Process synthesis of hybrid coal, biomass, and natural gas to liquids via Fischer-Tropsch synthesis, ZSM-5 catalytic conversion, methanol synthesis, methanol-to-gasoline, and methanol-to-olefins/distillate technologies

Abstract Several technologies for synthesis gas (syngas) refining are introduced into a thermochemical based superstructure that will convert biomass, coal, and natural gas to liquid transportation fuels using Fischer–Tropsch (FT) synthesis or methanol synthesis. The FT effluent can be (i) refined into gasoline, diesel, and kerosene or (ii) catalytically converted to gasoline and distillate over a ZSM-5 zeolite. Methanol can be converted using ZSM-5 (i) directly to gasoline or to (ii) distillate via olefin intermediates. A mixed-integer nonlinear optimization model that includes simultaneous heat, power, and water integration is solved to global optimality to determine the process topologies that will produce the liquid fuels at the lowest cost. Twenty-four case studies consisting of different (a) liquid fuel combinations, (b) refinery capacities, and (c) superstructure possibilities are analyzed to identify important process topological differences and their effect on the overall system cost, the process material/energy balances, and the well-to-wheel greenhouse gas emissions.

[1]  Efstratios N. Pistikopoulos,et al.  A Multi-Objective Optimization Approach to Polygeneration Energy Systems Design , 2010 .

[2]  Christodoulos A. Floudas,et al.  Simultaneous process synthesis, heat, power, and water integration of thermochemical hybrid biomass, coal, and natural gas facilities , 2012, Comput. Chem. Eng..

[3]  F. Miloua,et al.  Sustainable process for the production of methanol from CO2 and H2 using Cu/ZnO-based multicomponent catalyst , 2009 .

[4]  J. Jechura,et al.  Biomass to Hydrogen Production Detailed Design and Economics Utilizing the Battelle Columbus Laboratory Indirectly-Heated Gasifier , 2005 .

[5]  I. S. Nashawi,et al.  Forecasting World Crude Oil Production Using Multicyclic Hubbert Model , 2010 .

[6]  G. Hong,et al.  4FS control cuts drying costs , 1985 .

[7]  Thomas A. Adams,et al.  Optimal Design and Operation of Static Energy Polygeneration Systems , 2011 .

[8]  Frerich J. Keil,et al.  Methanol-to-hydrocarbons: process technology , 1999 .

[9]  I. Grossmann,et al.  Optimization of Energy and Water Consumption in Corn-Based Ethanol Plants , 2010 .

[10]  Richard C. Baliban,et al.  Toward Novel Hybrid Biomass, Coal, and Natural Gas Processes for Satisfying Current Transportation Fuel Demands, 1: Process Alternatives, Gasification Modeling, Process Simulation, and Economic Analysis , 2010 .

[11]  Ignacio E. Grossmann,et al.  Global optimization for the synthesis of integrated water systems in chemical processes , 2006, Comput. Chem. Eng..

[12]  R. Williams,et al.  Co-production of hydrogen, electricity and CO2 from coal with commercially ready technology. Part B: Economic analysis , 2005 .

[13]  Vern W. Weekman,et al.  Gazing into an Energy Crystal Ball , 2010 .

[14]  Dara Entekhabi,et al.  Water implications of biofuels production in the United States , 2008 .

[15]  Christodoulos A. Floudas,et al.  A review of recent advances in global optimization , 2009, J. Glob. Optim..

[16]  Wei-Ping Pan,et al.  Synthesis Gas Production with an Adjustable H2/CO Ratio through the Coal Gasification Process: Effects of Coal Ranks And Methane Addition , 2008 .

[17]  Ignacio E. Grossmann,et al.  Global superstructure optimization for the design of integrated process water networks , 2011 .

[18]  F. J. Krambeck,et al.  Conversion of propylene and butylene over ZSM‐5 catalyst , 1986 .

[19]  Efstratios N. Pistikopoulos,et al.  A mixed-integer optimization approach for polygeneration energy systems design , 2009, Comput. Chem. Eng..

[20]  Christodoulos A. Floudas,et al.  Optimization framework for the simultaneous process synthesis, heat and power integration of a thermochemical hybrid biomass, coal, and natural gas facility , 2011, Comput. Chem. Eng..

[21]  F. J. Krambeck,et al.  Shaping process makes fuels , 1985 .

[22]  Christodoulos A. Floudas,et al.  Optimal energy supply network determination and life cycle analysis for hybrid coal, biomass, and natural gas to liquid (CBGTL) plants using carbon-based hydrogen production , 2011, Comput. Chem. Eng..

