论文信息 - The first example of a doubly orthometallated aryl bis(phosphinite) ligand

The first example of a doubly orthometallated aryl bis(phosphinite) ligand

The reaction of 2-methylresorcinolbis(diphenyl)phosphinite with Pd(TFA)2 gives a dimeric tetranuclear complex which contains two of the ligands, each di-orthopalladated; the X-ray structure of the complex has been determined and its reactivity briefly examined.

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