Implications of the Nuvvuagittuq Greenstone Belt for the Formation of Earth's Early Crust

of the belt formed at � 4·28 Ga, which would make it the only known remnant of Hadean crust preserved on Earth. The dominant lithology of the belt has a mafic composition that consists of gneisses ranging from cummingtonite amphibolite to garnet^biotite schist composed of variable proportions of cummingtonite þ biotite þ quartz, � plagioclasegarnetanthophyllitecordierite. The composition of this unit ranges from basalt to andesite and it is divided into two distinct geochemical groups that are stratigraphical- ly separated by a banded iron formation (BIF). At the base of the se- quence, the mafic unit is mainly basaltic in composition and generally has relatively low Al2O3 and high TiO2 contents, whereas above the BIF, the unit is characterized by high Al2O3 and low TiO2 contents and exhibits a wider range of compositions from bas- altic to andesitic. The low-Ti unit can be further subdivided into a trace element depleted and a trace element enriched subgroup. The high-Ti unit is characterized by relatively flat REE patterns as opposed to the low-Ti gneisses, which display light REE-enriched profiles with flat heavy REE slopes. The incompatible element depleted low-Ti rocks have U-shaped REE profiles.The geochemical groups have compositional analogues in three types of ultramafic sills that exhibit the same stratigraphic succession. Generally, the mafic gneisses have low Ca, Na and Sr contents, with many samples having CaO contents51wt %. Such low Ca contents are unlikely to represent the original composition of their igneous precursors and are interpreted to reflect intensive alteration of plagioclase. These compositional characteristics along with the presence of cordier- ite þ anthophyllite suggest that the protoliths of the mafic gneisses were mafic volcanic rocks exhibiting variable degrees of hydrothermal alteration. The high-Ti compositional type shares geochemical char- acteristics with tholeiitic volcanic suites with low Al2O3 and high TiO2 contents and is consistent with crystal fractionation at low pressures under dry conditions. In contrast, the low-Ti compositional group is geochemically similar to boninitic and calc-alkaline volcanic suites.The high Al2O3 and lowTiO2 contents in the andesitic com- positions suggest the early crystallization of Fe^Ti oxides and late appearance of plagioclase, and are more consistent with fractionation at elevated water pressures. The succession from 'tholeitic' to 'calc-alkaline' magmatism seen in the Nuvvuagittuq greenstone belt is typical of the volcanic successions of many younger Archean green- stone belts. Regardless of the exact tectonic setting, this volcanic suc- cession suggests that the geological processes responsible for the formation and evolution of Archean greenstone belts were active at 3·8 Ga and perhaps as early as 4· 3G a.