[23]  Nathanael Greene,et al.  The role of biomass in America's energy future: framing the analysis , 2009 .

[24]  Christodoulos A. Floudas,et al.  Automatic synthesis of optimum heat exchanger network configurations , 1986 .

[25]  Ignacio E. Grossmann,et al.  Energy and Water Optimization in Biofuel Plants , 2010 .

[26]  Christodoulos A. Floudas,et al.  Global optimization in the 21st century: Advances and challenges , 2005, Comput. Chem. Eng..

[27]  I. Grossmann,et al.  Process Optimization of FT-Diesel Production from Lignocellulosic Switchgrass , 2011 .

[28]  Rakesh Agrawal,et al.  Sustainable fuel for the transportation sector , 2007, Proceedings of the National Academy of Sciences.

[29]  Robert H. Williams,et al.  Fischer-Tropsch Fuels from Coal and Biomass , 2008 .

[30]  Thomas A. Adams,et al.  High‐efficiency power production from coal with carbon capture , 2010 .

[31]  Maria Sudiro,et al.  Improving Process Performances in Coal Gasification for Power and Synfuel Production , 2008 .

[32]  Fuat E. Celik,et al.  Large‐scale gasification‐based coproduction of fuels and electricity from switchgrass , 2009 .

[33]  S. A. Tabak,et al.  Conversion of methanol over ZSM-5 to fuels and chemicals , 1990 .

[34]  Maria Sudiro,et al.  Synthetic Fuels by a Limited CO2 Emission Process Which Uses Both Fossil and Solar Energy , 2007 .

[35]  Christodoulos A. Floudas,et al.  Nationwide energy supply chain analysis for hybrid feedstock processes with significant CO2 emissions reduction , 2012 .

[36]  Richard C. Baliban,et al.  Toward Novel Hybrid Biomass, Coal, and Natural Gas Processes for Satisfying Current Transportation Fuel Demands, 2: Simultaneous Heat and Power Integration , 2010 .

[37]  Efstratios N. Pistikopoulos,et al.  Decomposition Based Stochastic Programming Approach for Polygeneration Energy Systems Design under Uncertainty , 2010 .

[38]  Arno de Klerk,et al.  Fischer-Tropsch Refining , 2011 .

[39]  Bryce J. Stokes,et al.  Biomass as Feedstock for A Bioenergy and Bioproducts Industry: The Technical Feasibility of a Billion-Ton Annual Supply , 2005 .

[40]  Steven D. Phillips,et al.  Gasoline from Wood via Integrated Gasification, Synthesis, and Methanol-to-Gasoline Technologies , 2011 .

[41]  Schreiner.  Research guidance studies to assess gasoline from coal by methanol-to-gasoline and sasol-type Fischer--Tropsch technologies. Monthly report, November 1977 , 1977 .

[42]  P. Pardalos,et al.  State of the art in global optimization: computational methods and applications , 1996 .

[43]  Thomas A. Adams,et al.  Optimal Design and Operation of Flexible Energy Polygeneration Systems , 2011 .

[44]  Thomas A. Adams,et al.  Combining coal gasification and natural gas reforming for efficient polygeneration , 2011 .

[45]  A. Faaij,et al.  Fischer–Tropsch diesel production in a well-to-wheel perspective: a carbon, energy flow and cost analysis , 2009 .

[46]  Robert H. Williams,et al.  Co-production of hydrogen, electricity and CO2 from coal with commercially ready technology. Part A: Performance and emissions , 2005 .

[47]  Christodoulos A. Floudas,et al.  Hybrid and single feedstock energy processes for liquid transportation fuels: A critical review , 2012, Comput. Chem. Eng..

[48]  Maria Sudiro,et al.  Production of synthetic gasoline and diesel fuel by alternative processes using natural gas and coal: Process simulation and optimization , 2009 .

[49]  Christodoulos A. Floudas,et al.  Global optimization of a MINLP process synthesis model for thermochemical based conversion of hybrid coal, biomass, and natural gas to liquid fuels , 2012, Comput. Chem. Eng..

[50]  Ignacio E. Grossmann,et al.  Simultaneous optimization and heat integration of chemical processes , 1986 .

[51]  M. Giordano,et al.  Biofuels and implications for agricultural water use: blue impacts of green energy , 2008 .

[52]  Christodoulos A. Floudas,et al.  Deterministic global optimization - theory, methods and applications , 2010, Nonconvex optimization and its applications.