论文信息 - ELECTROCHEMICAL OXIDATION OF AROMATIC OLEFINS. DEPENDENCE OF THE REACTION COURSE ON THE STRUCTURE OF THE OLEFINS AND ON THE NATURE OF THE ANODES

ELECTROCHEMICAL OXIDATION OF AROMATIC OLEFINS. DEPENDENCE OF THE REACTION COURSE ON THE STRUCTURE OF THE OLEFINS AND ON THE NATURE OF THE ANODES

Anodic oxidation of a series of substituted styrenes was investigated in methanol with a platinum and a graphite electrode. Use of the platinum anode gave mainly dimethoxylated monomers accompanied with one or more of three types of dimethoxylated dimers (αα-, αβ-, and ββ-dimers) depending on the substituents. Use of the graphite anode, however, afforded the ββ-dimers as the main product together with dimethoxylated monomers.

H. Sakuragi | K. Tokumaru | M. Kojima

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[2] Tadaomi Inoue,et al. Electrochemical Syntheses. III. The Homolytic Methoxylation of Some Arylated Olefins by the Anodic Oxidation of Methanol , 1965 .