potential of forward osmosis to energetically outperform reverse osmosis desalination , 2014 .

[149]  Jay R. Werber,et al.  Forward osmosis: Where are we now? , 2015 .

[150]  Sherub Phuntsho,et al.  Osmotic equilibrium in the forward osmosis process: Modelling, experiments and implications for process performance , 2014 .

[151]  Jincai Su,et al.  Sublayer structure and reflection coefficient and their effects on concentration polarization and me , 2011 .

[152]  Anthony G Fane,et al.  Direct microscopic observation of forward osmosis membrane fouling. , 2010, Environmental science & technology.

[153]  Zhenyu Li,et al.  Indirect desalination of Red Sea water with forward osmosis and low pressure reverse osmosis for water reuse , 2011 .

[154]  Sang-Jin Park,et al.  Operation and simulation of pilot-scale forward osmosis desalination with ammonium bicarbonate , 2015 .

[155]  Gary L. Amy,et al.  Well-constructed cellulose acetate membranes for forward osmosis: Minimized internal concentration polarization with an ultra-thin selective layer , 2010 .

[156]  Ho Kyong Shon,et al.  Organic fouling mechanisms in forward osmosis membrane process under elevated feed and draw solution temperatures , 2015 .

[157]  Jincai Su,et al.  Enhanced double-skinned FO membranes with inner dense layer for wastewater treatment and macromolecule recycle using Sucrose as draw solute , 2012 .

[158]  R. Baker Membrane Technology and Applications , 1999 .

[159]  Kai Yu Wang,et al.  Double-Skinned Forward Osmosis Membranes for Reducing Internal Concentration Polarization within the Porous Sublayer , 2010 .

[160]  Anthony G Fane,et al.  Fouling propensity of forward osmosis: investigation of the slower flux decline phenomenon. , 2010, Water science and technology : a journal of the International Association on Water Pollution Research.

[161]  Xiaoxiao Song,et al.  Nano Gives the Answer: Breaking the Bottleneck of Internal Concentration Polarization with a Nanofiber Composite Forward Osmosis Membrane for a High Water Production Rate , 2011, Advanced materials.

[162]  Chuyang Y. Tang,et al.  Characterization of internal and external concentration polarizations during forward osmosis processes , 2014 .

[163]  Kai Yu Wang,et al.  Polybenzimidazole (PBI) nanofiltration hollow fiber membranes applied in forward osmosis process , 2007 .

[164]  Tzahi Y Cath,et al.  Solute coupled diffusion in osmotically driven membrane processes. , 2009, Environmental science & technology.

[165]  Menachem Elimelech,et al.  Gypsum scaling and cleaning in forward osmosis: measurements and mechanisms. , 2010, Environmental science & technology.

[166]  Tzahi Y Cath,et al.  Forward osmosis for concentration of anaerobic digester centrate. , 2007, Water research.

[167]  Menachem Elimelech,et al.  Combined organic and colloidal fouling in forward osmosis: Fouling reversibility and the role of applied pressure , 2014 .

[168]  Hern Kim,et al.  Low internal concentration polarization in forward osmosis membranes with hydrophilic crosslinked PVA nanofibers as porous support layer , 2014 .

[169]  A. Yokozeki,et al.  Osmotic pressures studied using a simple equation-of-state and its applications , 2006 .

[170]  Mohsen Jahanshahi,et al.  Synthesis of novel thin film nanocomposite (TFN) forward osmosis membranes using functionalized multi-walled carbon nanotubes , 2013 .

[171]  Bo Jin,et al.  Functionalized thermo-responsive microgels for high performance forward osmosis desalination. , 2015, Water research.

[172]  Kang Li,et al.  Fabrication and characterization of forward osmosis hollow fiber membranes with antifouling NF-like selective layer , 2012 .

[173]  Rui Chin Ong,et al.  Novel Cellulose Esters for Forward Osmosis Membranes , 2012 .

[174]  S. Loeb,et al.  Effect of porous support fabric on osmosis through a Loeb-Sourirajan type asymmetric membrane , 1997 .

[175]  Qian Yang,et al.  Dual-layer hollow fibers with enhanced flux as novel forward osmosis membranes for water production. , 2009, Environmental science & technology.

[176]  How Yong Ng,et al.  Forward osmosis organic fouling: Effects of organic loading, calcium and membrane orientation , 2013 .

[177]  Nanqi Ren,et al.  Temperature as a factor affecting transmembrane water flux in forward osmosis: Steady-state modeling and experimental validation , 2012 .

[178]  C. D. Lundin,et al.  A multi-barrier osmotic dilution process for simultaneous desalination and purification of impaired water , 2010 .

[179]  J S Vrouwenvelder,et al.  Forward osmosis niches in seawater desalination and wastewater reuse. , 2014, Water research.

[180]  M. Elimelech,et al.  Membrane-based processes for sustainable power generation using water , 2012, Nature.

[181]  Edward Beaudry,et al.  DIRECT OSMOSIS FOR CONCENTRATING WASTEWATER , 1997 .

