Comparison of measured stratospheric OH with prediction

The production and loss of stratospheric OH involve relatively fast reactions that are in near-photochemical equilibrium. In this study, we compare OH measured by our balloon-borne far infrared limb observing spectrometer with that predicted from a simple model that uses water and ozone fields obtained from instruments on the upper atmosphere research satellite. This comparison is made for latitudes near 34°N over a full diurnal cycle for five balloon flights that span a period of over 2 years. The ratio of measurement to the photochemical model at 40 km is 0.95, with an uncertainty of 0.08 (at a 90% confidence level) due to the measurement. Comparison at other altitudes and as a function of the diurnal cycle also shows excellent agreement.

[1]  J. Pyle,et al.  Derivation of OH concentration from satellite infrared measurements of NO2 and HNO3 , 1983, Nature.

[2]  S. Lloyd,et al.  Simultaneous, in situ measurements of OH, HO2, O3, and H2O: A test of modeled stratospheric HOx chemistry , 1990 .

[3]  S. Wofsy,et al.  Removal of Stratospheric O3 by Radicals: In Situ Measurements of OH, HO2, NO, NO2, ClO, and BrO , 1994, Science.

[4]  H. Schiff The Stratosphere 1981: Theory and Measurements World Meterological Organization Global Ozone Research and Monitoring Project Report Number 11 Causes and Effects of Stratospheric Ozone Reduction: An Update National Academy of Sciences , 1982 .

[5]  R. M. Stimpfle,et al.  Simultaneous, in situ measurements of OH and HO2 in the stratosphere , 1990 .

[6]  K. Chance,et al.  Stratospheric Hydroperoxyl Measurements , 1990, Science.

[7]  H. Pickett,et al.  Stratospheric OH measurements with a far-infrared limb observing spectrometer , 1993 .

[8]  K. Minschwaner,et al.  Periodic behaviors in the observed vertical column abundances of atmospheric hydroxyl , 1989 .

[9]  G. Mount,et al.  An Intercomparison of Tropospheric OH Measurements at Fritz Peak Observatory, Colorado , 1992, Science.

[10]  J. Kaye,et al.  Concentrations and uncertainties of stratospheric trace species inferred from limb infrared monitor of the stratosphere data: 1. Methodology and application to OH and HO2 , 1986 .

[11]  William S. Heaps,et al.  Progress in stratospheric hydroxyl measurement by balloon-borne LIDAR , 1985 .

[12]  D. B. Peterson,et al.  An Empirical Expression for Line Widths of Ammonia From Far-Infrared Measurements , 1994 .

[13]  J. H. Park,et al.  Spectroscopic measurement of HO2, H2O2, and OH in the stratosphere , 1991 .