Diffusion models for evaporation losses during electron-beam melting of alpha/beta-titanium alloys

An analysis of the evaporation of aluminum during electron-beam melting (EBM) of alpha/beta-titanium alloys was performed. The analysis was based on the solution of the one-dimensional diffusion equation for the solute-concentration gradient in the melt pool subject to the flux boundary condition for the evaporation rate at the melt surface quantified using the Langmuir equation. The effect of process parameters and material coefficients (e.g., the diffusivity and solute activity in the melt) on predicted concentration gradients and melt losses under steady-state melting conditions was established for both the finite-domain and the semi-infinite-domain diffusion problems. The accuracy of the modeling approach was validated by comparison to previous measurements for the EBM of alloys with a nominal Ti-6Al-4V composition.

[1]  Irving Langmuir,et al.  The Vapor Pressure of Metallic Tungsten , 1913 .

[2]  K. Murakami,et al.  Aluminum Evaporation from Titanium Alloys in EB Hearth Melting Process. , 1992 .

[3]  R. Fox Tachyons and quantum statistics , 1972 .

[4]  Paul Shewmon,et al.  Diffusion in Solids , 2016 .

[5]  X-ray-based measurement of composition during electron beam melting of AISI 316 stainless steel: Part II. Evaporative processes and simulation , 2003 .

[6]  J. C. Jaeger,et al.  Conduction of Heat in Solids , 1952 .

[7]  R. W. Gurry,et al.  Physical chemistry of metals , 1953 .

[8]  Siegfried Schiller,et al.  Electron beam technology , 1982 .

[9]  P. Sanders,et al.  Liquid titanium solute diffusion measured by pulsed ion-beam melting , 2001 .

[10]  K. Easterling,et al.  Phase Transformations in Metals and Alloys , 2021 .

[11]  L. Gary Leal,et al.  Laminar Flow and Convective Transport Processes , 1992 .

[12]  S. Semiatin,et al.  Evaluation of evaporation losses during electron-beam melting of Ti-Al-V alloys , 2003 .

[13]  J. Bellot,et al.  Aluminum volatilization and inclusion removal in the electron beam cold hearth melting of Ti alloys , 2000 .

[14]  A. Mitchell,et al.  Melting, casting and forging problems in titanium alloys , 1998 .

[15]  J. Wood Producing Ti-6Al-4V plate from single-melt EBCHM ingot , 2002 .

[16]  V. N. Zamkov,et al.  Mathematical modeling of aluminum evaporation during electron-beam cold-hearth melting of Ti-6Al-4V ingots , 2003 .

[17]  P. Kobryn,et al.  Determination of interface heat-transfer coefficients for permanent-mold casting of Ti-6Al-4V , 2001 .

[18]  J. Szekely,et al.  Analysis of multicomponent evaporation in electron beam melting and refining of titanium alloys , 1997 .