Development of intrinsic optical fiber pH sensors for industrial applications

The development of intrinsic optical fiber pH sensors based on fluorescence from novel coumarin dyes which are covalently immobilized onto the distal end of the fiber is described. The sensors provide response in the pH range of 0.5–6 with good stability over 24 h. The response time of the sensors is approximately 25 s. The sensors show no sensitivity to ionic strength (IS) and have excellent photostability.

[1]  Christian Krause,et al.  Novel coumarin-based fluorescent pH indicators, probes and membranes covering a broad pH range , 2007, Analytical and bioanalytical chemistry.

[2]  D. Staneva,et al.  Synthesis and functional properties of new optical pH sensor based on benzo[de]anthracen-7-one immobilized on the viscose , 2007 .

[3]  Gerhard J. Mohr,et al.  Optical sensors for a wide pH range based on azo dyes immobilized on a novel support , 1994 .

[4]  W. Rudolf Seitz,et al.  pH sensor based on immobilized fluoresceinamine , 1982 .

[5]  J. Peterson,et al.  A fiber-optic broad-range pH sensor system for gastric measurements , 1995 .

[6]  B. T. Meggitt,et al.  Chemical and environmental sensing , 1999 .

[7]  M. Anpo,et al.  Multiple fluorescence spectra of fluorescein molecules encapsulated in the silica xerogel prepared by the sol-gel reaction , 1993 .

[8]  P. Radhakrishnan,et al.  A sensitive fibre optic pH sensor using multiple sol-gel coatings , 2001 .

[9]  W. D. Sloan,et al.  A fibre-optic calcium ion sensor using a calcein derivative. , 2001, Luminescence : the journal of biological and chemical luminescence.

[10]  Francisco J. Arregui,et al.  Optical fiber pH sensors based on layer-by-layer electrostatic self-assembled Neutral Red , 2008 .

[11]  Carlos Fernández-Valdivielso,et al.  An experimental study about the utilization of Liquicoat® solutions for the fabrication of pH optical fiber sensors , 2002 .

[12]  P. Krulevitch,et al.  In vitro and in vivo measurements of fiber optic and electrochemical sensors to monitor brain tissue pH , 2001 .

[13]  T. L. Yeo,et al.  Fibre-optic sensor technologies for humidity and moisture measurement , 2008 .

[14]  Jong Il Rhee,et al.  An optical pH sensor with extended detection range based on fluoresceinamine covalently bound to sol–gel support , 2006 .

[15]  R. Kaliszan,et al.  Combined pH/organic solvent gradient HPLC in analysis of forensic material. , 2005, Journal of pharmaceutical and biomedical analysis.

[16]  C. Seidel,et al.  Photobleaching of Fluorescent Dyes under Conditions Used for Single-Molecule Detection:  Evidence of Two-Step Photolysis. , 1998, Analytical chemistry.

[17]  S R Goldstein,et al.  Fiber optic pH probe for physiological use. , 1980, Analytical chemistry.

[18]  J. Anzai,et al.  Multilayered Assemblies Composed of Brilliant Yellow and Poly(allylamine) for an Optical pH Sensor , 2006, Analytical sciences : the international journal of the Japan Society for Analytical Chemistry.

[19]  A. Ensafi,et al.  Optical pH sensor based on chemical modification of polymer film , 1999 .

[20]  Jie Lin,et al.  Recent development and applications of optical and fiber-optic pH sensors , 2000 .

[21]  Stoyan Tzonkov,et al.  Membranes for optical pH sensors , 1993 .

[22]  J. B. Birks,et al.  Fluorescence Quantum Yield Measurements* , 1976, Journal of research of the National Bureau of Standards. Section A, Physics and chemistry.

[23]  O. Wolfbeis Fiber-optic chemical sensors and biosensors. , 2002, Analytical chemistry.

[24]  Tianlu Chen,et al.  Phenol red immobilized PVA membrane for an optical pH sensor with two determination ranges and long-term stability , 2005 .

[25]  M. Uttamlal,et al.  Covalent immobilization of fluorescent indicators in photo‐ and electropolymers for the preparation of fibreoptic chemical sensors , 2002 .

[26]  D. F. Eaton,et al.  International Union of Pure and Applied Chemistry Organic Chemistry Division Commission on Photochemistry. Reference materials for fluorescence measurement. , 1988, Journal of photochemistry and photobiology. B, Biology.

[27]  A. S. Holmes-Smith,et al.  Development of a quasi-distributed optical fibre pH sensor using a covalently bound indicator , 2001 .

[28]  D. Hopkins,et al.  What is the so-called optimum pH for denitrification in soil? , 2002 .

[29]  R. Ansell,et al.  Fluorescent imprinted polymer sensors for chiral amines. , 2009, Organic & biomolecular chemistry.

[30]  W. Wiczk,et al.  Acidity of carboxyl group of tyrosine and its analogues and derivatives studied by steady-state fluorescence spectroscopy , 2002 .

[31]  K. Drexhage Fluorescence Efficiency of Laser Dyes* , 1976, Journal of Research of the National Bureau of Standards. Section A, Physics and Chemistry.

[32]  Francesco Baldini,et al.  Optical sensor for interstitial pH measurements. , 2007, Journal of biomedical optics.