[182]  Menachem Elimelech,et al.  Global challenges in energy and water supply: the promise of engineered osmosis. , 2008, Environmental science & technology.

[183]  Jeffrey R. McCutcheon,et al.  Proper accounting of mass transfer resistances in forward osmosis: Improving the accuracy of model predictions of structural parameter , 2015 .

[184]  Ahmed Aidan,et al.  Draw solute recovery by metathesis precipitation in forward osmosis desalination. , 2013 .

[185]  Qian Yang,et al.  Enhanced forward osmosis from chemically modified polybenzimidazole (PBI) nanofiltration hollow fiber membranes with a thin wall , 2009 .

[186]  Ahmed Aidan,et al.  Copper sulfate as draw solute in forward osmosis desalination , 2013 .

[187]  Seockheon Lee,et al.  Evaluation of citrate-coated magnetic nanoparticles as draw solute for forward osmosis , 2014 .

[188]  Chuyang Y. Tang,et al.  Double-skinned forward osmosis membranes based on layer-by-layer assembly—FO performance and fouling behavior , 2012 .

[189]  Peng Wang,et al.  Thermoresponsive copolymer-based draw solution for seawater desalination in a combined process of forward osmosis and membrane distillation , 2014 .

[190]  Seungkwan Hong,et al.  A novel analysis of reverse draw and feed solute fluxes in forward osmosis membrane process , 2014 .

[191]  Rong Wang,et al.  Novel dual-layer hollow fiber membranes applied for forward osmosis process , 2012 .

[192]  Tae-woo Kim,et al.  Systematic approach for draw solute selection and optimal system design for forward osmosis desalination , 2012 .

[193]  C. D. Moody,et al.  Drinking water from sea water by forward osmosis , 1976 .

[194]  Menachem Elimelech,et al.  Highly hydrophilic thin-film composite forward osmosis membranes functionalized with surface-tailored nanoparticles. , 2012, ACS applied materials & interfaces.

[195]  Chuyang Y. Tang,et al.  Characterization of novel forward osmosis hollow fiber membranes , 2010 .

[196]  Emile R Cornelissen,et al.  Experimental studies and modeling on concentration polarization in forward osmosis. , 2010, Water science and technology : a journal of the International Association on Water Pollution Research.

[197]  Tongwen Xu,et al.  Thermo-sensitive polyelectrolytes as draw solutions in forward osmosis process , 2013 .

[198]  Amy E. Childress,et al.  The forward osmosis membrane bioreactor: A low fouling alternative to MBR processes , 2009 .

[199]  Menachem Elimelech,et al.  Reverse draw solute permeation in forward osmosis: modeling and experiments. , 2010, Environmental science & technology.

[200]  J. Smith,et al.  Introduction to chemical engineering thermodynamics , 1949 .

[201]  Chuyang Y. Tang,et al.  Zeolite-polyamide thin film nanocomposite membranes: Towards enhanced performance for forward osmosis , 2012 .

[202]  Lin Chen,et al.  A review on the recovery methods of draw solutes in forward osmosis , 2014 .

[203]  Richard E. Kravath,et al.  Desalination of sea water by direct osmosis , 1975 .

[204]  N. Widjojo,et al.  A sulfonated polyphenylenesulfone (sPPSU) as the supporting substrate in thin film composite (TFC) membranes with enhanced performance for forward osmosis (FO) , 2013 .

[205]  Michael Flynn,et al.  Membrane contactor processes for wastewater reclamation in space Part I. Direct osmotic concentration as pretreatment for reverse osmosis , 2005 .

[206]  Raphael Semiat,et al.  Finite element analysis of forward osmosis process using NaCl solutions , 2011 .

[207]  Menachem Elimelech,et al.  Performance evaluation of sucrose concentration using forward osmosis , 2009 .

[208]  I. Karagiannis,et al.  Water desalination cost literature: review and assessment , 2008 .

[209]  Ming Ming Ling,et al.  Surface-Dissociated Nanoparticle Draw Solutions in Forward Osmosis and the Regeneration in an Integrated Electric Field and Nanofiltration System , 2012 .

[210]  Dezhong Xiao,et al.  The role of physical and chemical parameters on forward osmosis membrane fouling during algae separa , 2011 .

[211]  Linda Zou,et al.  Brackish water desalination by a hybrid forward osmosis-nanofiltration system using divalent draw solute , 2012 .

[212]  Daniel Anastasio,et al.  Using forward osmosis to teach mass transfer fundamentals to undergraduate chemical engineering students , 2013 .

[213]  R. Baker,et al.  Membranes for power generation by pressure-retarded osmosis , 1981 .

[214]  Robert L McGinnis,et al.  Desalination by ammonia–carbon dioxide forward osmosis: Influence of draw and feed solution concentrations on process performance , 2006 .

[215]  François Zaviska,et al.  A case study of fouling development and flux reversibility of treating actual lake water by forward osmosis process , 2015 .

[216]  Menachem Elimelech,et al.  Chemical and physical aspects of organic fouling of forward osmosis membranes , 2008 .